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61.
Mohamed El Amine Dib Hocine Allali Amel Bendiabdellah Nawel Meliani Boufeldja Tabti 《Journal of Saudi Chemical Society》2013,17(4):381-385
In this study, antimicrobial activities of water and methanol extract, and three phenolic fractions of the roots of Arbutus unedo L. were investigated. Poor antibacterial activity against both Staphylococcus aureus and Pseudomonas aeruginosa bacteria was shown with water and methanol extract. However moderate antibacterial activity was shown by water extract and phenolic fractions against Escherichia coli and S. aureus, respectively. The phytochemical screening of roots of A. unedo revealed the presence of quinones, anthraquinones reducteurs compounds, anthocyanins, tannins and flavonoids. Quantitative analysis showed that the roots were strongly dominated by anthocyanins compounds (3.65 mg g?1) followed by total flavonoids (0.56 mg?1) and flavones & flavonols (0.17 mg g?1). 相似文献
62.
This paper addresses the issue of breakdowns in the block GMRES method for solving linear systems with multiple right-hand sides of the form AX = B. An exact (inexact) breakdown occurs at iteration j of this method when the block Krylov matrix (B, AB, … , Aj−1B) is singular (almost singular). Exact breakdowns are the sign that a part of the exact solution is in the range of the Krylov matrix. They are primarily of theoretical interest. From a computational point of view, inexact breakdowns are most likely to occur. In such cases, the underlying block Arnoldi process that is used to build the block Krylov space should not be continued as usual. A natural way to continue the process is the use of deflation. However, as shown by Langou [J. Langou, Iterative Methods for Solving Linear Systems with Multiple Right-Hand Sides, Ph.D. dissertation TH/PA/03/24, CERFACS, France, 2003], deflation in block GMRES may lead to a loss of information that slows down the convergence. In this paper, instead of deflating the directions associated with almost converged solutions, these are kept and reintroduced in next iterations if necessary. Two criteria to detect inexact breakdowns are presented. One is based on the numerical rank of the generated block Krylov basis, the second on the numerical rank of the residual associated to approximate solutions. These criteria are analyzed and compared. Implementation details are discussed. Numerical results are reported. 相似文献
63.
Sma?n Hocine Chérifa Rabia Mohammed M. Bettahar Michel Fournier 《Reaction Kinetics and Catalysis Letters》2003,79(2):357-364
Cs2.5M0.08H0.26PMo12O40and Cs2.5M0.08H1.26PMo11VO40(M: Ni, Fe) heteopolyanions were selectively prepared, characterized by IR, Raman, 31P NMR, XPS and XRD and tested in the ODH of cyclohexane. The salt structure, and reaction mechanism and kinetics are discussed.
This revised version was published online in June 2006 with corrections to the Cover Date. 相似文献
64.
Slimane Merouani Oualid Hamdaoui Yacine Rezgui Miloud Guemini 《Ultrasonics sonochemistry》2013,20(3):815-819
Numerical simulation of chemical reactions inside an isolated spherical bubble of oxygen has been performed for various ambient bubble radii at different frequencies and acoustic amplitudes to study the effects of these two parameters on the range of ambient radius for an active bubble in sonochemical reactions. The employed model combines the dynamic of bubble collapse with the chemical kinetics of single cavitation bubble. Results from this model were compared with some experimental results presented in the literature and good apparent trends between them were observed. The numerical calculations of this study showed that there always exists an optimal ambient bubble radius at which the production of oxidizing species at the end of the bubble collapse attained their upper limit. It was shown that the range of ambient radius for an active bubble increased with increasing acoustic amplitude and decreased with increasing ultrasound frequency. The optimal ambient radius decreased with increasing frequency. Analysis of curves showing optimal ambient radius versus acoustic amplitude for different ultrasonic frequencies indicated that for 200 and 300 kHz, the optimal ambient radius increased linearly with increasing acoustic amplitude up to 3 atm. However, slight minima of optimal radius were observed for the curves obtained at 500 and 1000 kHz. 相似文献
65.
Mebarek Hocine Hadjoui Abdelhamid 《Mathematical and Computer Modelling of Dynamical Systems: Methods, Tools and Applications in Engineering and Related Sciences》2013,19(6):573-597
The hp-version of the finite element method based on a triangular p-element is applied to free vibration of the orthotropic triangular and rectangular plates. The element's hierarchical shape functions, expressed in terms of shifted Legendre orthogonal polynomials, is developed for orthotropic plate analysis by taking into account shear deformation, rotary inertia, and other kinematics effects. Numerical results of frequency calculations are found for the free vibration of the orthotropic triangular and rectangular plates with the effect of the fiber orientation and plate boundary conditions. The results are very well compared to those presented in the literature. 相似文献
66.
Mössbauer spectroscopy can be a useful structural tool to assist crystallographic methods for site assignment when the compound under investigation contains divalent tin. The goal of this work was to show that the structure of tin(II) fluoride, also know as stannous fluoride, SnF2, could have been solved 14 years earlier if Mössbauer spectroscopic results, already known, had been used. A first attempt to solve the crystal structure, carried out by Bergerhoff in 1962 seemed to find the tin positions, however, it failed to find the positions of fluorine. Further extensive studies by Dénès et al. in the mid 1970s yielded the same results as those of Bergerhoff, despite the use of a Nonius CAD-4 automatic diffractometer, in contrast with Bergerhoff’s film work. The tin positions yielded a residual of 0.23, and Fourier difference maps showed significant electron density that could be fluorine atoms, however, their number did not match the number of fluorine atoms expected and several F-F distances were way too short. In addition, refinement using these possible fluorine positions led to no improvement of the residual factor. Finally, the crystal structure was published by McDonald et al. in 1976. It was found that the tin sublattice determined by Bergerhoff was basically correct, except that half of the tin atoms found by Bergerhoff to be on the (4b) and (4e) special Wyckoff sites were actually on the (8f) general site. A translation of the origin of the unit-cell by the [1/8, 0, 3/16] vector allows to change the tin Wyckoff sites from (4b), (4e) and (8f) to two (8f) sites, while keeping the basic spatial distribution of tin. A method has now been designed, using 119Sn Mössbauer spectroscopy, to test the suitability of some Wyckoff sites for divalent tin, using the Mössbauer spectrum. The tin(II) doublet (δ = 3.430(3) mm/s, Δ = 1.532(3) mm/s) shows that the lone pair is on a hybrid orbital, therefore, it is stereoactive, and it results that tin cannot be on either the (4b) or (4e) tin site since both an inversion center and a 2-fold axis would generate a second lone pair unless the 2-fold axis were along the tin-lone pair axis. 相似文献
67.
Faouzi Guenadil Hocine Aichaoui Coco N. Kapanda Didier M. Lambert Christopher R. McCurdy Jacques H. Poupaert 《Monatshefte für Chemie / Chemical Monthly》2011,27(7):67-80
Abstract
A simpler and efficient “green” method using solid sodium hydroxide in a solvent mixture of acetone/water was found to catalyze N-acylation of 2(3H)-benzoxazolones and 2(3H)-benzothiazolones for facile and rapid synthesis of N-acyl derivatives in excellent yields. This method was applied to the synthesis of a series of 132 compounds employing a variety of acyl chlorides. 相似文献68.
Ammonium salts, (NH4)6HPMo11MO40 (M = Ni, Co, Fe), have been investigated for the oxidation of propane, with molecular oxygen, at temperature ranging between 380 °C and 420 °Cafter in-situ pre-treatment performed at two heating rate of 5 or 9 °C/min. They were characterized by BET method, XRD, 31P NMR, UV-Vis and IR techniques. The catalysts were found active in the propane oxidation and selective to propene or acrolein, in particular for samples pre-treated with the heating rate of 9 °C/min. 相似文献
69.
Miloud Assal 《Journal of Computational and Applied Mathematics》2009,233(3):617-620
In this paper we consider the generalized shift operator generated from the Laguerre hypergroup; by means of this, pseudo-differential operators are investigated and Sobolev-boundedness results are obtained. 相似文献
70.
In this paper we give some congruences on the r-derangement polynomials (defined below), Lah polynomials and some versions of Bell numbers and polynomials. 相似文献