Quantum vs. classical models of the nitro group for proton chemical shift calculations and conformational analysis

A model based on classical concepts is derived to describe the effect of the nitro group on proton chemical shifts. The calculated chemical shifts are then compared to ab initio (GIAO) calculated chemical shifts. The accuracy of the two models is assessed using proton chemical shifts of a set of rigid organic nitro compounds that are fully assigned in CDCl3 at 700 MHz. The two methods are then used to evaluate the accuracy of different popular post-SCF methods (B3LYP and MP2) and molecular mechanics methods (MMX and MMFF94) in calculating the molecular structure of a set of sterically crowded nitro aromatic compounds. Both models perform well on the rigid molecules used as a test set, although when using the GIAO method a general overestimation of the deshielding of protons near the nitro group is observed. The analysis of the sterically crowded molecules shows that the very popular B3LYP/6-31G(d,p) method produces very poor twist angles for these, and that using a larger basis set [6-311++G(2d,p)] gives much more reasonable results. The MP2 calculations, on the other hand, overestimate the twist angles, which for these compounds compensates for the deshielding effect generally observed for protons near electronegative atoms when using the GIAO method at the B3LYP/6-311++G(2d,p) level. The most accurate results are found when the structures are calculated using B3LYP/6-311++G(2d,p) level of theory, and the chemical shifts are calculated using the CHARGE program based on classical models.     

A flexible synthesis of the phytoprostanes B1 type I and II

Syntheses of the enantiomerically pure phytoprostanes B(1) type I and II are described starting from furfural and n-propylfuran. Key steps include the preparation of the Freimanis (+/-)-hydroxycyclopentenone and Wittig coupling using chiral phosphonium salts.     

Coproducts in the Category <Emphasis Type="Bold">M</Emphasis>κ<Emphasis Type="Bold">Frm</Emphasis>

The purpose of this paper is to study coproducts in the category MFrm (resp. M_cFrm), of metric -frames and uniform (resp. contractive) -frame maps. First, by applying the same technic that was used to find coproducts in Frm, we construct coproducts in the category Frm of -frames and -frame maps. Then, we define a metric diameter on the coproduct in Frm of a family of metric -frames and show that coproduct in Frm preserves metrizability.Mathematics Subject Classifications (2000) 06B23, 06D22, 18A30.     

Stopping criteria, forward and backward errors for perturbed asynchronous linear fixed point methods in finite precision

^** Email: pierre.spiteri{at}enseeiht.fr This paper deals with perturbed linear fixed point methods inthe presence of round-off errors. Successive approximationsas well as the more general asynchronous iterations are treated.Forward and backward error estimates are presented, and theseare used to propose theoretical stopping criteria for thesemethods. In the case of asynchronous iterations, macro-iterationsare used as a tool in order to obtain estimates.     

Calcul fonctionnel harmonique dans les algèbres localementp-convexes

We define and study a harmonic functional calculus in locallyp-convex algebras in the case with a linear involution. Some applications are also provided.

     

Numerical solution of Volterra integral equations by spline functions

A method for obtaining spline function approximations to solutions of non-singular Volterra equations of the second kind is presented. Convergence results as well as numerical examples comparing the method with known techniques are given.     

Effect of magnetic field on nonlinear interactions of electromagnetic and surface waves in a plasma layer

Investigation is made for nonlinear interaction between incident radiation and a surface wave in a magnetized plasma layer. Both interacting waves are ofP polarization. We get the generated currents and fields at combination frequencies analytically. Unlike theS-polarized interacting waves, the magnetic field affects the fundamental waves and leads to an amplification of generated waves when their frequencies approach the cyclotron frequency.