Measurement of the polarization for the reactions K+n → K+n and K0p at 1.06, 1.28, 1.39 and 1.49 GeV/c

The polarization for the K⁺n elastic and charge-exchange reactions was measured at the momenta of 1.06, 1.28, 1.39 and 1.49 GeV/c. It was found to be negative for the K⁺n elastic process and generally positive for the charge-exchange process. The present results are compared with the predictions of phase shift analyses.     

X-ray compressibility measurements of the graphite intercalates KC8 and KC24

The isothermal compressibilities of pristine graphite and stages 1 and 2 potassium-graphite have been measured at room temperature. Diamond anvil X-ray diffraction techniques were employed to determine the c-axis lattice constant as a function of hydrostatic pressure up to 12 kbar. The compressibilities $\text{k}{}_{\mathrm{c}}\text{?}\text{1}\text{C}{}_{33}$ were found to be (2.73±0.09)×10^-12, (2.13±0.09)×10^-12, (5.3±0.8)×10^-12 and $\text{(1.6±0.2)×10}{}^{-12}\text{cm}{}^2\text{dyn}$ for graphite, KC₈, stage 2 KC₂₄ and stage 3 KC₂₄, respectively. The compressibility of KC₈ was comparable to that of RbC₈ deduced from neutron scattering experiments.     

Enantiomer-selective membrane electrode for amino acid methyl esters

Polymeric membrane electrodes based on the chiral crown ether, 2,3:4,5-bis-[1,2-(3-phenylnaphtho)]-1,6,9,12,15,18-hexaoxacycloeicosa-2,4-diene, were prepared, and their characteristics were examined. The electrodes showed good enantiomer-selectivity for many amino acid methylesters, the enantiomer-selective factor reaching the high value of 13 for phenylglycine methyl ester. The electrodes responded preferably to the enantiomer forming the more stable complex with the crown ether. The electrodes proved useful for determining the concentrations of each enantiomer. The calculated concentrations from the potential changes of the electrodes were in good agreement with the predicted ones.     

Effects of polymerization and hydrolysis degrees of poly(vinyl alcohol) (PVA) on the efficiency of the PVA-solid substrate for room-temperature phosphorimetry.

Several kinds of poly(vinyl alcohols) (PVAs) having different degrees of polymerization and hydrolysis were tested as a material of a solid substrate for room-temperature phosphorimetry (RTP). Effects of these differences on the efficiency of the solid substrate were investigated. Completely hydrolyzed PVAs acquired a luminescence property in the grinding process of substrate preparation, but partially hydrolyzed PVAs did not acquire this property. When the completely hydrolyzed PVA substrates were prepared by drying their aqueous solutions, their luminescence property almost disappeared. However, very weak background emission remained on the surface of a completely dried substrate which had been treated with an analyte aqueous solution. This residual background affected the spectrum of the analyte, especially at low concentrations. Stability of the phosphorescence intensity with the passage of time was superior on the partially hydrolyzed PVAs than on the completely hydrolyzed PVAs. On the other hand, the RTP intensity and reproducibility were superior on the completely hydrolyzed PVAs. Practically, partially hydrolyzed PVAs were more suitable as a material of the substrate because of the stability of its RTP intensity and the weakness of its background emission. The linear dynamic range of the analytical curve for p-aminobenzoic acid on the substrate of partially hydrolyzed PVA having a degree of polymerization of 3,500 was 5-2,000 pmol/spot (20 microL) and its correlation coefficient was 0.963 for 30 data points.     

Effect of crystallization and liquid–liquid phase separation on phase‐separation kinetics in poly(ethylene‐co‐vinyl alcohol)/glycerol solution

Liquid–liquid thermally induced phase separation of the polymer‐diluent system of poly(ethylene‐co‐vinyl alcohol) (EVOH)‐glycerol was examined under light scattering. For EVOH with an ethylene content of 38 mol % (EVOH38), maxima of the scattered light intensity were observed that indicated that phase separation occurred by the spinodal decomposition (SD). The growth of the structures formed by the general liquid–liquid phase separation obeyed a power‐law scaling relationship in SD. For EVOH with an ethylene content of 32 mol % (EVOH32), the liquid–liquid phase separation resulted from the polymer crystallization. In this case, the structure growth showed the characteristic behavior in which the crystalline particles were initially formed, and then the droplets formed by the liquid–liquid phase separation induced by the crystallization grew rapidly. Furthermore, the growth of the droplet by the phase separation was followed by an optical microscope measurement at a constant cooling rate. The phase‐separated structure formed after the crystallization can grow faster than that formed by the normal liquid–liquid phase separation. © 2002 Wiley Periodicals, Inc. J Polym Sci Part B: Polym Phys 41: 194–201, 2003     

Radiative pion capture in 12C and 16O

Radiative pion capture in ¹²C and ¹⁶O is investigated. An effective interaction Hamiltonian based upon the CGLN theory is employed. Capture rates in ¹²C and ¹⁶O from Is and 2p pionic orbits are calculated by using the nuclear model of Kamimura, Ikeda and Arima for the odd parity states of ¹²C, and that of Walker with strong ground state correlations, for the odd parity states of ¹⁶O. The results are compared with those of the 1p-1h nuclear model under the Tamm-Dancoff and random phase approximations of Gillet and Vinh Mau. Detailed examinations are made for the transitions to low-lying states with 1⁺ and 2⁺ for ¹²C and with 1^?, 2^? and 3^? for ¹⁶O by using the Cohen-Kurath and the Walker models, respectively. The results are in good agreement with the recent experimental data from Berkeley.