Asymptotic cones of finitely presented groups

Let G be a connected semisimple Lie group with at least one absolutely simple factor S such that and let Γ be a uniform lattice in G.

(a)

If CH holds, then Γ has a unique asymptotic cone up to homeomorphism.

(b)

If CH fails, then Γ has 2^2ω asymptotic cones up to homeomorphism.

     

Simple groups of finite morley rank and Tits buildings

Theorem A:If ℬ is an infinite Moufang polygon of finite Morley rank, then ℬ is either the projective plane, the symplectic quadrangle, or the split Cayley hexagon over some algebraically closed field. In particular, ℬ is an algebraic polygon. It follows that any infinite simple group of finite Morley rank with a spherical MoufangBN-pair of Tits rank 2 is eitherPSL ₃(K),PSp ₄(K) orG ₂(K) for some algebraically closed fieldK. Spherical irreducible buildings of Tits rank ≥ 3 are uniquely determined by their rank 2 residues (i.e. polygons). Using Theorem A we show Theorem B:If G is an infinite simple group of finite Morley rank with a spherical Moufang BN-pair of Tits rank ≥ 2, then G is (interpretably) isomorphic to a simple algebraic group over an algebraically closed field. Theorem C:Let K be an infinite field, and let G(K) denote the group of K-rational points of an isotropic adjoint absolutely simple K-algebraic group G of K-rank ≥ 2. Then G(K) has finite Morley rank if and only if the field K is algebraically closed. We also obtain a result aboutBN-pairs in splitK-algebraic groups: such aBN-pair always contains the root groups. Furthermore, we give a proof that the sets of points, lines and flags of any ℵ₁-categorical polygon have Morley degree 1. Partially sponsored by the Edmund Landau Center for Research in Mathematical Analysis, supported by the Minerva Foundation (Germany). Supported by the Minerva Foundation (Germany). Research Director at the Fund for Scientific Research-Flanders (Belgium).     

Exceptionally Simple Enantioselective Syntheses of Chiral Hexa- and Tetracyclic Polyprenoids of Sedimentary Origin

Coupling between a sulfone and an acylsilane fragment (see below) constitutes the first step in the exceptionally short total syntheses of two chiral hexacyclic hydrocarbons isolated from Eocene Messel shale (Germany). Like the first step, subsequent steps also employ a powerful synthetic tactic: polycyclization of a specially constructed chiral, multiply unsaturated oxirane. TBS=tBuMe₂Si.     

Strongly transitive actions on euclidean buildings

We prove a decomposition result for a group G acting strongly transitively on the Tits boundary of a Euclidean building. As an application we provide a local to global result for discrete Euclidean buildings, which generalizes results in the locally compact case by Caprace–Ciobotaru and Burger–Mozes. Let X be a Euclidean building without cone factors. If a group G of automorphisms of X acts strongly transitively on the spherical building at infinity ?X, then the G-stabilizer of every affine apartment in X contains all reflections along thick walls. In particular G acts strongly transitively on X if X is simplicial and thick.     

Analysis of environment response effects on excitation energies within subsystem-based time-dependent density-functional theory

We analyze the ability of subsystem time-dependent density-functional theory (sTDDFT) to describe environmental response effects. To this end, we utilize the recently proposed “exact” version of sTDDFT relying on projection-based embedding (PbE), which so far was applied only for the special case of two subsystems. We confirm that PbE-sTDDFT in combination with supersystem bases yields results equivalent to those of supermolecular TDDFT calculations for systems solvated by many solvent molecules, using the previously studied system of methylene-cyclopropene⋯(H₂O)₁₇ as an example. By means of this exact reference embedding framework, we are able to disentangle solvent effects introduced in terms of the embedding potential from those caused by solvent response couplings, both for the PbE variant and for sTDDFT with approximate non-additive kinetic energy functionals. Furthermore, we show that the use of a monomer basis introduces significant errors for the environmental response contribution. Employing a virtual-orbital localization strategy on top of PbE-sTDDFT, we can also directly assess the impact of inter-subsystem charge-transfer excitations on the entire solvent effect, which turn out to play a significant role for the environmental response. Finally, we analyze the response effects introduced by the individual solvent molecules and their interdependence, and show that a simple, pair-wise additive correction for solvent response yields excellent results in the present example.     

A highly active catalyst system for the heteroarylation of acetone

A highly active catalyst system for the heteroarylation of acetone has been identified. The coupling between the in situ generated tributyltin enolate of acetone and a variety of heteroaromatic bromides, chlorides, and triflates in the presence of this catalyst system provided arylacetones in good yields.