Production of carrier-free 188Re in the past ten years in Taiwan

Twenty clinical scale alumina-based ¹⁸⁸W/¹⁸⁸Re generators and carrier-free ¹⁸⁸Re has been produced at the Institute of Nuclear Energy Research (INER-Taiwan) for over ten years. 2845.6 GBq (76.9 Ci) of ¹⁸⁸Re-perrhenate solution has been eluted from generators during the past ten years. We have used the harvesting ¹⁸⁸Re solution for labeling radiopharmaceuticals, such as ¹⁸⁸Re-HEDP, ¹⁸⁸Re-MDP, ¹⁸⁸Re-microsphere, ¹⁸⁸Re-lipiodol, and ¹⁸⁸Re-sulfur colloid, etc. The average eluting yield of ¹⁸⁸Re is 78.6±5.8% that was investigated at 1115 harvesting times from 20 generators. Each generator can be used more than six months but the Millipore needs to be changed every two months for smooth harvesting and high yield of ¹⁸⁸Re solution.     

Synthesis of electroluminescent copoly(aryl ether)s containing alternate 1,4‐distyrylbenzene derivatives and aromatic 1,3,4‐oxadiazole or 3,3″‐terphenyldicarbonitrile segments

New copoly(aryl ether)s ( P1 – P3 ) containing alternate 2,5‐dihexyloxy‐1,4‐di(m‐ethoxystyryl)benzene ( P1 , P2 ) or 2,5‐dihexyloxy‐1,4‐distyrylbenzene ( P3 ) chromophores and aromatic 1,3,4‐oxadiazole ( P1 ) or 3,3″‐terphenyldicarbonitrile ( P2 , P3 ) segments were prepared by Horner reaction ( P1 and P2 ) or nucleophilic displacement reaction ( P3 ). They are basically amorphous materials with 5% weight‐loss temperature above 410 °C. Their absorption, photoluminescence spectra, and quantum yields are dependent on the composition of the isolated fluorophores. The emissions are exclusively dominated by 1,4‐distyrylbenzene segments via excitation energy transfer from electron‐transporting 1,3,4‐oxadiazole ( P1 ) or 3,3″‐terphenyldicarbonitrile ( P2 , P3 ) chromophores. The HOMO and LUMO energy levels have been estimated from their cyclic voltammograms, and the observations confirm that oxidation and reduction start from the emitting 1,4‐distyrylbenzene and electron‐transporting segments, respectively, indicating that both carriers affinity can be enhanced simultaneously. Among the two‐layer PLED devices (ITO/PEDOT/ P1 – P3 /Al), P1 exhibits the best performance with a turn‐on field of 4 × 10⁵ V/cm and a maximum luminance of 225 cd/m². However, P2 emits green–yellow light (555 nm), owing to the excimer emission. © 2005 Wiley Periodicals, Inc. J Polym Sci Part A: Polym Chem 43: 5009–5022, 2005     

Build-up of supercontinuum in heated and unheated photonic crystal fibers using a chirped femtosecond laser

The build-up of supercontinuum in a photonic crystal fiber (PCF) has been investigated experimentally as a function of pump power using chirped 100-fs pulses from a Ti:sapphire laser. As compared with the PCF at room temperature, a new blue-shifted spectral component is observed in the initial steps of supercontinuum (SC) generation when the central part of PCF is heated to 120 °C by a hot plate. In addition, the slope efficiency of SG is slightly improved with the slightly extension of supercontinuum spectrum in blue edge at high pump powers. The change in dispersion property as well as the effective cascading of nonlinear photonic crystal fibers for heated PCF would be the main attributions.     

Experimental limitations in impedance spectroscopy: Part VI. Four-point measurements of solid materials systems

Four-point impedance spectroscopy of solid materials systems is severely hampered by unavoidable voltage-divider effects associated with the reference electrodes. As demonstrated by test circuit studies and experiments with Pt/YSZ/Pt cells (with embedded silver reference electrodes), high impedance reference electrodes can produce distorted and erroneous impedance data. The relationships between these data and the sample properties (conductivity, dielectric constant) and instrument limitations (input impedance/capacitance) are derived. Successful four-point impedance measurements on conductive systems require large effective dielectric constants, which may be unattainable in bulk solids, but are often associated with internal interfaces.     

Asymptotic Stability for a Class of Neutral Systems with Discrete and Distributed Time Delays

In this note, the asymptotic stability for a class of neutral systems with discrete time and distributed time delays is considered. Delay-dependent criteria are proposed to guarantee the stability for such systems. Some numerical examples are given to illustrate that our results are less conservative than previous results.     

Effect of interfacial shallow traps on polaron transport at the surface of organic semiconductors

The photo-induced electron and hole transfer across the semiconductor-dielectric interface in trap-dominated p-type organic field-effect transistors has been investigated. It has been observed that the transfer of electrons into the dielectric results in a decrease of the field-effect mobility of polarons, suggesting that additional shallow traps are generated in the conduction channel. Using this effect, the dependence of the field-effect mobility on the density of shallow traps, mu(N), has been measured, which allowed us to estimate the average polaron trapping time, tau_{tr}=50+/-10 ps, and the density of shallow traps, N0=(3+/-0.5) x 10(11) cm(-2), in the channel of single-crystal tetracene devices.     

Nonlinear theory of forced surface waves in a circular basin

A nonlinear theory is developed to study surface waves excited by the prescribed horizontal oscillation of the side wall of a circular basin. It is assumed that the frequency of the forced oscillation is near either one of the resonance frequencies of the water in the basin or twice of it. A multiple-scale asymptotic expansion is constructed to derive an equation for the amplitude of an excited eigenmode and critical points of some parameters are found for primary and subharmonic resonance waves. Across these critical points the eigenmode amplitude increases abruptly but remains bounded except at certain values of the water radius to the depth ratio where internal resonance appears.     

Forced capillary-gravity waves in a circular basin

A linear theory is developed to study the forced capillary-gravity waves generated on water in a circular basin by the horizontal oscillations of its side wall. A Green's function method is used to construct a solution of the linearized equations subject to an edge condition at the contact line. The problem is reformulated in terms of an integral equation on the equilibrium free surface, and a uniqueness result is obtained by invoking the Fredholm's alternatives.     

Electric and elastic multipole defects in finite piezoelectric media

In this paper, a piezoelectric analogy theorem is proposed, in which a piezoelectric body is represented as being composed of two fictitious bodies, an elastic body and a rigid dielectric body. An electric and elastic multipole approach for the treatment of various defects (dislocation, inhomogeneity, …) in finite piezoelectric media is then developed. It is shown that the electric and elastic coupling effects, the boundary effects, and the defects may be considered uniformly as sources of permanent and induced electric and elastic multipoles.     

Active dielectric metasurface based on phase‐change medium

We propose all‐dielectric metasurfaces that can be actively re‐configured using the phase‐change material Ge₂Sb₂Te₅ (GST) alloy. With selectively controlled phase transitions on the composing GST elements, metasurfaces can be tailored to exhibit varied functionalities. Using phase‐change GST rod as the basic building block, we have modelled metamolecules with tunable optical response when phase change occurs on select constituent GST rods. Tunable gradient metasurfaces can be realized with variable supercell period consisting of different patterns of the GST rods in their amorphous and crystalline states. Simulation results indicate a range of functions can be delivered, including multilevel signal modulating, near‐field coupling of GST rods, and anomalous reflection angle controlling. This work opens up a new space in exploring active meta‐devices with broader applications that cannot be achieved in their passive counterparts with permanent properties once fabricated.