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111.
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Maher F. El-Zohry Thanaa A. Mohamed Essam M. Hussein 《Monatshefte für Chemie / Chemical Monthly》2009,140(3):265-272
Abstract 2-Methylbenzimidazole 1 reacted with 3-dicyanomethylidine-1-ethyl-2-oxoindoline 2 in ethyl acetate to afford 1-amino-2-cyano-3,4-dihydro-1′-ethylspiro{benzimidazo[1,2-a]pyridine-3,3′-indolin}-2′-one 6, which was used as a key intermediate in the synthesis of fused spiropolyheterocyclic derivatives of benzimidazopyridopyrimidine
and/or benzimidazonaphthyridine nucleus incorporating an indoline moiety.
Graphical abstract
相似文献
114.
Essam R. Shaaban Ishu Kansal M. Shapaan José M. F. Ferreira 《Journal of Thermal Analysis and Calorimetry》2009,98(2):347-354
This paper presents the results of kinematical studies of glass transition and crystallization in glassy Se85?x Te15Sb x (x = 2, 4, 6 and 8) using differential scanning calorimetry (DSC). From the dependence on heating rates of, the glass transition temperatures (T g), and temperature of crystallization (T p) the activation energy for glass transition (E g) and the activation energy for crystallization (E c) are calculated and their composition dependence can be discussed in term of the average coordination number and cohesive energy. The thermal stability of Se85?x Te15Sb x was evaluated in terms of criterion ΔT = T c ? T g and kinetic criteria K(T g) and K(T p). By analyzing the crystallization results, the crystallization mechanism is characterized. Two (two- and three-dimensional growth) mechanisms are working simultaneously during the amorphous–crystalline transformation of the Se83Te15Sb3 alloy while only one (three-dimensional growth) mechanism is responsible for the crystallization process of the chalcogenides Se85?x Te15Sb x (x = 4, 6 and 8) glass. The phases at which the alloy crystallizes after the thermal process have been identified by X-ray diffraction. 相似文献
115.
Ahmed M. El-Agrody Heba K. Abd El-Mawgoud Ahmed M. Fouda Essam S. A. E. H. Khattab 《Chemical Papers》2016,70(9):1279-1292
A series of 2-amino-4H-benzo[h]chromene and 2,7-diamino-4H-benzo[h]chromene derivatives were prepared as potential cytotoxic agents. The structures of the synthesised compounds were established on the basis of spectral data. The in-vitro cytotoxic activity of the synthesised compounds against the cell lines MCF-7, HCT-116 and HepG-2 was investigated in comparison with vinblastine and colchicine, using an MTT colorimetric assay. The structure-activity relationship of 4H-benzo[h]chromenes with modification at the 3-, 4- and 7-positions was explored. The results of the anti-tumour evaluation revealed that compounds VIIIc, VIId, VIIb, VIIe, VIIIg and VIIIc, VIId, VIIb, VIIe, VIIIg, VIIc, VIIIe, Vf, IIIa inhibited the growth of MCF-7 in comparison with vinblastine and colchicine, while VIIb, VIId, VIIe, IIIa, VIIa, VIIIc, VIIc, IIId, IIIg, IIIf, IIIb, IIIh, VIIIb, VIIIa, VIIIe, IIIc, Vg, IIIe, VIIIg, Vf, IIIf inhibited the growth of HCT-116 in comparison with colchicine. In addition, compounds VIIe, IIIg, IIIa, VIIc and VIIe, IIIg, IIIa, VIIc, VIIb, VIIa, VIIIf, VIIIe inhibited the growth of HepG-2 in comparison with vinblastine and colchicine, respectively. 相似文献
116.
During the last two decades, dealing with big data problems has become a major issue for many industries. Although, in recent years, differential evolution has been successful in solving many complex optimization problems, there has been research gaps on using it to solve big data problems. As a real-time big data problem may not be known in advance, determining the appropriate differential evolution operators and parameters to use is a combinatorial optimization problem. Therefore, in this paper, a general differential evolution framework is proposed, in which the most suitable differential evolution algorithm for a problem on hand is adaptively configured. A local search is also employed to increase the exploitation capability of the proposed algorithm. The algorithm is tested on the 2015 big data optimization competition problems (six single objective problems and six multi-objective problems). The results show the superiority of the proposed algorithm to several state-of-the-art algorithms. 相似文献
117.
Thirty-six new N,N'-disubstituted thioureas have been synthesized by the reaction of phenyl-, p-fluorophenyl- and benzoylisothiocyanates with various substituted anilines, aminopyridines and 4-aminoquinolines. The uv, ir and nmr spectral data are presented and discussed. 相似文献
118.
Mono 3-(2′-arylallyl) derivatives of 4-hydroxycoumarin 1a,b, 4-hydroxy-6-methyl-pyran-2-one (3) and 6-hydroxy-1,4-dimethyl-1,2-dihydropyrid-2-one-3-carbonitrile (4) are produced in 3-component cascades involving aryl/heteroaryl/vinyl iodides and allene (1 atm) using Pd(PPh3)4/Cs2CO3/MeCN/80 °C or Pd2(dba)3/tris(2-furyl)phosphine/K2CO3/DMF/80 °C as the catalyst system. 4-Hydroxy-2-quinolone (2) afforded a mixture of mono- and bis-allylation products under these conditions. Mono C-allylation products 5a-e and 15a-e undergo facile acid catalysed cyclisation to afford dihydrofurocoumarins 11a-e and dihydrofurodihydropyrid-2-ones 16a-e in good overall yield. 相似文献
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120.
We report on lithium ion conductivity and diffusivity along major crystallographic directions of Al-doped LiFePO4 single crystals. Impedance spectroscopy as well as galvanostatic polarization measurements have been carried out on the electronically blocking symmetric cell LiAl/LiI/LiFe(Al)PO4/LiI/LiAl. Neither ionic conductivity nor lithium diffusivity show anisotropy in the bc planes within the experimental error, but much lower values in the a-direction. Similar features were observed earlier by us for the pure single-crystal and the Si-doped single crystal. On Al-doping the ionic conductivity has increased while the electronic conductivity has decreased compared to undoped LiFePO4. Not only this donor doping effect but also the temperature dependence of ionic conductivity and of lithium-diffusivity are successfully interpreted in terms of lithium vacancies, holes and associates in the framework of a detailed defect chemical analysis. Ion-electron as well as ion-ion associates play a significant role in this system. 相似文献