2-碘酰基苯甲酸(2-Iodoxybenzoic acid, IBX)在有机合成中的应用

综述了近年来2-碘酰基苯甲酸(2-iodoxybenzoic acid, IBX)在有机合成中的应用, 重点评述了IBX对醇类、含氮有机物、含硫有机物、连接在芳环上的碳原子的氧化反应, 探讨了IBX在α,β-不饱和羰基化合物和内酯合成中的应用, 这些反应具有反应条件温和、产率高、选择性好等优点. 简单介绍了IBX的一些新衍生物的合成及应用.     

快速响应的温敏性聚(N-异丙基丙烯酰胺)水凝胶的合成及表征

快速响应的温敏性聚(N-异丙基丙烯酰胺)水凝胶的合成及表征;N-异丙基丙烯酰胺;水凝胶;温敏性;快速响应     

Chiral Borated Esters in Asymmetric Synthesis： 1. The First Asymmetric Reaction Catalyzed by Chiral Spiroborated Esters with an O3BN Framework

The first asymmetric reaction catalyzed by chiral spiroborated esters with an O3BN framework was reported. In the presence of 0.1 equivalent of (R,S)-1 or (S,S)-1, acetophenone was reduced by 0.6 equivalent of borane in THF at 0-5℃ for 2 h to give (R)-1-phenylethanol of up to 76% ee and 73% isolated yield. Influence of reaction conditions on the stereoselectivity of the reduction was investigated and a possible catalytic mechanism of the chiral spiroborated esters toward the reduction was also suggested.     

Microcalorimetric Investigation of Influence of Fungicide SYP-L190 on Growth Metabolism of Tetrahyrnena therrnophila and Bacillus thuringiensis

Flumorph (SYP‐L190) is a new systemic fungicide with good protective, curative and antisporulant activities but no phytotoxicity to certain plants. Its performance on the environmental ecosystem is unknown. Tetrahymena thermophila and Bacillus thuringiensis are two of biological indicators for the aquatic and soil environmental ecosystem respectively. Microcalorimetric technique based on the heat output was applied to evaluate the influence of fungicide flumorph (SYP‐L190) on the two microorganisms. The thermogenic curves and corresponding thermodynamic and thermokinetic parameters were obtained. SYP‐L190 at a concentration of 50–100 µg·mL^?1 had 5% –10% inhibitory ratios aganist Tetrahymena thermophila and was used as a protection reagent, while at a concentration of 100–200 µg·mL^?1 SYP‐L190 had 10% –20% inhibitory ratios and was used as a therapy reagent. The metabolic thermogenic curves of Bacillus thuringiensis contained bacterial growth phase and sporulation phase. The SYP‐L190 at a concentration of 0–200 µg·mL^?1 had no influence on bacterial growth phase, but led to a little lag of the sporulation phase with a constant heat output. Hormesis was obviously observed in present study.     

一族Nd:YxGd1-xVO4混晶性质比较及其调Q性能研究

Czoehralski法成功生长了一系列不同Cd／Y的低掺杂Nd：YxGd1-xVO4混晶，并对它们的一些基本性质进行了比较，发现随着Gd含量的增加，晶体晶胞a，c轴常数呈线性增长，故YVO4和GdVO4晶体可以实现无限互溶。少量Gd掺杂可使混晶晶体比热和荧光寿命增大，并有效地增强了其荧光强度。我们对该晶体的低功率泵浦下的Cr^4 ：YAG调Q激光性能也进行了研究，发现Nd：YxGd1-xVO4混晶具有良好调Q性能。     

一种基于局部回归的多尺度碳市场价格预测模型研究

碳市场价格呈现非线性、非平稳的复杂特性,准确预测具有较大的挑战。基于“分而治之”的思想,提出了一种基于局部回归的多尺度碳市场价格预测模型。提出的模型利用集成经验模态分解(EEMD)对碳市场价格时间序列进行分解。启发于EEMD局部特征分解的特点,对分解后的分量采用局部回归方法进行预测,然后将分量预测结果进行集成。采用的局部回归方法包括局部线性回归(LLP)、局部多项式回归、局部岭回归、局部主成分回归、局部偏最小二乘回归和局部套索回归。实验结果表明基于局部回归的多尺度预测模型具有优异的预测性能。在提出的模型中,EEMD-LLP结构简单且性能更为突出,进一步对EEMD-LLP参数的适应性进行探讨。与新近提出模型的对比结果表明了EEMD-LLP在碳市场价格预测中的有效性。     

三Ⅰ表达式取最小值时的最优解

在本文中,针对蕴涵算子R_0,我们给出了当A→B与A~*(B~*)给定时,求使三Ⅰ表达式(A→B)→(A~*→B~*)取最小值的全体B~*(A~*)之集的上确界(下确界)算法。并将上确界算法推广到多维多重的模糊推理中。从三Ⅰ表达式取最值时求最优的B~*(A~*)的角度来看,本文是三Ⅰ算法思想的延伸和完善。     

Water-soluble phosphate-functionalized polyfluorene as fluorescence biosensors toward cytochrome c

An anionic water-soluble polyfluorene derivative, poly(9,9-bis(6′-phosphatehexyl)fluorene-alt-1,4-pheny lene) sodium salt (PFHPNa), was synthesized by Suzuki coupling reaction in DMF/water. Polymer PFHPNa was well soluble in water with a strong blue fluorescence emission. Effect of the side chain length on fluorescence sensory properties was studied by comparing quenching efficiencies toward different quenchers of PFHPNa with a reported polymer poly(9,9-bis(3′-phosphatepropyl)fluorene-alt-1,4-phenylene) sod...     

非旋波近似下级联型三能级原子与腔场相互作用的量子动力学性质

研究非旋波近似下级联型三能级原子与单模腔场的相互作用.结果表明：非旋波近似下，由于虚光场的影响，辐射场的平均光子数和二阶相干度的演化曲线均出现了“小锯齿状”，表现为系统的量子噪声，随着ω和的增大，量子噪声分别减小和增大；非旋波近似下，系统的反聚束效应较旋波近似的强；研究结果还揭示了平均光子数N(t)和二阶相干度g²(t)与原子-场耦合系数λ的关系. 关键词：     

P3121(D34)空间群晶体的Raman谱研究(Ⅰ)——二元系压电晶体用Al1-xGaxPO4的Raman谱

测得了二元系压电晶体磷酸铝镓Al_1-xGa_xPO₄(x=0.12)的Raman谱,与α-ALPO₄晶体的Raman谱相比,声子频率的红移多于蓝移;E类振动的TO和LO模的劈裂明显减少,依据晶格动力学的观点解释了这些特点。 关键词：