全文获取类型
收费全文 | 8231篇 |
免费 | 409篇 |
国内免费 | 137篇 |
专业分类
化学 | 4882篇 |
晶体学 | 60篇 |
力学 | 215篇 |
综合类 | 7篇 |
数学 | 1691篇 |
物理学 | 1922篇 |
出版年
2023年 | 59篇 |
2022年 | 54篇 |
2021年 | 82篇 |
2020年 | 108篇 |
2019年 | 136篇 |
2018年 | 217篇 |
2017年 | 186篇 |
2016年 | 291篇 |
2015年 | 248篇 |
2014年 | 315篇 |
2013年 | 654篇 |
2012年 | 497篇 |
2011年 | 621篇 |
2010年 | 371篇 |
2009年 | 313篇 |
2008年 | 483篇 |
2007年 | 462篇 |
2006年 | 451篇 |
2005年 | 334篇 |
2004年 | 301篇 |
2003年 | 206篇 |
2002年 | 213篇 |
2001年 | 125篇 |
2000年 | 104篇 |
1999年 | 95篇 |
1998年 | 78篇 |
1997年 | 80篇 |
1996年 | 82篇 |
1995年 | 59篇 |
1994年 | 45篇 |
1993年 | 54篇 |
1992年 | 71篇 |
1991年 | 54篇 |
1990年 | 58篇 |
1989年 | 59篇 |
1988年 | 56篇 |
1987年 | 57篇 |
1986年 | 44篇 |
1985年 | 70篇 |
1984年 | 81篇 |
1983年 | 69篇 |
1982年 | 62篇 |
1981年 | 48篇 |
1980年 | 56篇 |
1979年 | 50篇 |
1978年 | 76篇 |
1977年 | 45篇 |
1976年 | 54篇 |
1975年 | 47篇 |
1974年 | 54篇 |
排序方式: 共有8777条查询结果,搜索用时 31 毫秒
991.
Ana Amić Zoran Marković Jasmina M. Dimitrić Marković Dejan Milenković Bono Lučić 《Molecular physics》2013,111(2):207-217
ABSTRACTParticipation of guaiacyl moiety of 3,5-dihydroxy-4-methoxybenzyl alcohol (DHMBA) in inactivation of free radicals was investigated using the DFT method. The thermodynamics of triple (3H+/3e?) free radical scavenging mechanisms was investigated. The Gibbs free energies of reactions of inactivation of selected 10 free radicals indicate DHMBA as a potent scavenger. Obtained results allow us to suggest that the contribution of guaiacyl moiety to antioxidant activity of phenolic compounds should be taken into account, what has been scarcely considered until now. 相似文献
992.
Existence of 2D enstrophy cascade in a suitable mathematical setting, and under suitable conditions compatible with 2D turbulence phenomenology, is known both in the Fourier and in the physical scales. The goal of this paper is to show that the same geometric condition preventing the formation of singularities – ${\frac{1}{2}}$ -Hölder coherence of the vorticity direction – coupled with a suitable condition on a modified Kraichnan scale, and under a certain modulation assumption on evolution of the vorticity, leads to existence of 3D enstrophy cascade in physical scales of the flow. 相似文献
993.
Jasmina M. Dimitrić Marković Dragan S. Veselinović Jelisaveta M. Baranac Tanja P. Brdarić 《光谱学快报》2013,46(3):104-115
Complexation of aluminum (III) with cyanidin, a natural anthocyanidin molecule, has been investigated in methanol and buffered solutions of pH 3.0 and 4.0. Electronic absorption spectroscopy was performed to characterize the stoichiometry and stability of the complexes formed. In investigated solvents, aluminum bonded moderately to cyanidin requiring large mole ratios of the components (up to 200) for the access of complexation. Molar ratio plots showed the formation of only one complex with stoichiometry aluminum (III):cyanidin of 1∶1 in both investigated media. Semiempirical calculations, performed in the Austin Model 1 parameterization, enabled the determination of the structural features of free compounds as well as complex structural modifications caused by chelation of Al(III). 相似文献
994.
Raman spectra of the species Hg(SCN)2, [Hg(SCN)3], and [Hg(SCN)4]2- in solution of ten aprotic donor solvents have been investigated in the region of the Hg-S vibration. Observed frequency values of measured band of Hg(SCN)2 and [Hg(SCN)3] in different solutions correlate well with donor strength of the solvents. There is a linearity between Hg-S frequency decreasing and increasing of the interaction of the solvent molecules with the mercury (II) ion in the thiocyanate complexes. No significant frequency changes have be found for [Hg(SCN)4]2-. Evidence based on the frequency shifts and depolarization ratios in various solvents supports the view that the Hg(SCN)2 in solution undergos departure from linearity as a result of increasing solvent coordination to the mercury (II) ion. Almost constant frequencies of Hg-S vibration of [Hg(SCN)4]2- in all investigated solvents suggest a regular tetrahedral structure of the ion in solution having much larger radius than corresponding HgX4 (X=Cl,Br,I) ions. 相似文献
995.
The fluorescence characteristics of the Schiff bases 2-(3-pyridylmethyliminornethyl)phenol (1), 2-(2 pyridyliminomethyl)phenol (2), N.N-bis(salicylidene)-2,3-pyridinediamine (3), N,N'-bis(salicylidene)-2,6-pyridinediamine (4) and 2-(2-amino-4-methoxymethyl-6-methyl-3-pyridylmethyliminomethyl)phenol (5) were studied in various solvents at different pH values. Corresponding quantum efficiencies were determined. Compound 1, which showed a tendency towards tautomeric mterconversion to ketoamine in polar protic solvents, was not fluorescent at pH < 8. The fluorescence of other compounds was very sensitive to solvent polarity and the pH of the medium. Compounds 2-4, preferably present as enolimines in all solvents, were not fluorescent in non-polar and moderately polar solvents, whereas weak emission was observed in polar solvents, like methanol, dimethylformamide and dioxane/water 1/1 (0.001 < Q < 0.072). A significant increase in Stokes shifts and in quantum efficiencies was noted as a result of increasing polarity of dioxane/water mixtures, indicating specific interactions with polar water molecules. The emission was promoted at acidic pH values where a pyridinium cation was formed (0.061 < Q < 0.519, in dioxane/water 1/1 at pH 3.4). Compound 5, which was a tautomeric mixture of enoiimine and cyclic diamine in all solvents, was fluorescent in polar as well as in non-polar media. The quantum efficiency varied dependent on the solvent and pH (0.023 <Q< 0.435). The cyclic diamine, i. e. the more rigid structure was supposed to be responsible for the fluorescence in non-polar and aprotic solvents as well as at neutral, and weakly basic pH values. 相似文献
996.
Abstract The emission spectra of isotopic BeO molecules as excited in low-pressure arc have been photographed in the region 300–350 nm at medium dispersion. The bands have been assigned to the c3II ? a3II system. The vibrational numbering was obtained from a study of the vibrational isotope effect. Vibrational constants for involved states are derived from least-squares fits of the measured bandhead wavenumbers. 相似文献
997.
Nenad Velisavljevic & Yogesh K. Vohra 《高压研究》2013,33(2):295-302
It is generally observed that the rare earth metals adapt an orthorhombic alpha-uranium (α-U) structure at high pressures following the delocalization of 4f shell under compression. We examine the stability of the α-U structure in praseodymium metal at ultrahigh pressures of 313 GPa (volume compression V/V 0?=?0.343) in a diamond anvil cell at room temperature. X-ray diffraction data show a transformation from the α-U structure to a primitive orthorhombic P212121 phase at 147±5 GPa, which is characterized by the anisotropic compressibility of various crystallographic axes. This anisotropic compressibility leads to an interesting situation when the b-axis and the c-axis of the orthorhombic phase become nearly equal above 260 GPa and the structure can be regarded as a pseudo-tetragonal phase. Our present study shows that the 4f band metal Pr does not adapt a body centred tetragonal phase as predicted by theory, but instead novel crystallographic phases are observed at extreme compressions. The present results have a broader impact on the stability of the α-U phase in a variety of f-band systems at high pressures. 相似文献
998.
M. Maćkowiak 《高压研究》2013,33(1-6):499-501
Abstract A variational correlated ground state wave-function theory is applied to investigate the high-pressure deformation of hydrogen-bond potential described by a double Morse potential functions. The evolution of the hydrogen bond potential with increasing pressure and the effects of deuterium isotope substitution on the quantum-fluctuation-driven phenomena are discussed. The theory was employed for predicting and interpreting the pressure dependence of the phase transition temperatue for KDP-like ferroelectrics and NQR-frequency coefficients for several deuterated and undeuterated crystals. 相似文献
999.
Vladan Čelebonović 《高压研究》2013,33(1-6):693-695
Abstract Using the mass and radius of Uranus, as determined by Voyager, and a particular semiclassical theory of dense matter, a model of its interior has been developed. Details of the model, the underlying theory and possible sources of discrepancies with recent work on this topic are briefly presented. 相似文献
1000.
用一维粒子模拟程序对功率密度在1022 W/cm2以上的超强激光驱动薄膜靶产生的相对论电子层及其经过汤姆孙散射产生的阿秒X射线进行了研究. 结果表明, 在超相对论强度范围下增大驱动激光强度, 相应减小等离子体密度及厚度可使电子层获得更高纵向动量, 使汤姆孙散射光明显向更短波长移动. 优化相关参数得到了波长为 1.168 nm的阿秒脉冲. 经过对倍频探测光方案与驱动光以及薄膜靶参数进行综合考虑和优化, 得到的X射线相干辐射波长有效减小到0.4 nm以下, 产生的光子能量达到2 keV以上.
关键词:
超相对论强度激光
阿秒X射线
相对论电子层
汤姆孙后向散射 相似文献