高抗冲聚丙烯序列结构的综合表征

用高分辨＾１３Ｃ ＮＭＲ、ＦＴＩＲ等手段获得了高抗冲聚丙烯的组成和序列分布等链结构方面的信息。用ＤＳＣ、ＷＡＸＤ等方法研究了它们的结晶行为、熔融转变及晶体结构，多种方法相结合有效地表征了高抗冲聚丙烯的序列结构。     

质量控制图原理在股票投资组合中的应用研究

质量控制图是用来控制生产过程质量的一种统计方法。其基本理论方法应用到股票投资组合中,可以降低投资风险,提高投资组合的收益率。通过实证研究表明:利用质量控制图原理来确定投资组合的选股、买点和卖点,可以使投资组合获得明显高于大盘指数的收益率,从而验证了质量控制图的基本理论方法完全可以应用于股票投资决策,并且具有显著的实际应用价值。     

三维内肋管内插入螺旋扭带的强化传热实验

本文分别以水和乙二醇为工质，在Ｒｅ数范围为：６００～４００００，Ｐｒ数范围为：５．５～１１０之间，对四根分别插入三种不同扭率螺旋扭带的三维内助管内的换热和流阻特性进行了实验研究。结果表明：三维内肋管内加装扭带的强化传热技术适用于低Ｒｅ数下高Ｐｒ数工质的管内对流换热强化。根据实验值得到了流阻和换热关联式。     

LD泵浦Nd：BGO晶体的自调Q激光器

首次实现了ＬＫ泵浦Ｎｄ∶ＢＧＯ固体激光器的１．０６４μｍ的激光输出，泵浦阈值功率为２５ｍＷ，在连续运转状态下得到最大为４０ｍＷ的ＴＥＭ００模输出，光－光效率为１３．３％，根据法拉第磁光效庆理论，了ＬＤ泵浦Ｎｄ∶ＢＧＯ自调Ｑ激光器的各种参数，并研制成该激光器，在该器件中，作为损耗调制元件的磁光调制器就是绕有线圈的Ｎｄ∶ＢＧＯ晶体本身，实验在重复率为１ＫＨｚ的条件下得到了ＦＷＨＭ为１００ｎｓ的稳定脉冲     

灰色Verhulst模型的样条插值函数的残差修正

本用样条函数对灰色Verhulst模型的残差序列进行插值拟合，然后作用于二阶线性微分方程，并以此修正原模型，得到一种新的预测模型的数值解，提高了拟合的精确度。     

同输入M/M/∞排队群的联合队长过程

本提出一个偏微分方程方法，用这一方法研究同输入M/M／∞排队群中的联合队长分布。在任意初始条件下，给出了瞬时联合队长分布的多元母函数，也讨论了稳态队长的联合分布及各排队系统之间的相关性。     

二阶椭圆型微分方程解的振动定理

考虑二阶非线性椭圆型微分方程∑^n_{i,j}∂/∂x_i{A_{i,j}(x,y)∂/∂x_j}+q(x)f(y)=0 (E)，其中q(x)在外区域 Ω∈R\+n上变号. 利用偏Riccati变换和积分平均技巧, 建立了方程(E)所有解振动的充分准则.     

关于自双反函数的性质之研究

阐述了双反函数、自双反函数和多数函数的定义,提出了自双反函数的性质.根据上述定义利用布尔代数中的基本概念、定理和公式证明了这些性质,展示了自双反函数在RM展开系数图(bj图)中的特点,讨论了自双反函数在函数分类中的应用.     

Formation of β‐iPP in isotactic polypropylene/ethylene–propylene rubber blends: Effects of preparation method,composition, and thermal condition

The effects of preparation method, composition, and thermal condition on formation of β‐iPP in isotactic polypropylene/ethylene–propylene rubber (iPP/EPR) blends were studied using modulated differential scanning calorimeter (MDSC), wide angle X‐ray diffraction (WAXD), and phase contrast microscopy (PCM). It was found that the α‐iPP and β‐iPP can simultaneity form in the melt‐blended samples, whereas only α‐iPP exists in the solution‐blended samples. The results show that the formation of β‐iPP in the melt‐blended samples is related to the crystallization temperature and the β‐iPP generally diminishes and finally vanishes when the crystallization temperature moves far from 125 °C. The phenomena that the lower critical temperature of β‐iPP in iPP/EPR obviously increases to 114 °C and the upper critical temperature decreases to 134 °C indicate the narrowing of temperature interval, facilitating the formation of β‐iPP in iPP/EPR. Furthermore, it was found that the amount of β‐iPP in melt‐blended iPP/EPR samples is dependent on the composition and the maximum amount of β‐iPP formed when the composition of iPP/EPR blends is 85:15 in weight. The results through examining the effect of annealing for iPP/EPR samples at melt state indicate that this annealing may eliminate the susceptibility to β‐crystallization of iPP. However, only α‐iPP can be observed in solution‐blended samples subjected to annealing for different time. The PCM images demonstrate that an obvious phase‐separation happens in both melt‐blended and solution‐blended iPP/EPR samples, implying that compared with the disperse degree of EPR in iPP, the preparation method plays a dominant role in formation of β‐iPP. It is suggested that the origin of formation of β‐iPP results from the thermomechanical history of the EPR component in iPP/EPR. © 2007 Wiley Periodicals, Inc. J Polym Sci Part B: Polym Phys 45: 1704–1712, 2007     

Study on Inhibitors of Methionine Synthase Ⅷ: Synthesis of 2,5-Diamino-4-oxo-6- (3-butenyl) pyrimidine

Cobalamin-dependent methionine synthase plays a crucial role in folate metabolism and such would appear to be an excellent target for rational antifolate drug design. However, to date, no anticancer agents directed at this enzyme are available, but the enzyme is efficiently and specifically inhibited by N2O and this has proven invaluable for evaluating the biochemical consequence of enzyme inhibition and for mechanistic studies. [1,2] 2,5-Diamino-4-oxo-6-(3-butenyl) pyrimidine, a key intermediate in synthetic inhibitors of methionine synthase, was first synthesized using γbutenyl-β-ketoester and guanidine carbonate (Scheme 1). [3]