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981.
An expression is obtained for the reflection coefficient of circularly polarized light normally incident on the film of a cholesteric liquid crystal with a variable helix pitch. It is shown that, in the case of a single defect (local change in the helix pitch), the spectrum of light reflection from a cholesteric acquires a dip corresponding to the defect mode. New qualitative features appear in the reflection spectrum of a cholesteric with two defects as the distance between them varies. 相似文献
982.
983.
Mathematical Notes - 相似文献
984.
985.
Isabel Brandariz José L. Barriada Teresa Vilari?o Manuel E. Sastre de Vicente 《Monatshefte für Chemie / Chemical Monthly》2004,343(6):1475-1488
Several reported procedures for calibrating glass electrodes in proton concentration are compared. Some recommendations for non-experts are also given. The examined procedures can be classified into two broad categories, namely: those based on direct potential difference measurements of solutions of known proton concentration and those that use one or several pH standards to calibrate the electrode and subsequently measure the pH of solutions containing known proton concentrations. With a single buffer, the two types of procedures lead to equivalent results. However, if two pH buffers are used, the slope of the calibration graph in proton concentration will differ from the real electrode slope to an extent proportional to the difference between the liquid junction potentials of the two buffers. Therefore, any other method is preferable under these circumstances. 相似文献
986.
Gatiyatullina G. V. Battalov E. M. Voloshin A. I. Prochukhan Yu. A. 《Russian Journal of Applied Chemistry》2003,76(4):626-628
Luminophores, 4,4'-diaminodiphenylmethane and Oxazine-17, were introduced into a photopolymerizable formulation based on an epoxy-acrylate oligomer, and their behavior in thin-film polymerization was studied. 相似文献
987.
V. V. Kuznetsov Yu. V. Ermolenko A. Ya. Zheltov K. A. Kornev S. V. Sheremet'ev 《Journal of Analytical Chemistry》2004,59(1):17-22
The coprecipitation of azo compounds based on 4-nitrophenyl- and 4-sulfophenyldiazonium naphthol sulfonates as their diphenylguanidinium ion-pair complexes with analogous compounds of naphthalene-2-sulfonic acid and 4-phenylsulfodiazonium is investigated. The optimization of the coprecipitation is considered based on the notions of the driving force of the cocrystallization of impurities. The optical characteristics of colored ion-pair complexes are measured. It is found that the water solubility is decreased most substantially for azosulfonates with hydrophobic nitro groups and with no more than two sulfo groups in different aromatic nuclei, which can lead to a decrease in the detection limit due to preconcentration by coprecipitation, which stimulates the thermodynamic flux of concentrate elution. Coprecipitation is combined with flow-injection analysis in the on-line mode, and new procedures are developed for determining naphthol sulfonates and related azo compounds with the detection limit equal to 0.003–0.006 mg/50 mL. 相似文献
988.
989.
Synthesis of Protein A Conjugates with Silver Nanoparticles 总被引:1,自引:0,他引:1
The single-stage synthesis of the conjugates of protein A with silver nanoparticles is performed. The dependence of the dispersity of the prepared sols on the composition of reaction mixture is investigated by optical spectroscopy and transmission electron microscopy. The relative stability of the obtained preparations with respect to the coagulation by NaCl is estimated. 相似文献
990.