Antioxidants and stabilizers: Part IC—Hydroperoxide deactivation by aliphatic sulfides. A model study

The hydroperoxide decomposing efficiencies of dioctadecylsulfide (I), dioctadecyldisulfide (IV) and dioctadecyl 3,3-thio-dipropionate (VII) have been compared at 75°C and 85°C. The formation of oxidation products from (I) and (IV) has been checked. Experimental evidence is given of the important rôle of the activation of the molecule of (IV) by the presence of two sulfidic sulfur atoms compared with the activation of the sulfur atom in (VII) by the alkoxycarbonyl group in the beta position. The explanation of the high efficiency of disulfide has been based on the formation of thiosulfinate—the key intermediate for the generation of peroxidolytic species—in the first reaction step.     

Some radiation protection problems connected with the use of186Re-HEDP and153Sm-EDTMP for palliative therapy of bone metastases

The paper deals with the problem of the outpatient administration of¹⁸⁶Re-HEDP and¹⁵³Sm-EDTMP for palliative therapy of bone metastases. The subsequent 6 hours stay of the treated patients in a department of nuclear medicine appears to be in compliance with regulations proposed in the Czech Republic as well as with ICRP recommendations.     

A Safe Way of Performing Some Dangerous Experiments. II. Construction of a Safety Dropper

Due to the high safety risks, chemistry instructors avoid demonstrating many remarkable experiments based on the addition of a liquid to a solid. Well-known examples of such demonstrations are various pyrotechnic mixtures of potassium chlorate and sugar (sucrose), which are usually activated with a drop of concentrated sulfuric acid. Other attractive demonstrations are the addition of water to freshly prepared magnesium phosphide and addition of water to burning magnesium. In all of these demonstrations the reaction that takes place immediately is very vigorous and can be hazardous for the instructor. Because chemistry teachers and instructors usually try to avoid performing experiments that include a hazard, a number of highly attractive experiments may remain unknown to the public. Using a simple homemade device called a safety dropper, one can perform all of these experiments with complete safety, both for the audience and the demonstrator. Details for performing some of these experiments as well as for the construction of the safety dropper are given in this paper. Video clips of demonstrations are included as an aid for inexperienced instructors.     

Heterocyclic diazo compounds as starting materials in organic synthesis (review)

Data on the structures and reactions of heterocyclic diazo compounds that lead to the formation of new heterocyclic systems as a result of intra- or intermolecular cyclization and rearrangements are systematized.Translated from Khimiya Geterotsiklicheskikh Soedinenii, No. 5, pp. 579–603, May, 1980.     

Electrocatalysis by foreign metal monolayers: Oxidation of formic acid on platinum

It was demonstrated that some foreign metal monolayers formed by underpotential deposition have pronounced catalytic effects on the oxidation of formic acid on platinum. The explanation of these effects was sought within the framewor of existing data on the formic acid oxidation and the underpotential deposition. It was found that the catalytic effect of foreign metal monolayers originates in the decrease of hydrogen adsorption thus preventing the formation of the main poisoning species COH. At the same time these experiments confirm the previously postulated mechanism of formation of the poisoning species involving adsorbed hydrogen.     

Mesoporous electrode material from alumina-stabilized anatase TiO2 for lithium ion batteries

A mesoporous electrode material whose structure is composed of anatase nanocrystals stabilized by alumina is reported. Powder X-ray diffraction shows the anatase phase only, but micro-Raman spectroscopy shows that the materials have a core-shell morphology with grains of bulk anatase covered by a thin rutile layer on the surface. This structure is unique when compared to analogous materials stabilized by zirconia (PNNL-1). Nitrogen adsorption isotherms demonstrate a monotonous increase in surface area and mesopore volume with increasing Al content. Thin film electrodes from these materials were characterized by lithium insertion electrochemistry. Cyclic voltammograms exhibit significant differences in Li accommodation in Al-free and Al-stabilized materials.     

Sensitive stripping voltammetry of heavy metals by using a composite sensor based on a built-in bismuth precursor

A new graphite-epoxy composite electrode (GECE) containing Bi(NO(3))(3) as a built-in bismuth precursor for simultaneous and individual anodic stripping analysis of heavy trace metals like lead and cadmium is reported. The developed Bi(NO(3))(3)-GECE is compatible with bismuth film electrodes reported previously including the composite electrodes (Bi-GECE) recently reported by our group. Bi(NO(3))(3)-GECE displays the ability for the detection of both individual and simultaneous determination of heavy trace metals and exhibits well defined, reproducible and sharp stripping signals. The sensitive response is combined with the minimal toxicity of Bi(NO(3))(3). This novel sensor would be an appropriate alternative tool to sensors using bismuth in solution during their utilization in environmental quality monitoring as well as other applications.     

Lifetime prediction of ABS polymers based on thermoanalytical data

The service life of ABS polymer, stabilized by 2-(3,5-di-tert-butyl-4-hydroxyanilino)-4,6-bis(octylthio)-1,3,5-triazine and containing 50% of a modifying rubber component, was estimated from oxidative induction times measured by DSC in isothermal mode in the temperature interval 140–170°C. The lifetime of ABS powder at the actual temperature of drying was predicted by linear extrapolation according to Arrhenius. However, the extrapolated value was much longer than the real lifetime determined from the long-term oven aging tests at 70 and 90°C, simulating the industrial drying process. The effect of changes in the apparent activation energy of oxidation due to antioxidant consumption during polymer aging is discussed.     

Optimization of the TLC Separation of Seven Amino Acids

JPC – Journal of Planar Chromatography – Modern TLC - A ternary mobile phase for thin-layer chromatographic separation and identification of seven amino acids on microcrystalline...