Crystal and molecular structure of N-(bicyclo[5.1.0]octa-3,5-dien-2-yl)phthalimide, C16H13NO2

Single crystal X-ray diffraction analysis of the title compound revealed that the phthalimide substituent was endo with respect to the bicyclic ring system.     

On the characteristic map of finite unitary groups

In his classic book on symmetric functions, Macdonald describes a remarkable result by Green relating the character theory of the finite general linear group to transition matrices between bases of symmetric functions. This connection allows one to analyze the character theory of the general linear group via symmetric group combinatorics. Using works of Ennola, Kawanaka, Lusztig and Srinivasan, this paper describes the analogous setting for the finite unitary group. In particular, we explain the connection between Deligne–Lusztig theory and Ennola's efforts to generalize Green's work, and from this we deduce various character theoretic results. Applications include calculating certain sums of character degrees, and giving a model of Deligne–Lusztig type for the finite unitary group, which parallels results of Klyachko and Inglis and Saxl for the finite general linear group.     

Isotopologue fractionation during N2O production by fungal denitrification

Identifying the importance of fungi to nitrous oxide (N₂O) production requires a non‐intrusive method for differentiating between fungal and bacterial N₂O production such as natural abundance stable isotopes. We compare the isotopologue composition of N₂O produced during nitrite reduction by the fungal denitrifiers Fusarium oxysporum and Cylindrocarpon tonkinense with published data for N₂O production during bacterial nitrification and denitrification. The fractionation factors for bulk nitrogen isotope values for fungal denitrification were in the range −74.7 to −6.6‰. There was an inverse relationship between the absolute value of the fractionation factors and the reaction rate constant. We interpret this in terms of variation in the relative importance of the rate constants for diffusion and enzymatic reduction in controlling the net isotope effect for N₂O production during fungal denitrification. Over the course of nitrite reduction, the δ¹⁸O values for N₂O remained constant and did not exhibit a relationship with the concentration characteristic of an isotope effect. This probably reflects isotopic exchange with water. Similar to the δ¹⁸O data, the site preference (SP; the difference in δ¹⁵N between the central and outer N atoms in N₂O) was unrelated to concentration during nitrite reduction and, therefore, has the potential to act as a conservative tracer of production from fungal denitrification. The SP values of N₂O produced by F. oxysporum and C. tonkinense were 37.1 ± 2.5‰ and 36.9 ± 2.8‰, respectively. These SP values are similar to those obtained in pure culture studies of bacterial nitrification but quite distinct from SP values for bacterial denitrification. The large magnitude of the bulk nitrogen isotope fractionation and the δ¹⁸O values associated with fungal denitrification are distinct from bacterial production pathways; thus multiple isotopologue data holds much promise for resolving bacterial and fungal production. Our work further provides insight into the role that fungal and bacterial nitric oxide reductases have in determining site preference during N₂O production. Copyright © 2008 John Wiley & Sons, Ltd.     

Reduction of N2 to ammonia and hydrazine utilizing H2 as the reductant

The trans-Fe(DMeOPrPE)2Cl2 complex (where DMeOPrPE = 1,2-bis(bis(methoxypropyl)phosphino)ethane) undergoes a series of reactions that involve the activation of both H2 and N2 to produce ammonia and hydrazine. A Leigh-type cycle was employed to achieve laboratory fixation of dinitrogen at room temperature and pressure utilizing H2 as the reductant.     

Informational masking for simultaneous nonspeech stimuli: psychometric functions for fixed and randomly mixed maskers

Sensitivity d' and response bias beta were measured as a function of target level for the detection of a 1000-Hz tone in multitone maskers using a one interval, two-alternative forced-choice (1I-2AFC) paradigm. Ten such maskers, each with eight randomly selected components in the region 200-5000 Hz, with 800-1250 Hz excluded to form a protected zone, were presented under two conditions: the fixed condition, in which the same eight-component masker is used throughout an experimental run, and the random condition, in which an eight-component masker is chosen randomly trial-to-trial from the given set of ten such maskers. Differences between the results obtained with these two conditions help characterize the listener's susceptibility to informational masking (IM). The d' results show great intersubject variability, but can be reasonably well fit by simple energy-detector models in which internal noise and filter bandwidth are used as fitting parameters. In contrast, the beta results are not well fit by these models. In addition to presentation of new data and its relation to energy-detector models, this paper provides comments on a variety of issues, problems, and research needs in the IM area.     

Synthesis of cyclopropanes via organoiron methodology: preparation and rearrangement of divinylcyclopropanes

Addition of alkenyl Grignard reagents to (1-methoxycarbonylpentadienyl)iron(1+) cation generates the corresponding (2-alkenylpent-3-en-1,5-diyl)iron complexes. Oxidatively induced-reductive elimination of these complexes gives divinylcyclopropanes which can undergo subsequent Cope rearrangement to give 1,4-cycloheptadienes.     

Envelope-onset asynchrony as a cue to voicing in initial english consonants

An acoustic cue for voicing is proposed based on the underlying processes associated with the production of the voicing contrast. This cue is based on the time asynchrony between the onsets of two amplitude-envelope signals derived from different bands of speech (i.e., envelopes derived from a lowpass-filtered band at 350 Hz and from a highpass-filtered band at 3000 Hz). Acoustic measurements made on the envelope signals of a set of 16 initial consonants represented through multiple tokens of C1VC2 syllables indicate that the onset-timing difference between the low- and high-frequency envelopes (Envelope-Onset Asynchrony or EOA) provides a reliable and robust cue for distinguishing voiced from voiceless consonants. This cue, which is simply derived in real-time, has applications to the design of sensory aids for persons with profound hearing impairments (e.g., as a supplement to lipreading), as well as to automatic speech recognition.