Oxygen and hydrogen profiles and electrical properties of unintentionally doped gallium nitride grown by hydride vapor phase epitaxy

Commercially available hydride vapor phase epitaxy gallium nitride (GaN) is characterized with the aim to correlate the oxygen and hydrogen secondary ion mass spectrometry profiles of a GaN wafer with the electrical properties of the sample. A GaN layer model, including doping profile and mobility, is derived, utilizing electrical (capacitance–voltage, Hall), structural (high resolution X‐ray diffraction) and optical (polarized infrared spectroscopy) methods. Oxygen and hydrogen are easily incorporated during hydride vapor phase epitaxy growth of GaN. Oxygen is an n‐type dopant in GaN, whereas hydrogen may passivate some of the donors. Electrical and optical properties correlate with a low defect concentration top GaN layer and a high defect concentration GaN interlayer.     

Evaluation of choice set generation algorithms for route choice models

This paper discusses choice set generation and route choice model estimation for large-scale urban networks. Evaluating the effectiveness of Advanced Traveler Information Systems (ATIS) requires accurate models of how drivers choose routes based on their awareness of the roadway network and their perceptions of travel time. Many of the route choice models presented in the literature pay little attention to empirical estimation and validation procedures. In this paper, a route choice data set collected in Boston is described and the ability of several different route generation algorithms to produce paths similar to those observed in the survey is analyzed. The paper also presents estimation results of some route choice models recently developed using the data set collected.     

Uniform CLT for Markov chains and its invariance principle: A martingale approach

The convergence of stochastic processes indexed by parameters which are elements of a metric space is investigated in the context of an invariance principle of the uniform central limit theorem (UCLT) for stationary Markov chains. We assume the integrability condition on metric entropy with bracketing. An eventual uniform equicontinuity result is developed which essentially gives the invariance principle of the UCLT. We translate the problem into that of a martingale difference sequence as in Gordin and Lifsic.⁽⁷⁾ Then we use the chaining argument with stratification adapted from that of Ossiander.⁽¹¹⁾ The results of this paper generalize those of Levental⁽¹⁰⁾ and Ossiander.⁽¹¹⁾     

Selective fluorination on tertiary carbon-hydrogen single bonds in the aliphatic series

Fluorine acts as an electrophile and, as such, reacts with remote and unactivated tertiary hydrogens in aliphatic alcohols and acids, resulting in the corresponding fluorine derivatives.     

The temperature dependence of the electron mobility in molecular crystals

We show that a hopping model may explain the experimental temperature dependence of the electron mobility in molecular crystals. The flat, higher temperature portion is obtained if anharmonic effects are included in a simple manner. The low temperature part is obtained if coherent effects are added to the diffusional ones.     

Sufficient conditions for continuous dependence in nonlinear hyperelasticity

Sufficient conditions are derived for the continuous dependence of C ¹-solutions of the mixed boundary value problem (with dead loading) upon the given data, within the framework of nonlinear hyperelasticity.The second author was a visitor at the Department of Mathematics, University of Strathclyde, Glasgow, Scotland, at the time that the revised version was prepared. Author's present address: Department of Mathematics, Plymouth Polytechnic, Plymouth, England.     

Native and modified glucose oxidase in reversed micelles

The enzymatic activity of the native and modified glucose oxidase (GOx) from Aspergillus niger in the system of reversed micelles of Aerosol OT in octane was investigated. Two forms of the modified enzyme were studied: a hydrophobized form obtained by the attachment of palmitic chains to lysine amino groups by the reaction with palmitic acid ester of N-hydroxysuccinimide and a glycosylated (hydrophilized) form obtained by the attachment of the cellobiose moieties. The native glucose oxidase and its derivatives, while incorporated into micelles in a surfactant concentration range from 0.05 to 0.3 M, display an enzymatic activity, which is comparable with the activity in aqueous solution. The dependence of the enzymatic activity on hydration degree of surfactant (the molar ratio of water to surfactant, W₀) does not indicate the formation of qualitatively new associated forms of the enzyme subunits inside the micelles. The apparent size of Aerosol OT micelles obtained by dynamic light scattering gradually increases from 10±3 nm at low W₀ up to 25±5 nm at high W₀. Incorporation of the native and hydrophobized glucose oxidase into micelles does not affect their mean size. Kinetic analysis shows that the enzyme specificity is about an order of magnitude greater in the system of reversed micelles as compared with aqueous solution.     

Variable density effect of self-assembled polarizable monolayers on the electronic properties of silicon

Electronic structures at the Si/SiO2/molecule interfaces were studied by Kelvin probe techniques (contact potential difference) and compared to theoretical values derived by the Helmholtz equation. Two parameters influencing the electronic properties of n-type <100> Si/SiO2 substrates were systematically tuned: the molecular dipole of coupling agent molecules comprising the layer and the surface coverage of the chromophoric layer. The first parameter was checked using direct covalent grafting of a series of trichlorosilane-containing coupling agent molecules with various end groups causing a different dipole with the same surface number density. It was found that the change in band bending (DeltaBB) clearly indicated a major effect of passivation due to two-dimensional polysiloxane network formation, with minor differences resulting from the differences in the end groups' capacity to act as "electron traps". The change in electron affinity (DeltaEA) parameter increased upon increasing the dipole of the end group comprising the monolayer, resulting in a range of 600 mV. Moreover, a shielding effect of the aromatic spacer compared with the aliphatic spacer was found and estimated to be about 200 mV. The density effect was examined using the 4-[4-(N,N-dimethylamino phenyl)azo]pyridinium halide chromophore which has a calculated dipole of more than 10 D. It was clearly shown that upon increasing surface chromophoric coverage an increase in the electronic effects on the Si substrate was observed. However, a major consequence of depolarization was also detected while comparing the experimental and calculated values.