全文获取类型
收费全文 | 1004篇 |
免费 | 27篇 |
国内免费 | 10篇 |
专业分类
化学 | 716篇 |
晶体学 | 5篇 |
力学 | 24篇 |
数学 | 103篇 |
物理学 | 193篇 |
出版年
2024年 | 4篇 |
2023年 | 5篇 |
2022年 | 6篇 |
2021年 | 42篇 |
2020年 | 19篇 |
2019年 | 23篇 |
2018年 | 33篇 |
2017年 | 25篇 |
2016年 | 30篇 |
2015年 | 26篇 |
2014年 | 33篇 |
2013年 | 83篇 |
2012年 | 54篇 |
2011年 | 54篇 |
2010年 | 51篇 |
2009年 | 50篇 |
2008年 | 53篇 |
2007年 | 64篇 |
2006年 | 46篇 |
2005年 | 48篇 |
2004年 | 58篇 |
2003年 | 33篇 |
2002年 | 41篇 |
2001年 | 11篇 |
2000年 | 9篇 |
1999年 | 13篇 |
1997年 | 9篇 |
1996年 | 12篇 |
1995年 | 4篇 |
1994年 | 3篇 |
1993年 | 4篇 |
1992年 | 7篇 |
1991年 | 7篇 |
1990年 | 3篇 |
1989年 | 5篇 |
1987年 | 3篇 |
1986年 | 2篇 |
1985年 | 10篇 |
1983年 | 5篇 |
1982年 | 6篇 |
1981年 | 4篇 |
1980年 | 8篇 |
1979年 | 5篇 |
1978年 | 6篇 |
1977年 | 3篇 |
1976年 | 2篇 |
1975年 | 2篇 |
1974年 | 2篇 |
1973年 | 4篇 |
1962年 | 2篇 |
排序方式: 共有1041条查询结果,搜索用时 140 毫秒
61.
62.
The spiro-compound 3′H-spiro[indole-3,2′-[1,3]benzothiazole-2(1H)-one (IBTH2) was synthesized and its structure was determined using spectroscopic techniques (FTIR, 1H NMR and mass) and X-ray crystallography. This ligand possesses different centers for coordination. Reactions of [M(CO)6], M = Cr, Mo or W with IBTH2 in THF under reduced pressure were studied. For chromium a complex with molecular formula [Cr(ITP)2] was isolated; where ITP is the opened form of the ligand which occurred through Cspiro–S bond, while [Mo(CO)5(IBTH2)] and [W(CO)5(IBTH2)] were isolated from the reaction of IBTH2 with molybdenum and tungsten carbonyls, respectively. All complexes were characterized by elemental analysis, IR, mass and 1H NMR spectroscopy. The biological activity of the ligand and its complexes were studied and compared with the parent compound isatin. 相似文献
63.
We study the entanglement between a pair of two-level atoms simultaneously interacting via a singlemode thermal field. The Hamiltonian also describes a two-photon process. The entanglement between a nonlinear atom-field interacting system is also studied using atomic and field entropy changes. We use concurrence to detect the sudden death phenomenon. Furthermore, we discuss the relationship between entropy changes and concurrence entanglement. Our results show that the behavior of the entropy change is in agreement with the behavior of the concurrence when we measure the entanglement between the two-subsystem structure. 相似文献
64.
We show that string models with low energy supersymmetry which accommodate the fermion mass hierarchy generally give nonuniversal soft trilinear couplings (A terms). In conjunction with the apparently large Cabibbo-Kobayashi-Maskawa (CKM) phase, this results in large fermion electric dipole moments (EDMs) even in the absence of CP violating phases in the supersymmetry breaking auxiliary fields and the micro term. Nonobservation of the EDMs therefore implies that strings select special flavor and/or supersymmetry breaking patterns. 相似文献
65.
G. I. Khalil 《Journal of Radioanalytical and Nuclear Chemistry》1985,96(5):539-546
Neutron activation technique using a low intensity252Cf source has been applied for Mn and Na analysis in geological samples. The series of samples tested in the present work were collected from the boreholes Nádudvar-9, Hajdúböszörmény-1 and Nagyecsed-1 in Hungary, from different strata. 相似文献
66.
Let and be Banach spaces, and be the spaces of bounded linear operators from into In this paper we give full characterization of isometric onto operators of for a certain class of Banach spaces, that includes We also characterize the isometric onto operators of and the compact operators on Furthermore, the multiplicative isometric onto operators of , when multiplication on is taken to be the Schur product, are characterized.
67.
MostafaADIMY MostafaLAKLACH KhalilEZZINBI 《数学学报(英文版)》2004,20(5):933-942
In this work, we are concerned with a general class of abstract semilinear autonomous functional differential equations with a non-dense domain on a Banach space. Our objective is to study, using the Crandall-Liggett approach, the solutions as a semigroup of non-linear operators. 相似文献
68.
Khalil H Mahajan D Rafailovich M Gelfer M Pandya K 《Langmuir : the ACS journal of surfaces and colloids》2004,20(16):6896-6903
Concurrent sonolysis of iron pentacarbonyl and poly(ethylene glycol)-400 (PEG-400) in hexadecane solvent proceeds via zero-order kinetics and results in Fe nanoparticles encapsulated in PEG-400 (Fe-PEG). The transmission electron microscopy images show Fe-PEG consisting of <3 nm Fe particles that are evenly dispersed in the PEG matrix. M?ssbauer and X-ray absorption fine structure/X-ray absorption near-edge structure data reveal an ordered PEG assembly that helps protect the zerovalent Fe core. The Fe nanoparticles in Fe-PEG are superparamagnetic with a magnetization value of 45 emu/g-Fe at 10 KOe. The rheology of the synthesized material shows an unusual increase in viscosity with temperature that is likely due to lower critical saturation temperature phase segregation over 40 degrees C. The low-temperature mobility of the PEG-400 moiety in Fe-PEG would allow facile ligation of the Fe0 core with biologically and chemically active groups. 相似文献
69.
Eight new polyamides containing azo moieties and hydantoin groups were synthesized under microwave irradiation by using a domestic microwave oven from the polycondensation reactions of 4,4′-azodibenzoyl chloride [4,4′-azobenzenedicarboxylic acid] 3 with eight different derivatives of 5,5-disubstituted hydantoin 4a-h in the presence of a small amount of a polar organic medium such as o-cresol. The polycondensation proceeded rapidly, compared with the bulk polycondensation and the solution polycondensation and was completed between 7-12 min, producing a series of new polyamides 5a-h in high yield, and inherent viscosity between 0.35 and 0.60 dL/g. The resulting polyamides were characterized by elemental analysis, viscosity measurements, thermal gravimetric analysis (TGA and DTG), solubility test and FT-IR spectroscopy. All of the polymers were soluble at room temperature in polar solvents such as N,N-dimethylacetamide, N,N-dimethylformamide, dimethylsulfoxide, tetrahydrofurane and N-methyl-2-pyrrolidone. 相似文献
70.
A new strategy for the combinatorial synthesis of new materials has been developed through the consecutive application of an Ugi 4CC reaction and a ring-opening metathesis polymerization (ROMP) reaction. Norbornenyl aldehydes and carboxylic acids could be used in the Ugi MCR to give highly diverse monomers that were converted to the corresponding polymers by exposure to the second-generation Grubbs' catalyst. These polymers have structural features reminiscent of polypeptides and the process could be extended to the preparation of chiral materials. 相似文献