Wind tunnel simulation of air pollution dispersion in a street canyon

Physical simulation was used to study pollution dispersion in a street canyon. The street canyon model was designed to study the effect of measuring flow and concentration fields. A method of C02-laser photoacoustic spectrometry was applied for detection of trace concentration of gas pollution. The advantage of this method is its high sensitivity and broad dynamic range, permitting monitoring of concentrations from trace to saturation values. Application of this method enabled us to propose a simple model based on line permeation pollutant source, developed on the principle of concentration standards, to ensure high precision and homogeneity of the concentration flow. Spatial measurement of the concentration distribution inside the street canyon was performed on the model with reference velocity of 1.5 m/s.     

Cylindricity of tangent bundles of strongly parabolic metrics and strongly parabolic surfaces

It is proved that if the intrinsic zero-index of the Sasaki metric of a tangent bundleTM ⁿ isk, thenk is even andM ⁿ is the metric product of a Riemannian manifoldM ^n–k/2 by a Euclidean spaceE ^k/2, whileTM ⁿ is the metric product ofTM ^n–k/2 byE ^k . An expression is obtained for the second fundamental forms of the imbeddingTF ^l TM ⁿ in terms of the second fundamental forms of the imbeddingF ^l M ⁿ and the curvature tensor ofM ⁿ . It is proved thatTF ^l is totally geodesic inTM ⁿ if and only ifF ^l is totally geodesic inM ⁿ .Translated from Ukrainskií Geometricheskií Sbornik, Issue 28, 1985, pp. 12–32.     

Non-steady state homogeneous nucleation in glass-forming systems: Dimensionless kinetic equation

The kinetic equation of the classical homogeneous nucleation theory is rewritten in dimensionless form and it is shown that the numerical computation of the dimensionless kinetic equation is approximately 20 times faster in comparison with the original kinetic equation. The results are compared with known analytical results and with previous numerical results in the case of the constant and variable temperature for the model Li₂O.2 SiO₂ melt. It is shown, e.g., that under non-isothermal conditions the nucleation rate is greater than the quasistationary nucleation rate and the cluster distribution function is greater than the corresponding quasiequilibrium cluster distribution function.     

Sensitivity of hydrodynamic system of the Obukhov type

The paper deals with the regime of advanced Bénard instabilities (described usually by the Lorenz system) in a more general system formulated firstly by Obukhov. It has been shown that triplet co-operation leads to characteristic courses where some new regularities occur.     

Influence of metastable-metastable collisions on electron distribution function in afterglow

The time dependence of the electron distribution function in helium afterglow, for pressures of 60–260 Pa, is calculated for the case in which metastable-metastable reactions are present. The time variation of the shape of the distribution function shows that careful consideration must be made of the time derivative of the distribution function in the Boltzmann equation for the calculation of the rate constant of such reactions from experimentally determined distribution function.     

Softening during and after the hot deformation of the AISI 321 steel with respect to practical applications

The softening processes during and after the hot deformation (850–1180 C) in AISI 321 stainless steel were studied with respect to true strains _D and true strain rates . The analysis of deformation curves indicates the occurrence of dynamic recrystallization for values of Zener-Hollomon parameterZ10¹⁵ s^–1. The retardation of static recrystallization by fine Ti(N, C) precipitates is documented by microstructure studies and by variations of annealing conditions.     

Scalar gluonium candidates and the radiativeJ/ψ decays

We discuss productions of scalar gluonium candidates in the radiativeJ/ decays. The branching ratios of such productions are estimated on the basis of the Euler-Heisenberg effective Lagrangian for gluon-photon couplings. We mention that these estimates cannot be expected to be accurate to better than within a factor 2. We show that the radiativeJ/ decays probably invalidate gluoniumgg interpretation of the GAMS meson F₀(1590) and a narrow 0⁺⁺ stateS lying below 1 GeV. However, a possible wide scalar effective gluonium candidate(920) is shown not to be excluded by the data on the decayJ/. We also find that the experimental data about radiativeJ/ decays presumably agree with a recently suggested interpretation of F₀(1590) as being approximately a half-and-half mixture of pure 0⁺⁺ gluoniumgg andSU(3)_f singlet quarkoniumq¯q states.     

Peptide labeling using 188Re, 188Re-MAG3 and 153Sm-H1ETA: A comparison on their in vitro lipophilicity

Lanreotide peptide was labeled with ¹⁵³Sm-H₁ETA and ¹⁸⁸Re-MAG₃ in order to evaluate whether or not their conjugation to the peptide produce significant differences of the in vitro lipophilicity with respect to the ¹⁸⁸Re-lanreotide prepared by the direct labeling method (highly lipophilic). The differences of lipophilicity between the complexes, were evaluated using a reverse phase HPLC system. The measured lipophilicity of ¹⁵³Sm-H₁ETA-lanreotide, ¹⁸⁸Re-MAG₃-lanreotide and ¹⁸⁸Re-lanreotide was taken to be the capacity factor [k" = (t _R-t ₀)/t ₀ where t _R is the retention time and t ₀ is the dead time] for each of the complexes under identical chromatography conditions. Results showed that the in vitro lipophilicity decreased in the order ¹⁸⁸Re-lanreotide (direct labeling), ¹⁸⁸Re-MAG₃-lanreotide and ¹⁵³Sm-H₁ETA-lanreotide. Since the last one has a capacity factor (k") similar to that of ¹⁸⁸Re-MAG₃, some renal elimination for ¹⁵³Sm-H₁ETA-lanreotide could be expected, which probably would reduce the unnecessary radiation dose to normal tissues.     

Bonding Properties of a Novel Inorganometallic Complex, Ru(SnPh(3))(2)(CO)(2)(iPr-DAB) (iPr-DAB = N,N'-Diisopropyl-1,4-diaza-1,3-butadiene), and its Stable Radical-Anion, Studied by UV-Vis, IR, and EPR Spectroscopy, (Spectro-) Electrochemistry, and Density Functional Calculations

Ru(SnPh(3))(2)(CO)(2)(iPr-DAB) was synthesized and characterized by UV-vis, IR, (1)H NMR, (13)C NMR, (119)Sn NMR, and mass (FAB(+)) spectroscopies and by single-crystal X-ray diffraction, which proved the presence of a nearly linear Sn-Ru-Sn unit. Crystals of Ru(SnPh(3))(2)(CO)(2)(iPr-DAB).3.5C(6)H(6) form in the triclinic space group P&onemacr; in a unit cell of dimensions a = 11.662(6) ?, b = 13.902(3) ?, c = 19.643(2) ?, alpha = 71.24(2) degrees, beta = 86.91(4) degrees, gamma = 77.89(3) degrees, and V = 2946(3) ?(3). One-electron reduction of Ru(SnPh(3))(2)(CO)(2)(iPr-DAB) produces the stable radical-anion [Ru(SnPh(3))(2)(CO)(2)(iPr-DAB)](*-) that was characterized by IR, and UV-vis spectroelectrochemistry. Its EPR spectrum shows a signal at g = 1.9960 with well resolved Sn, Ru, and iPr-DAB (H, N) hyperfine couplings. DFT-MO calculations on the model compound Ru(SnH(3))(2)(CO)(2)(H-DAB) reveal that the HOMO is mainly of sigma(Sn-Ru-Sn) character mixed strongly with the lowest pi orbital of the H-DAB ligand. The LUMO (SOMO in the reduced complex) should be viewed as predominantly pi(H-DAB) with an admixture of the sigma(Sn-Ru-Sn) orbital. Accordingly, the lowest-energy absorption band of the neutral species will mainly belong to the sigma(Sn-Ru-Sn)-->pi(iPr-DAB) charge transfer transition. The intrinsic strength of the Ru-Sn bond and the delocalized character of the three-center four-electron Sn-Ru-Sn sigma-bond account for the inherent stability of the radical anion.