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排序方式: 共有212条查询结果,搜索用时 359 毫秒
61.
62.
Matej Rkoš 《Czechoslovak Journal of Physics》1957,7(4):495-502
Zusammenfassung Es wird ein auf der integrierten Gleichung der Kraft, mit der ein unhomogenes Feld auf die Probe einwirkt, beruhender Apparat zur Messung der Suszeptibilität schwach magnetischer Stoffe beschrieben. Die Kraftwirkungen werden in elektrische Wirkungen übergeführt, die elektronisch gemessen werden. 相似文献
63.
Matej Pavšič 《International Journal of Theoretical Physics》1975,14(5):299-311
If we assume that scale is a degree of freedom which a physical object, such as a galaxy possesses besides translational and rotational degrees of freedom, we are able to incorporate such diverse phenomena as the systematic cosmological red-shifts, anomalous red-shifts, controversals of quasars, and the expansion of Earth into a single theory. At the same time we can consider the proposed existence of active dilatation as a physical realization of conformal transformations. Active conformal transformations transform the rest masses of particles. The objection that this implies a continuous rest mass spectrum which is not observed is avoided by assuming that particles can form bound systems such as nuclei, atoms, crystals, galaxies, etc., only if ‘discrete’ scale relations are established among the constituent particles. Different galaxies can be dilated relative to each other. (Note the analogy with ‘discrete’ positions of atoms in a crystal. Different crystals can be translated arbitrarily each to the other.) An observer in a contracting galaxy experiences that the universe is expanding. 相似文献
64.
Matej Kordoš 《Journal of Mathematical Analysis and Applications》2004,298(2):655-666
We consider the system
65.
Lucija Peterlin‐Mai
Mateja Malei
Matej Breznik Ale Krbav
i
《Journal of heterocyclic chemistry》2000,37(1):95-101
5‐Oxo‐5H‐[1,3]thiazolo[3,2‐a]pyrimidine‐6‐carboxylic acid ( 4 ), and 6‐methylimidazo[2,1‐b]thiazole‐5‐carboxylic acid ( 17 ) were reacted with amines 6a‐i by the reaction with oxalyl chloride and N, N‐di methyl‐formamide as a catalyst into primary and secondary amide derivatives 7‐14 and 19‐22. From compound 24 N,N'‐disubstituted ureas 26, 27 and perhydroimidazo[1,5‐c]thiazole 29 derivatives of imidazo[2,1‐b]thiazole were prepared. By nmr analysis of compound 29 , the existence of two stereoisomers resulting from both optical, due to centre of chirality at C7′a, and conformational isomerism, due to restricted C5? N6′ bond rotation were proved. 相似文献
66.
Prof. Peter Baláž Dr. Erika Dutková Dr. Matej Baláž Dr. Róbert Džunda Dr. Jiří Navrátil Dr. Karel Knížek Dr. Petr Levinský Dr. Jiří Hejtmánek 《ChemistryOpen》2021,10(8):806-814
Chalcopyrite CuFeS2, a semiconductor with applications in chemical sector and energy conversion engineering, was synthetized in a planetary mill from elemental precursors. The synthesis is environmentally friendly, waste-free and inexpensive. The synthesized nano-powders were characterized by XRD, SEM, EDX, BET and UV/Vis techniques, tests of chemical reactivity and, namely, thermoelectric performance of sintered ceramics followed. The crystallite size of ∼13 nm and the strain of ∼17 were calculated for CuFeS2 powders milled for 60, 120, 180 and 240 min, respectively. The evolution of characteristic band gaps, Eg, and the rate constant of leaching, k, of nano-powders are corroborated by the universal evolution of the parameter SBET/X (SBET-specific surface area, X-crystallinity) introduced for complex characterization of mechanochemically activated solids in various fields such as chemical engineering and/or energy conversion. The focus on non-doped semiconducting CuFeS2 enabled to assess the role of impurities, which critically and often negatively influence the thermoelectric properties. 相似文献
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D‐Glucosamine in iron‐catalysed cross‐coupling reactions of Grignards with allylic and vinylic bromides: application to the synthesis of a key sitagliptin precursor
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A sustainable D ‐glucosamine ligand is successfully introduced into iron‐catalysed C ? C cross‐coupling reactions for the first time. The Fe(acac)2/D ‐glucosamine·HCl/Et3N catalytic system was effective at 5 mol% loading in coupling reactions of Grignard reagents with organic bromides. Moderate to high efficiency was achieved with preserved stereochemistry when allyl (Csp3) or alkenyl (Csp2) bromides were coupled with phenylmagnesium (Csp2) or benzylmagnesium (Csp3) bromides. The catalytic system developed was also successfully applied for the novel and economic preparation of a Michael‐acceptor‐like starting material used in an alternative synthesis of the drug sitagliptin, a known blockbuster for the treatment of type II diabetes mellitus. Copyright © 2015 John Wiley & Sons, Ltd. 相似文献
70.
Paweł Wyżga Igor Veremchuk Matej Bobnar Christoph Hennig Andreas Leithe-Jasper Roman Gumeniuk 《无机化学与普通化学杂志》2020,646(14):1091-1098
A combined structural, magnetic and thermoelectric study of polycrystalline ternary MIn2S4 (M = Mn, Fe, Co, Ni) thiospinels is presented. All compounds crystallize with MgAl2O4-type structure. Rietveld refinement analysis confirmed that the preferred crystallographic position of transition metal element changes from mainly tetrahedral 8a for Mn to exclusively octahedral 16d for Ni (i.e. increase of the inversion parameter). Magnetic susceptibility measurements revealed M-elements to possess 2+ oxidation state in MIn2S4. All these compounds order antiferromagnetically with Néel temperatures TN ranging from 5–13 K. The studied thiospinels are n-type semiconductors with large values of electrical resistivity ρ > 0.6 Ω · m at room temperature. An increase of the inversion parameter leads to a reduction of the determined activation energies, as well as to a more disorder-like behavior of thermal conductivity. The highest thermoelectric Figure of merit ZT was observed for MIn2S4 with M = Fe, Ni, which adopt inverse spinel structure. 相似文献