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101.
Elena V. Ukhatskaya Sergey V. Kurkov Roman V. Rodik Vitaly I. Kalchenko Susan E. Matthews Phatsawee Jansook Thorsteinn Loftsson 《Journal of inclusion phenomena and macrocyclic chemistry》2014,79(3-4):473-483
The self-aggregation ability of three amphiphilic cationic calix[4]arenes possessing four quaternary amino groups (aminoCAs) was investigated using a variety of methods. All of the studied compounds possess high aggregation ability. Their critical aggregation concentration (CAC) values in water are in the 0.0009–0.04 % (w/v) concentration range. Several size populations of aggregates were detected by DLS for all three CAs, and restructuring of aggregates was observed to be dependent on concentration. Particles formed above CAC were attributed to formation of vesicular structures (vesicles). The coexistence of other type of aggregates (presumably micelles) with vesicles was observed in the aqueous solution of CAs 2 and 3 from concentrations of 0.5 and 0.8 % (w/v), respectively. The filtration procedure was found to be a significant factor since the obtained data from filtered and unfiltered samples was different. The particle sizes obtained by TEM measurements were somewhat correlated with the DLS data for unfiltered CAs solutions. An analysis of the aggregate composition was undertaken by a size-exclusion method using semi-permeable cellophane membranes with different MWCO. A negative deviation from linearity of permeability flux profile starting from 0.8 % (w/v) concentration of donor phase indicated that the fraction of large aggregates at this point is significant enough that the molecules could not easily permeate through the membranes. 相似文献
102.
Dr. Christina Rest Dr. Divya Susan Philips Torsten Dünnebacke Dr. Papri Sutar Dr. Angel Sampedro Jörn Droste Dr. Vladimir Stepanenko Prof. Dr. Michael Ryan Hansen Dr. Rodrigo Q. Albuquerque Prof. Dr. Gustavo Fernández 《Chemistry (Weinheim an der Bergstrasse, Germany)》2020,26(44):10005-10013
Besides their widespread use in coordination chemistry, 2,2’-bipyridines are known for their ability to undergo cis–trans conformational changes in response to metal ions and acids, which has been primarily investigated at the molecular level. However, the exploitation of such conformational switching in self-assembly has remained unexplored. In this work, the use of 2,2’-bipyridines as acid-responsive conformational switches to tune supramolecular polymerization processes has been demonstrated. To achieve this goal, we have designed a bipyridine-based linear bolaamphiphile, 1 , that forms ordered supramolecular polymers in aqueous media through cooperative aromatic and hydrophobic interactions. Interestingly, addition of acid (TFA) induces the monoprotonation of the 2,2’-bipyridine moiety, leading to a switch in the molecular conformation from a linear (trans) to a V-shaped (cis) state. This increase in molecular distortion along with electrostatic repulsions of the positively charged bipyridine-H+ units attenuate the aggregation tendency and induce a transformation from long fibers to shorter thinner fibers. Our findings may contribute to opening up new directions in molecular switches and stimuli-responsive supramolecular materials. 相似文献
103.
A new disposable sensitive voltammetric sensor for the determination of Fe(III) based on a graphene (G) and piroxicam (Pir) modified screen printed carbon electrode (Pir/G/SPCE) has been developed. The developed method is based on accumulation of Fe(III) on the surface of the prepared sensor strip, formation a complex with Pir and subsequent reduction the adsorbed chelated Fe(III) at ?0.03 V (vs. Ag/AgCl) coupled with the catalytic enhancement of bromate. Characterizations of the modified electrode surface were performed by field emission scanning electron microscopy (FE‐SEM), energy dispersive X‐ray spectroscopy (EDX) and electrochemical impedance spectroscopy (EIS). Electrochemical behavior of the modified SPCEs was investigated by cyclic voltammetry (CV) and differential pulse voltammetry (DPV). Under the optimum conditions, the catalytic voltammetric method exhibited linear calibration plot in the concentration ranges of 1–100 ng mL?1 and 100–3500 ng mL?1 Fe(III) with a limit of detection of 0.3 ng mL?1. The sensor strip displayed good reproducibility with 1.7 % relative standard deviation (RSD%). The developed method was successfully applied for the determination of iron in food samples such as vegetables, fruit, and cereal. 相似文献
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Kurosaki Hiromu Mueller Rebecca J. Lambert Susan B. Rao Govind R. 《Journal of Radioanalytical and Nuclear Chemistry》2017,311(1):323-329
Journal of Radioanalytical and Nuclear Chemistry - An alternate method of preparing actinide alpha counting sources was developed in place of electrodeposition or lanthanide fluoride... 相似文献
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This study examined the effect of the distribution of values for various acoustic properties on the similarity ratings obtained in a paired-comparison study of complex sounds. Listeners rated the similarity of tones and tone complexes in one of four sets. Across the four sets both component frequency and the number of components in the stimuli were drawn from distributions that were either categorical or noncategorical. Other acoustic properties were distributed similarly in all sets. Solutions suggested that frequency was most important to the ratings, followed by the number of components in each critical band. Results suggest that when the values of an acoustic property are distributed categorically, its importance to similarity ratings increases relative to that observed with a less categorical distribution. 相似文献
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