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61.
The thermal stability, kinetics of crystallization, and glass forming ability of a Ti48Ni32Cu8Si8Sn4 bulk amorphous alloy have been studied by differential scanning calorimetry using both isothermal and non-isothermal experiments. The activation energy, frequency factor, and reaction rate for the crystallization cascade were determined via the Kissinger method. X-ray diffractometry and transmission electron microscopy studies revealed that crystallization starts with the primary precipitation of Ti(Ni,Cu), followed by the nucleation of Cu3Ti from the amorphous precursor. The kinetics of nucleation of the primary crystalline phase was also investigated using the Johnson–Mehl-Avrami method and the Avrami exponent, n, was determined. This new alloy possesses a significantly larger supercooled liquid region than any other non beryllium- or non rare earth – containing titanium-based bulk metallic glass to date. 相似文献
62.
Khalifa El Mabrouk 《Positivity》2006,10(4):665-680
We obtain a characterization of all locally bounded functions p ≥ 0 for which the equation (E) Δu +p(x)ψ(u) = 0 has a positive solution in Ω vanishing on the boundary, where Ω is a domain of ℝN and ψ > 0 is a nonincreasing continuous function on ]0,∞[. In particular, for Ω = ℝN with N ≥ 3, it is shown that (E) has a (unique) positive solution in ℝN which decays to zero at infinity if and only if the set {p > 0} has positive Lebesgue measure and
This condition can be replaced by if p is radial. 相似文献
63.
A new and unequivocal synthesis of pteroyl-λ-L-glutamyl-L-glutamic acid free of isomers is described. A melt of N(2′)-acetyl-6-formylpterine and trimethyl-N-(p-amino-benzoyl)-λ-L-glutamyl-L-glutamate was quantitatively converted to 6-azomethin-pterine-trimethylester XI. NaBH4-reduction followed by basic hydrolysis of acetyl and methyl ester groups gives pure pteroyl-λ-glutamyl-glutamic acid in good yield. 相似文献
64.
We consider a generalized convolution , , on the real line generated by the Dunkl operator
Through this convolution structure, we associate with the differential-difference operator a Calderon type reproducing formula which involves finite Borel measures, and gives rise to new representations for -functions on the real line and their generalized Hilbert transforms.
Received 25 July 2000; in final form 29 September 2001 相似文献
65.
We consider a generalized convolution , , on the real line generated by the Dunkl operator
Through this convolution structure, we associate with the differential-difference operator a Calderon type reproducing formula which involves finite Borel measures, and gives rise to new representations for -functions on the real line and their generalized Hilbert transforms. 相似文献
66.
A simple, rapid, and reliable method for cerium(IV) alone; in presence of a variety of cations involving rare earths and iron (III); or in binary, ternary, and quaternary mixtures is given. By its aid 10?3 down to 1.5 × 10?5 mole of cerium(IV) were determined with requisite accuracy and precision. The potential breaks detecting the end points ranged from a maximum of 410 to a minimum of 100 mV/0.1 ml of 0.05 or 10?4M titrant, respectively. Analysis of 15 mixtures using the present method together with other recommended procedures was always much less tedious or time-consuming than reported methods. 相似文献
67.
A stable solution of (cobalt(III)(salen))2O2 was prepared under optimum conditions for its use for the potentiometric determination of xylenols, hydroquinone, sodium thiosulfate, and sodium metabisulfite, by iodide reduction of unreacted cobalt(III) complex and back titrating excess iodide with mercury(II) using silver amalgum and SCE combination. The possible schemes for the course of the redox reactions were suggested. The procedure was also evaluated in comparison with those mentioned in the literature. 相似文献
68.
Copper in different organs of Egyptian camels was successfully determined spectrophotometrically using Fast Grey RA. Its values amounted to: 200.8 ± 11.4, 155.8 ± 16.1, 142 ± 6.8, 128.3 ± 6.9, 117.6 ± 5.1, 113.0 ± 5.3, 86.3 ± 3.2, 79.0 ± 5.2, 76.3 ± 3.7, 66.3 ± 4.3, 59.8 ± 1.7, 57.6 ± 3.0, 53.0 ± 2.2, 36.3 ± 2.3 and 3.03 ± 0.32 μg/g dry matter of hair, liver, spleen, lung, heart, integument, muscle, brain, lymph gland, small intestine, large intestine, kidney, adrenal, fourth stomach, and hump, respectively, while 1 ml citrated blood contained 6.97 ± 0.64 μg. Of 16 elements mentioned, only vanadium interferes with the determination of copper in hair by the present method. 相似文献
69.
H. Khalifa 《Microchemical Journal》1973,18(5):529-535
A survey on the iodide-mercury(II) reaction and its analytical uses is given. Titrations of iodide with mercury(II) in various acidities, using nitrate, acetate, and chloride as titrants and silver or platinum amalgam as the indicator electrode, showed that mercury(II) nitrate is the best titrant giving 0.46 V/0.1 ml potential break in comparison with 0.14 V/0.1 ml of mercury(II) chloride and 0.35V/0.1 ml of mercury(II) acetate, all titrants being 0.05 M in mercury(II). 相似文献
70.
Radiation effects on polymers—IV: Straight radiation vulcanization of styrene-butadiene rubber mixes
Vulcanization of styrene-butadiene rubbers was carried out by gamma radiation in air. For unloaded unextracted rubbers, the dose required for optimum cross-linking was about 40 megaroentgens (MR). Elimination of foreign materials and stabilizers and also incorporation of filler affected the vulcanization. Loaded samples gave vulcanizates with best complex physico-mechanical properties for filler content of 50 (phr) and a dose of 30 MR. Evaluation of various fillers has shown that the best properties were obtained with HAF among the black fillers and silica in the case of white fillers. 相似文献