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11.
12.
Slepukhin P. A. Krinochkin A. P. Starnovskaya E. S. Shtaitz Ya. K. Savchuk M. I. Kopchuk D. S. Egorov I. N. Santra S. Zyryanov G. V. Chupakhin O. N. 《Russian Chemical Bulletin》2022,71(7):1533-1543
The structures of six 2,2′-bipyridine derivatives containing aromatic amine moieties, namely N-aryl-4-aryl-1-(pyridin-2-yl)-6,7-dihydro-5H-cyclopenta[c]pyridine-3-amines, were studied by single-crystal X-ray diffraction. The molecular structures and the effect of the substituents of these compounds on the crystal packing are discussed.
相似文献13.
An optical atomic clock scheme is proposed that utilizes two lasers to establish coherent coupling between the 5s2 1S0 ground state of 88Sr and the first excited state, 5s5p 3P0. The coupling is mediated by the broad 5s5p 1P1 state, exploiting the phenomenon of electromagnetically induced transparency. The effective linewidth of the clock transition can be chosen at will by adjusting the laser intensity. By trapping the 88Sr atoms in an optical lattice, long interaction times with the two lasers are ensured; Doppler and recoil effects are eliminated. Based on a careful analysis of systematic errors, a clock accuracy of better than 2 x 10(-17) is expected. 相似文献
14.
A simple model is developed that quantitatively describes intense interactions of a vacuum ultraviolet (VUV) laser pulse with a xenon cluster. We find good agreement with a recent experiment [Nature (London) 420, 482 (2002)]]. In particular, the large number of VUV photons absorbed per atom, at intensities significantly below 10(16) W/cm(2), is now understood. 相似文献
15.
Using neon and its dimer as a specific example, it is shown that excited Auger decay channels that are electronically stable in the isolated monomer can relax in a cluster by electron emission. The decay mechanism, leading to the formation of a tricationic cluster, is based on an efficient energy-transfer process from the excited, dicationic monomer to a neighbor. The decay is ultrafast and expected to be relevant to numerous physical phenomena involving core holes in clusters and other forms of spatially extended atomic and molecular matter. 相似文献
16.
It is demonstrated that excited van der Waals systems can relax by electron emission via a novel interatomic mechanism. The process is analyzed by means of extensive ab initio calculations of potential energy surfaces and electronic decay rates. The electronic emission, taking place on the same time scale as the motion of the atomic nuclei, is accompanied by interesting dynamical effects amenable to experimental observations. These effects arise as a consequence of the weak chemical bond in van der Waals clusters and the Coulomb repulsion pattern originating from electron emission. 相似文献
17.
We discuss the asymptotic behavior of the least energy solution of a Dirichlet problem in the zero mass case. If Q is a uniformly positive potential having k isolated local minima, then we prove the existence of a positive multi-spike solutions having k peaks concentrating at each local minima of the potential. 相似文献
18.
Akhil R Chakravarty Pattubala A. N. Anreddy Bidyut K. Santra Anitha M. Thomas 《Journal of Chemical Sciences》2002,114(4):391-401
Redox active mononuclear and binuclear copper(II) complexes have been prepared and structurally characterized. The complexes have planar N-donor heterocyclic bases like 1,10-phenanthroline
(phen), dipyridoquinoxaline (dpq) and dipyridophenazine (dppz) ligands that are suitable for intercalation to B-DNA. Complexes
studied for nuclease activity have the formulations [Cu(dpq)2(H2O)] (ClO4)2.H2O (1), [CuL(H2O)2(μ-ox)](ClO4)2 (L = bpy,2; phen,3; dpq,4; and dppz,5) and [Cu(L)(salgly)] (L = bpy,6; phen,7; dpq,8; and dppz,9), where salgly is a tridentate Schiff base obtained from the condensation of glycine and salicylaldehyde. The dpq complexes
are efficient DNA binding and cleavage active species. The dppz complexes show good binding ability but poor nuclease activity.
The cleavage activity of thebis-dpq complex is significantly higher than thebis-phen complex of copper(II). The nuclease activity is found to be dependent on the intercalating nature of the complex and
on the redox potential of the copper(II)/copper(I) couple. The ancillary ligand plays a significant role in binding and cleavage
activity. 相似文献
19.
We consider the problem ${\varepsilon^{2}\Delta u - u^q + u^p = 0\,{\rm in}\,\Omega,\,u > 0\,{\rm in}\,\Omega,\,\frac{\partial u}{\partial \nu} = 0\,{\rm on}\,\partial\Omega }$ where Ω is a smooth bounded domain in ${\mathbb{R}^N}$ , ${1 < q < p < {N+2\over N-2}}$ if N ≥ 2 and ${\varepsilon}$ is a small positive parameter. We determine the location and shape of the least energy solution when ${\varepsilon \rightarrow 0.}$ 相似文献
20.
B. S. Dandapat A. Kitamura B. Santra 《Zeitschrift für Angewandte Mathematik und Physik (ZAMP)》2006,57(4):623-635
In this paper we have studied a non-planar thin liquid film flow on a planar stretching surface. The stretching surface is
assumed to stretch impulsively from rest and the effect of inertia of the liquid is considered. Equations describing the laminar
flow on the stretching surface are solved analytically. It is observed that faster stretching causes quicker thinning of the
film on the stretching surface. Velocity distribution in the liquid film and the transient film profile as functions of time
are obtained.
(Received: May 4, 2004; revised: February 2/August 24, 2005) 相似文献