Planar Chiral Phosphoramidites with a Paracyclophane Scaffold: Synthesis,Gold(I) Complexes,and Enantioselective Cycloisomerization of Dienynes

The key structural feature of the new phosphoramidites is a paracyclophane scaffold in which two aryl rings are tethered by both a 1,8‐biphenylene unit and a O?P?O bridge. Suitable aryl substituents generate planar chirality. The corresponding gold(I) complexes promote the cycloisomerization of prochiral nitrogen‐tethered dienynes. These reactions afford bicyclo[4.1.0]heptene derivatives displaying three contiguous stereogenic centers, with very high diastereoselectivity and up to 95 % ee.     

Energy transfer in poly(3‐hexylthiophene)‐g‐Polyfluorene graft copolymers

Conjugated graft copolymers consisting of a poly(3‐hexylthiophene) (P3HT) backbone and poly(9,9'‐dioctylfluorene) side chains (PF) with different grafting degrees were synthesized by the CuAAC reaction. The properties of these materials were studied by UV‐Vis and fluorescence spectroscopy. The former technique provides insight in their self‐assembly, while the latter is used to study the energy funneling from the PF side chains to the P3HT backbone. © 2015 Wiley Periodicals, Inc. J. Polym. Sci., Part A: Polym. Chem. 2016 , 54, 1252–1258     

A spatial covariance model with a single wave effect and a finite range

We propose a new spatial covariance model with a single wave effect and a finite range. The construction of this model is based on a radial kernel composed of two concentric spheres and the finite range enables us to obtain an exact simulation from the circulant embedding method. This model responds to the lack of efficient covariance functions to model patterns characterized by concentration areas surrounded by gaps. We compare the single wave model to other existing hole effect models such as the Bessel model, the damped cosine model and the cardinal sine model.     

Acid Catalyzed Cyclization of Bis Silyl Diacylhydrazines: A New 1, 3, 4-Oxadiazole Synthesis

Diacylhydrazines are converted in good yields into 1,3,4-oxadiazoles with dichlorodimethyl-silane and trifluoromethane sulfonic acid.