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951.
Ohne Zusammenfassung 相似文献
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C. Aguilar‐Lugo R. Le Lagadec Alexander D. Ryabov G. Cedillo Valverde S. Lopez Morales L. Alexandrova 《Journal of polymer science. Part A, Polymer chemistry》2009,47(15):3814-3828
Cationic substitutionally inert cyclometalated ruthenium (II) and osmium (II) complexes, ([Mt(o‐C6H4‐2‐py)(LL)2]PF6), where LL‐1,10‐phenanthroline (phen) or 2,2′‐bipyridine (bipy), were used for radical polymerization of styrene. Gradual modification of the complexes within the series allowed comparison of the catalytic activity and the redox properties. There was no correlation between the reducing powers of the complexes and their catalytic activities. The osmium compound of the lowest reduction potential was not active. All the ruthenium complexes catalyzed the polymerization of styrene in a controlled manner; but the level of control and the catalytic activity were different under the same polymerization conditions. [Ru(o‐C6H4‐2‐py)(phen)2]PF6 demonstrated the best catalytic performance though its redox potential was the highest. It catalyzed the “living” polymerization with a reasonable rate at a catalyst‐to‐initiator ratio of 0.1. 1 equiv. of Al(OiPr)3 accelerated the polymerization and improved the control, but higher amount of Al(OiPr)3 did not speed up the polymerization and moved the process into the uncontrollable regime. Under the most optimal conditions, the controlled polymerization occurs fast without any additive and the catalyst degradation. Added free ligands inhibited the polymerization suggesting that the catalytically active ruthenium intermediates are generated via the reversible dechelation of bidentate phen or bipy ligands. © 2009 Wiley Periodicals, Inc. J Polym Sci Part A: Polym Chem 47: 3814–3828, 2009 相似文献
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Yohann Catel Michel Degrange Loïc Le Pluart Pierre‐Jean Madec Thi‐Nhàn Pham Fei Chen Wayne D. Cook 《Journal of polymer science. Part A, Polymer chemistry》2009,47(20):5258-5271
Four new monomers, 3‐(N‐methylacrylamido)propylidenebisphosphonic acid, 3‐(N‐propyl‐acrylamido)propylidenebisphosphonic acid, 3‐(N‐hexylacrylamido)propylidenebisphosphonic acid, and 3‐(N‐octylacrylamido)propylidenebisphosphonic acid, have been synthesized in good yields and fully characterized by 1H, 13C, 31P NMR, and HRMS. The copolymerization of these monomers with N,N′‐diethyl‐1,3‐bis(acrylamido)propane (DEBAAP) has been investigated with differential scanning calorimetry. These mixtures show a higher reactivity than DEBAAP. New self‐etch dental primers, based on these acrylamide monomers, have been formulated. Dentin shear bond strength measurements have shown that primers based on these bisphosphonic acids assure a strong bond between the tooth substance and a dental composite. © 2009 Wiley Periodicals, Inc. J Polym Sci Part A: Polym Chem 47: 5258–5271, 2009 相似文献
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We get the Bergman kernel functions in explicit formulas on four types of Hua domain.There are two key steps: First, we give the holomorphic automorphism groups of four types of Hua domain; second, we introduce the concept of semi-Reinhardt domain and give their complete orthonormal systems. Based on these two aspects we obtain the Bergman kernel function in explicit formulas on Hua domains. 相似文献
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In this paper, we give some conditions to assure that the equation P(X)=Q(Y) has no meromorphic solutions in all K, where P and Q are polynomials over an algebraically closed field K of characteristic zero, complete with respect to a non-Archimedean valuation. In particular, if P and Q satisfy the hypothesis (F) introduced by H. Fujimoto, a necessary and sufficient condition is obtained when deg P=deg Q. The results are presented in terms of parametrization of a projective curve by three entire functions. In this way we also
obtain similar results for unbounded analytic functions inside an open disk.
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