A note on the reflection principle for the biharmonic equation and the Stokes system

In this note, we discuss the reflection principle of the Stokes system in a half space for the threedimensional case, and of the biharmonic equation. Admitting different boundary conditions, we use the reflection principle to prove uniqueness of solutions of the Stokes system or the biharmonic equation in weightedLq-spaces     

Zeeman transitions in deuterium atoms induced by ultra-relativistic electrons

We present data showing hyperfine transitions in an atomic deuterium beam induced by the (476 MHz) radio-frequency field of a 704 MeV electron beam in a storage ring. A polarized deuterium beam, produced in an atomic beam source, was crossed with a stored electron beam and analyzed with a Breit--Rabi polarimeter. Electron-beam induced transitions were singled out by injecting different combinations of hyperfine states. Transition probabilities as high as 70% were measured at large currents (~ 100 mA). All possible deuterium transitions for a radio-frequency of 476 MHz were observed. In addition, a 1--6 transition resulting from the first harmonic (952 MHz) was observed. The effects of these transitions are of general importance for the polarized internal target technique applied in nuclear and particle physics experiments. The data are reasonably described by numerical estimates. The observed mechanism can be exploited to create nuclear polarized atoms when injecting electron polarized atoms with no net nuclear polarization into a storage cell. However, when nuclear polarized atoms are injected, care should be taken to avoid this mechanism, since it would result in depolarization of the atoms. The studies enabled us to choose the magnetic guide field during our spin-dependent electron--deuteron scattering experiments, such that electron-beam induced depolarizing effects were avoided. This revised version was published online in July 2006 with corrections to the Cover Date.     

Radical Couplings as Key Steps for the Preparation of Derivatives of Nonactic Acid

Summary. Free radical couplings from furan, as cheap starting material, were studied in view of developing a rapid strategy en route to the synthesis of derivatives of nonactin. The chain containing the alcohol function was introduced in one or two steps in 86% yield. For the introduction of the second chain with the ester function two different coupling methods were tested. Starting from the advanced intermediates obtained nonactin derivatives can be prepared by catalytic hydrogenation of the furan ring.     

The stationary and non-stationary stokes system in exterior domains with non-zero divergence and non-zero boundary values

In an exterior domain Ω??ⁿ, n ? 2, we consider the generalized Stokes resolvent problem in L^q-space where the divergence g = div u and inhomogeneous boundary values u = ψ with zero flux ∫_?Ωψ·N do = 0 may be prescribed. A crucial step in our approach is to find and to analyse the right space for the divergence g. We prove existence, uniqueness and a priori estimates of the solution and get new results for the divergence problem. Further, we consider the non-stationary Stokes system with non-homogeneous divergence and boundary values and prove estimates of the solution in L⁵(0, T;L^q(Ω)) for 1 < s, q < ∞.     

New polaron effect in magnetooptic phenomena in a quantum well

It is predicted that resonance coupling between two discrete electron energy levels corresponding to different size-quantization quantum numbers and different Landau quantum numbers can occur in a quantum well in a quantizing magnetic field. The resonance coupling is due to the interaction of an electron with LO phonons and results in the formation of polaron states of a new type. It is shown that for a certain value of the magnetic field, which depends on the splitting of the electron size-quantization levels, the absorption peak and the two-phonon resonance Raman scattering peak split into two components, the separation between which is determined by the electron-phonon coupling constant. The resonance coupling between size-quantization levels with the same Landau quantum numbers is also studied. The splitting of the peaks in this case is virtually independent of the magnetic field and can be observed in much weaker fields. The experimental observation of the effect will make it possible to determine the relative position of the electronic levels and the electron-phonon coupling constant. Pis’ma Zh. éksp. Teor. Fiz. 65, No. 7, 511–515 (10 April 1997)     

Preparing polymer brushes on polytetrafluoroethylene films by free radical polymerization

Films of polytetrafluoroethylene (PTFE) were exposed to sodium naphthalenide (Na/naphtha) etchant so as to defluorinate the surface for obtaining hydroxyl functionality. Surface-initiators were immobilized on the PTFE films by esterification of 4,4′-azobis(4-cyanopentanoic acid) (ACP) and the hydroxyl groups covalently linked to the surface. Grafting of polymer brushes on the PTFE films was carried out by the surface-initiated free radical polymerization. Homopolymers brushes of methyl methacrylate (MMA) were prepared by free radical polymerization from the azo-functionalized PTFE surface. The chemical composition and topography of the graft-functionalized PTFE surfaces were characterized by X-ray photoelectron spectroscopy (XPS), attenuated total reflectance (ATR) FT-IR spectroscopy and atomic force microscopy (AFM). Water contact angles on PTFE films were reduced by surface grafting of MMA.     

Cogenerators for convex spaces

We give cogenerators for the categories of convex (= finitely superconvex), finitely positively convex, and absolute convex (= finitely totally convex) spaces introduced by Pumplün and Röhrl.Dedicated to our academic teacher Dieter Pumplün on the occasion of his sixtieth birthday.