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121.
Kirill V. Kholin Mikhail N. Khrizanforov Vasily M. Babaev Guliya R. Nizameeva Salima T. Minzanova Marsil K. Kadirov Yulia H. Budnikova 《Molecules (Basel, Switzerland)》2021,26(18)
A selective noble-metal-free molecular catalyst has emerged as a fruitful approach in the quest for designing efficient and stable catalytic materials for CO2 reduction. In this work, we report that a sodium pectate complex of copper (PG-NaCu) proved to be highly active in the electrocatalytic conversion of CO2 to CH4 in water. Stability and selectivity of conversion of CO2 to CH4 as a product at a glassy carbon electrode were discovered. The copper complex PG-NaCu was synthesized and characterized by physicochemical methods. The electrochemical CO2 reduction reaction (CO2RR) proceeds at −1.5 V vs. Ag/AgCl at ~10 mA/cm2 current densities in the presence of the catalyst. The current density decreases by less than 20% within 12 h of electrolysis (the main decrease occurs in the first 3 h of electrolysis in the presence of CO2). This copper pectate complex (PG-NaCu) combines the advantages of heterogeneous and homogeneous catalysts, the stability of heterogeneous solid materials and the performance (high activity and selectivity) of molecular catalysts. 相似文献
122.
Kirill M. Skupov Pooja R. Marella Michel Simard Glenn P. A. Yap Nathan Allen David Conner Brian L. Goodall Jerome P. Claverie 《Macromolecular rapid communications》2007,28(20):2033-2038
The reaction of 2‐[bis(2‐methoxy‐phenyl)phosphanyl]‐4‐methyl‐benzenesulfonic acid (a) and 2‐[bis(2′,6′‐dimethoxybiphenyl‐2‐yl)phosphanyl]benzenesulfonic acid (b) with dimethyl(N,N,N′,N′‐tetramethylethylenediamine)‐palladium(II) (PdMe2(TMEDA)) leads to the formation of TMEDA bridged palladium based polymerization catalysts ( 1a and 1b ). Upon reaction with pyridine, two mononuclear catalysts are formed ( 2a and 2b ). These catalysts are able to homopolymerize ethylene and also copolymerize ethylene with acrylates or with norbornenes. With ligand b , high molecular weight polymers are formed in high yields, but higher comonomer incorporations are obtained with ligand a .
123.
Alexandra Svyatova Dr. Ivan V. Skovpin Dr. Nikita V. Chukanov Dr. Kirill V. Kovtunov Prof. Eduard Y. Chekmenev Dr. Andrey N. Pravdivtsev Prof. Jan-Bernd Hövener Prof. Igor V. Koptyug 《Chemistry (Weinheim an der Bergstrasse, Germany)》2019,25(36):8465-8470
Magnetic Resonance Imaging (MRI) is a powerful non-invasive diagnostic method extensively used in biomedical studies. A significant limitation of MRI is its relatively low signal-to-noise ratio, which can be increased by hyperpolarizing nuclear spins. One promising method is Signal Amplification By Reversible Exchange (SABRE), which employs parahydrogen as a source of hyperpolarization. Recent studies demonstrated the feasibility to improve MRI sensitivity with this hyperpolarization technique. Hyperpolarized 15N nuclei in biomolecules can potentially retain their spin alignment for tens of minutes, providing an extended time window for the utilization of the hyperpolarized compounds. In this work, we demonstrate for the first time that radio-frequency-based SABRE hyperpolarization techniques can be used to obtain 15N MRI of biomolecule 1-15N-nicotinamide. Two image acquisition strategies were utilized and compared: Single Point Imaging (SPI) and Fast Low Angle SHot (FLASH). These methods demonstrated opportunities of high-field SABRE for biomedical applications. 相似文献
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The pyramidal character of life cycles of economic structures is empirically confirmed on the basis of official statistical data of the years 2003 and 2004. The ergodic hypothesis is applied as one of methods of economic forecasting in evolutionary economics, econophysics and applied researches. 相似文献
127.
V. I. Vovna V. V. Gorchakov V. E. Karasev A. I. Cherednichenko 《Journal of Structural Chemistry》1989,30(3):486-488
Physicotechnical Research Institute of the Far Eastern State University. Chemical Institute of the Far Eastern Branch, Academy of Sciences of the USSR. Translated from Zhurnal Strukturnoi Khimii, Vol. 30, No. 3, pp. 147–149, May–June, 1989. 相似文献
128.
Kirill A. Kovnir Yury V. Kolen’ko Sugata Ray Tomoaki Watanabe Masahiro Yoshimura 《Journal of solid state chemistry》2006,179(12):3756-3762
An effective method of synthesis of tin phosphide Sn4P3 starting from metallic tin and amorphous red phosphorus by a low-temperature (200 °C) solvothermal reaction in ethylenediamine is offered. The key parameters of this process - duration, temperature, and the ratio of initial components (Sn/P) are studied. The structure, phase composition, and morphology of the products are investigated using powder X-ray diffraction and scanning electron microscopy. Different synthetic ways for tin phosphide are discussed and compared with the proposed one. The mechanism of solvothermal preparation of tin phosphide in ethylenediamine is discussed. It is shown that the proposed solvothermal method opens up the possibility of preparing other metal-rich phosphides. 相似文献
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