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121.
振动谱学研究中的光谱线型函数 总被引:3,自引:1,他引:2
本文讨论了在振动谱带计算拟合处理中的光谱线型函数问题,推导出适用于单道及多道拉曼光谱仪及色散型红外谱仪谱带线型公式。通过实验及拟合计算证实了它们的适用性并讨论了可能的误差源。理论计算和实验验证结果说明:在振动谱的谱带拟合计算中,应使用根据测谱条件计算求得的谱带线型函数,以保证拟合结果的可靠性。 相似文献
122.
123.
We investigate the propeties of differential algebras generated by an operator d satisfying the property dN = 0 instead of d2 = 0 as in the usual case. Several examples of realizations of such differential algebras are given, either in the context of ZN-graded N × N matrix algebras, or as a generalized differential calculus on manifolds. 相似文献
124.
Summary. In this paper we are interested in two phase flow problems in porous media. We use a Dual Mesh Method to discretize this
problem with finite volume schemes. In a simplified case (elliptic - hyperbolic system) we prove the convergence of approximate
solutions to the exact solutions. We use the Dual Mesh Method in physically complex problems (heterogeneous cases with non
constant total mobility). We validate numerically the Dual Mesh Method on practical examples by computing error estimates
for different test-cases.
Received March 21, 1997 / Revised version received October 13, 1997 相似文献
125.
A series of 7-amino- and polyaminosterol analogues of squalamine and trodusquemine were synthesized involving a new stereoselective titanium reductive amination reaction in high chemical yields of up to 95% in numerous cases. These derivatives were evaluated for their in vitro antimicrobial properties against human pathogens. All the compounds present excellent activities against Gram-positive bacteria exhibiting similar results against Staphylococcus aureus and Streptococcus faecalis with minimum inhibitory concentrations (MICs) varying from 2.5 to 10 μg/mL. Numerous derivatives possess also MICs against Gram-negative Escherichia coli bacteria (MICs varying from 2.5 to 10 μg/mL) suggesting that nature of the amino group attached to the sterol moiety plays an important role on the activities of such products. 相似文献
126.
In this Note we first introduce the concept of pullback asymptotic compactness. Next, we establish a result ensuring the existence of a pullback attractor for a non-autonomous dynamical system under the general assumptions of pullback asymptotic compactness and the existence of a pullback absorbing family of sets. Finally, we prove the existence of a pullback attractor for a non-autonomous 2D Navier–Stokes model in an unbounded domain, a case in which the theory of uniform attractors does not work since the non-autonomous term is quite general. To cite this article: T. Caraballo et al., C. R. Acad. Sci. Paris, Ser. I 342 (2006). 相似文献
127.
We study percolation in the following random environment: let Z be a Poisson process of constant intensity on ℝ2, and form the Voronoi tessellation of ℝ2 with respect to Z. Colour each Voronoi cell black with probability p, independently of the other cells. We show that the critical probability is 1/2. More precisely, if p>1/2 then the union of the black cells contains an infinite component with probability 1, while if p<1/2 then the distribution of the size of the component of black cells containing a given point decays exponentially. These
results are analogous to Kesten's results for bond percolation in ℤ2.
The result corresponding to Harris' Theorem for bond percolation in ℤ2 is known: Zvavitch noted that one of the many proofs of this result can easily be adapted to the random Voronoi setting.
For Kesten's results, none of the existing proofs seems to adapt. The methods used here also give a new and very simple proof
of Kesten's Theorem for ℤ2; we hope they will be applicable in other contexts as well.
Research supported in part by NSF grant ITR 0225610 and DARPA grant F33615-01-C-1900
Research partially undertaken during a visit to the Forschungsinstitut für Mathematik, ETH Zürich, Switzerland 相似文献
128.
A. Cerdán Vidal A. R. Maurí Aucejo M. Llobat Estellés C. Pascual Martí J. Simeón Martí 《Fresenius' Journal of Analytical Chemistry》1994,350(12):706-711
The possibility of identification of substances which have similar spectral behaviour by means of Apparent Content Curves has been studied. This study is carried out with absorption, excitation and emission spectra of several amphetamines of widespread pharmaceutical use. Results obtained show that amphetamine, phenylpropanolamine, pseudoephedrine, phenylephrine, epinephrine, dopamine and methoxyamphetamine can be identified with a probability of >95%. 相似文献
129.
B. Hornetz H.-J. Michel J. Halbritter 《Fresenius' Journal of Analytical Chemistry》1994,349(1-3):233-235
ARXPS (angle resolved X-ray photoelectron spectroscopy) measurements are used to obtain informations about surfaces and grain boundaries. Data acquired from nanocrystalline carbidic hard coatings have been employed to establish structural models. Magnetron-sputtered coatings of TiC, SiC and TiC/SiC were examined. In such coatings, partly defective TiC nanocrystallites are surrounded by interfacial carbide. This excess carbon shows a binding state similar to that of doped graphite or fullerenes. X-ray amorphous SiC is found in the residue. On top of sputtered SiC coatings, less oxide and graphite is found as compared to TiC/SiC or TiC coatings. 相似文献
130.
W. D. Hoffmann D. Michel I. G. Sorina E. V. Charnaya 《Physics of the Solid State》1998,40(8):1288-1289
The shift in the nuclear magnetic resonance (NMR) line of 71Ga isotopes in GaAs crystals is investigated in the temperature range 160–360 K. It is observed that the position of the resonance
line is temperature-independent. The value of the shift relative to an isolated nucleus is 440 and 420 ppm for the three samples
investigated. The roles of various contributions to the NMR line shift are discussed.
Fiz. Tverd. Tela (St. Petersburg) 40, 1418–1419 (August 1998) 相似文献