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71.
The lifetime of electrostatically trapped indirect excitons in a field-effect structure based on coupled AlGaN/GaN quantum wells has been theoretically studied. Within the plane of a double quantum well, indirect excitons are trapped between the surfaces of the AlGaN/GaN heterostructures and a semitransparent metallic top gate. The trapping mechanism has been assumed to be a combination of the quantum confined Stark effect and local field enhancement. In order to study the trapped exciton lifetime, the binding energy of indirect excitons in coupled quantum wells is calculated by finite difference method in the presence of an electric field. Thus, the lifetime of trapped excitons is computed as a function of well width, AlGaN barrier width, the position of double quantum well in the device and applied voltage. 相似文献
72.
Strong, surprising, and multifaceted effects of the width of the external surface layer Δ(ξ) and internal stresses on surface-induced pretransformation and phase transformations (PTs) are revealed. Using our further developed phase-field approach, we found that above some critical Δ(ξ)(*), a morphological transition from fully transformed layer to lack of surface pretransformation occurs for any transformation strain ε(t). It corresponds to a sharp transition to the universal (independent of ε(t)), strongly increasing the master relationship of the critical thermodynamic driving force for PT X(c) on Δ(ξ). For large ε(t), with increasing Δ(ξ), X(c) unexpectedly decreases, oscillates, and then becomes independent of ε(t). Oscillations are caused by morphological transitions of fully transformed surface nanostructure. A similar approach can be developed for internal surfaces (grain boundaries) and for various types of PTs and chemical reactions. 相似文献
73.
In this paper, we study the polynomial integrability of natural Hamiltonian systems with two degrees of freedom having a homogeneous potential of degree k given either by a polynomial, or by an inverse of a polynomial. For k=−2,−1,…,3,4, their polynomial integrability has been characterized. Here, we have two main results. First, we characterize the polynomial integrability of those Hamiltonian systems with homogeneous potential of degree −3. Second, we extend a relation between the nontrivial eigenvalues of the Hessian of the potential calculated at a Darboux point to a family of Hamiltonian systems with potentials given by an inverse of a homogeneous polynomial. This relation was known for such Hamiltonian systems with homogeneous polynomial potentials. Finally, we present three open problems related with the polynomial integrability of Hamiltonian systems with a rational potential. 相似文献
74.
We present two linearization-based algorithms for mixed-integer nonlinear programs (MINLPs) having a convex continuous relaxation. The key feature of these algorithms is that, in contrast to most existing linearization-based algorithms for convex MINLPs, they do not require the continuous relaxation to be defined by convex nonlinear functions. For example, these algorithms can solve to global optimality MINLPs with constraints defined by quasiconvex functions. The first algorithm is a slightly modified version of the LP/NLP-based branch-and-bouund \((\text{ LP/NLP-BB })\) algorithm of Quesada and Grossmann, and is closely related to an algorithm recently proposed by Bonami et al. (Math Program 119:331–352, 2009). The second algorithm is a hybrid between this algorithm and nonlinear programming based branch-and-bound. Computational experiments indicate that the modified LP/NLP-BB method has comparable performance to LP/NLP-BB on instances defined by convex functions. Thus, this algorithm has the potential to solve a wider class of MINLP instances without sacrificing performance. 相似文献
75.
Laura Parejo Dr. Mahdi Chaari Sara Santiago Dr. Gonzalo Guirado Prof. Francesc Teixidor Dr. Rosario Núñez Dr. Jordi Hernando 《Chemistry (Weinheim an der Bergstrasse, Germany)》2021,27(1):270-280
Icosahedral metallacarboranes are θ-shaped anionic molecules in which two icosahedra share one vertex that is a metal center. The most remarkable of these compounds is the anionic cobalt-based metallacarborane [Co(C2B9H11)2]−, whose oxidation-reduction processes occur via an outer sphere electron process. This, along with its low density negative charge, makes [Co(C2B9H11)2]− very appealing to participate in electron-transfer processes. In this work, [Co(C2B9H11)2]− is tethered to a perylenediimide dye to produce the first examples of switchable luminescent molecules and materials based on metallacarboranes. In particular, the electronic communication of [Co(C2B9H11)2]− with the appended chromophore unit in these compounds can be regulated upon application of redox stimuli, which allows the reversible modulation of the emitted fluorescence. As such, they behave as electrochemically-controlled fluorescent molecular switches in solution, which surpass the performance of previous systems based on conjugates of perylendiimides with ferrocene. Remarkably, they can form gels by treatment with appropriate mixtures of organic solvents, which result from the self-assembly of the cobaltabisdicarbollide-perylendiimide conjugates into 1D nanostructures. The interplay between dye π-stacking and metallacarborane electronic and steric interactions ultimately governs the supramolecular arrangement in these materials, which for one of the compounds prepared allows preserving the luminescent behavior in the gel state. 相似文献
76.
In this article, the depth‐averaged transport equations are written in a new way so that it is possible to solve the transport equations for very small water depths. Variables are interpolated into the cell face with two different schemes and, the schemes are compared in terms of computational cost and accuracy. The bed source terms are computed using two different assumptions. The effect of these assumptions on numerical simulations is then investigated. Solutions of transport equations on different types of unstructured triangular grids are compared and, an appropriate choice of grid is suggested. Copyright © 2011 John Wiley & Sons, Ltd. 相似文献
77.
This presented study is to make comparison of cross sections to produce 117Sb and 90Nb via different reactions with particle incident energy up to 70 MeV as a part of systematic studies on particle-induced activations on enriched Sn, Y2O3 and ZrO2 targets, theoretical calculation of production yield, calculation of required thickness of target and suggestion of optimum reaction to produce Antimony-117 and Niobium-90. 相似文献
78.
79.
Hossein Mahdavi Mahdi Sadeghzadeh B. O. 《Journal of Polymer Science.Polymer Physics》2010,48(3):356-363
Coil‐globule transition of poly(N‐tert‐butylacrylamide‐co‐acrylamide) P(NTBAM‐co‐AM) copolymers is investigated in the aqueous solution and in the mixture of water–methanol by micro ATR‐FTIR spectroscopy technique. In this study the microstructure and its changes in the hydration states of the distinct groups of these copolymers are investigated by micro ATR/FTIR technique. The results showed that by heating the solution above the LCST hydrogen bonding between C?O and water was decreased but the hydrogen bonding between polymeric chains increased, which prove the aggregation of polymer chain during phase separation. The chemical shifts of IR bands are also studied in the mixture of water–methanol. © 2009 Wiley Periodicals, Inc. J Polym Sci Part B: Polym Phys 48: 356–363, 2010 相似文献
80.
Giovanni Borghi Marco Polini Reza Asgari A.H. MacDonald 《Solid State Communications》2009,149(27-28):1117-1122
In single-layer graphene sheets non-local interband exchange leads to a renormalized Fermi-surface effective mass which vanishes in the low carrier-density limit. We report on a comparative study of Fermi surface effective mass renormalization in single-layer and AB-stacked bilayer graphene. We explain why the mass does not approach zero in the bilayer case, although its value is still strongly suppressed. 相似文献