Differential Photoluminescent and Electrochemiluminescent Detection of Anions with a Modified Ruthenium(II)–Bipyridyl Complex

Different lights, different selectivies : Luminescence of a new guanidinium 3,3′‐functionalized bipyridyl–Ru^II complex has been studied for sensing of several anions. L ‐Glutamate and dihydrogenphosphate are both detected by photoluminescence and electrochemiluminescence. However, the complex displays differential selectivities for these anions depending on the sensing channels (see scheme).

     

f-Structures of Kenmotsu Type

A class of manifolds which admit an f-structure with s-dimensional parallelizable kernel is introduced and studied. Such manifolds are Kenmotsu manifolds if s = 1, and carry a locally conformal K?hler structure of Kashiwada type when s = 2. The existence of several foliations allows to state some local decomposition theorems. The Ricci tensor together with Einstein-type conditions and f-sectional curvatures are also considered. Furthermore, each manifold carries a homogeneous Riemannian structure belonging to the class of the classification stated by Tricerri and Vanhecke, provided that it is a locally symmetric space. Dedicated to the memory of Professor Aldo Cossu     

Helium-neon laser irradiation of rat liver mitochondria gives rise to a new subpopulation of mitochondria: isolation and first biochemical characterization.

An experiment was performed to isolate the small atypical mitochondria produced during the irradiation of normal mitochondria with an He-Ne laser. Rat liver mitochondria were irradiated with a low-power continuous-wave He-Ne laser (energy dose, 5 J cm-2), followed by isolation using a sucrose gradient. In the irradiated sample, two bands were observed, one corresponding to normal mitochondria and the other to atypical mitochondria. Certain biochemical features of the mitochondria were investigated: mitochondrial enzyme activity and the presence of DNA and RNA were demonstrated. Hybridization experiments carried out with labelled mitochondrial probes, containing the genes for cytochrome oxidase subunit I and 12S rRNA, confirmed the mitochondrial nature of the isolated RNA.     

Inelastic intermediate states in proton-deuteron and deuteron-deuteron elastic collisions at the ISR

We present experimental results on proton-deuteron and deuteron-deuteron elastic scattering measured at the two highest ISR energies, √s = 53 GeV and √s = 63 GeV. The data cover the single- and multiple-scattering regions over a wide interval of four-momentum transfer t. In both reactions we find clear evidence for a substantial t-dependent contribution of inelastic intermediate states in the multiple-scattering region, as well as in single scattering. In the analysis we use the Glauber multiple-scattering theory extended to include inelastic shadow effects. This extension of the basic theory contains as input a triple-Regge parametrization describing the high-mass inclusive spectrum. The analysis of inelastic corrections to multiple scattering on deuterons at high energies is shown to provide a sensitive test of different parametrization of inclusive production in proton-proton collisions.     

Evidence of Cr(VI) formation during analysis of leather Proposal of an alternative method of analysis through the ion-chromatographic approach and post-column reaction

The formation of Cr(VI) in Cr(III) tanned leather, in neutral and alkaline solution, has been demonstrated by means of crossed experiments using different pH buffers, ethylenediaminetetraacetic acid as Cr(III) complexing agent and NaCl solutions. According to the found results the composition of the extracting solution suitable to extract Cr(VI) amount present in leather was pH 4.4 (which is also the tanned leather natural pH) and 5% NaCl (w/v). Interferences coming from coloured compounds have been eliminated with suitable SPE cartridges. A new protocol for the analysis of Cr(VI) based on ion chromatography and a diphenylcarbazide post-column reaction has been implemented. The use of a large volume injection loop (500 μl) allowed to obtain a very low quantification limit (0.15 mg kg⁻¹) despite the low amount of leather extracted (0.2 g with respect to 2.0 g used by the IUC 18 official method). Evidence of the transient nature of Cr(VI) in leather requires using the external calibration procedure for the correct quantification of the species.     

Analysis of double diffraction dissociation in nucleon-nucleon collisions at the CERN ISR

Final results from combined measurements of single and double diffraction of protons neutrons into (Nπ) and (Nππ) final states are presented. The experiments were performed at the CERN Intersecting Storage Rings with the Split Field Magnet detector using proton and deuteron colliding beams.The general properties of the dissociating vertex in single and double diffractive reactions are essentially identical. Mass spectra and decay angular distributions are compared with the predictions of a dual resonant Deck model. Decay angular correlations and a strong slope-mass correlation are observed also in double diffraction. Detailed tests of factorization indicate its validity over the full range of all kinematical variables and in their correlations.A model-independent analysis gives strong support to the peripheral nature of diffraction dissociation, with double diffraction being concentrated in a narrow gaussian ring at the edge of the proton. Both the exclusive and the inclusive double diffractive cross sections display a marked increase over the ISR energy range. Both mechanisms yield comparable contributions to the peripheral increase of the total pp cross section, with an approximate saturation of the Pumplin bound.     

Anthocyanins Recovered from Agri-Food By-Products Using Innovative Processes: Trends,Challenges, and Perspectives for Their Application in Food Systems

Anthocyanins are naturally occurring phytochemicals that have attracted growing interest from consumers and the food industry due to their multiple biological properties and technological applications. Nevertheless, conventional extraction techniques based on thermal technologies can compromise both the recovery and stability of anthocyanins, reducing their global yield and/or limiting their application in food systems. The current review provides an overview of the main innovative processes (e.g., pulsed electric field, microwave, and ultrasound) used to recover anthocyanins from agri-food waste/by-products and the mechanisms involved in anthocyanin extraction and their impacts on the stability of these compounds. Moreover, trends and perspectives of anthocyanins’ applications in food systems, such as antioxidants, natural colorants, preservatives, and active and smart packaging components, are addressed. Challenges behind anthocyanin implementation in food systems are displayed and potential solutions to overcome these drawbacks are proposed.