Coexistence of solvated electrons and solvent valence anions in negatively charged acetonitrile clusters, (CH3CN)-n(n=10-100)

Anion photoelectron spectroscopy of acetonitrile cluster anions, (CH3CN)(-)(n) (n=10-100), successfully demonstrates the competitive coexistence of two different anionic species: a solvated electron and a solvent-bound valence anion. The distinctly different nature of these anions is revealed by hole-burning-type photoelectron spectroscopy and relative photodetachment cross section measurements. This unusual coexistence is attributed to the closely lying nature of their anionic states at just the number of solvent molecules sufficient to almost complete the first solvation layer.     

Delocalization transition of a rough adsorption-reaction interface

We introduce a kinetic interface model suitable for simulating adsorption-reaction processes which take place preferentially at surface defects such as steps and vacancies. As the average interface velocity is taken to zero, the self-affine interface with Kardar-Parisi-Zhang-like scaling behavior undergoes a delocalization transition with critical exponents that fall into a different universality class. As the critical point is approached, the interface becomes a multivalued, multiply connected self-similar fractal set. The scaling behavior and critical exponents of the relevant correlation functions are determined from Monte Carlo simulations and scaling arguments.     

Localization-delocalization transition in chains with long-range correlated disorder

We investigated numerically localization properties of electron eigenstates in a chain with long-range correlated diagonal disorder. A tight-binding one-dimensional model with on-site energies exhibiting long-range correlated disorder (LCD) was used with various disorder strength W. LCD was defined so that it gave a power-law spectral density of the form S(k)αk^-p, where p determines the roughness of the potential landscape. Numerical results on the correlation length ξ of eigenstates shows the existence of the localization-delocalization transition at p=2. It is found that the critical values for disorder strength W_c and also the critical exponent ν for localization length change with the values of p.     

Two non-linear azide containing heteronuclear complexes: crystal structure and thermal decomposition

Bis-N,N′(salicylidene)-2,2′-dimethyl-1,3-propanediamine (LDMH₂) has a high tendency to form polynuclear complexes. Two trinuclear complexes were obtained using this ligand and azide ions; (CuLDM)₂ · Mn(N₃)₂ · (DMF)₂, [(C₁₉H₂₀N₂O₂Cu)₂ · Mn(N₃)₂ · (C₃H₇NO)₂] and (CuLDM)₂ · Cd(N₃)₂ · (DMF)₂, [(C₁₉H₂₀N₂O₂Cu)₂ · Cd(N₃)₂ · (C₃H₇NO)₂]. The structures were identified with X-ray methods. TG and DSC methods were also employed to these complexes. Studies showed the (CuLDM)₂ · Mn(N₃)₂ · (DMF)₂ and (CuLDM)₂ · Cd(N₃)₂ · (DMF)₂ to be non-linear. Also μ-bridges were not encountered for the azide ions but were seen to form between the Cu and other metal via phenolic oxygens. Thermal analysis showed exothermic degradation of the azide ions destroying the trinuclear structure. Although azide containing structures show explosive characteristics, this was not observed for the present compounds.     

The taxicab space group

It is shown that the group of isometries of the 3-dimensional space with respect to taxicab metric is the semi-direct product of octahedral group O _h and T(3), where O _h is the (Euclidean) symmetry group of the regular octahedron and T(3) is the group of all translations of the 3-dimensional space.     

A review on design criteria for vortex tubes

In this study, the past investigations of the design criteria of vortex tubes were overviewed and the detailed information was presented on the design of them. Vortex tubes were classified and the type of them was described. All criteria on the design of vortex tubes were given in detail using experimental and theoretical results from the past until now. Finally, the criteria on the design of them are summarized.     

Oxidation of Pt(111) under near-ambient conditions

The oxidation of Pt(111) at near-ambient O2 pressures has been followed in situ using x-ray photoelectron spectroscopy (XPS) and ex situ using x-ray absorption spectroscopy (XAS). Polarization-dependent XAS signatures at the O K edge reveal significant temperature- and pressure-dependent changes of the Pt-O interaction. Oxide growth commences via a PtO-like surface oxide that coexists with chemisorbed oxygen, while an ultrathin α-PtO2 trilayer is identified as the precursor to bulk oxidation. These results have important implications for understanding the chemical state of Pt in catalysis.     

Spectral asymptotics and basis properties of fourth order differential operators with regular boundary conditions

In this paper, we consider the problem where λ is a spectral parameter; q(x) ∈ L₁(0,1) is complex‐valued function; α_s, s = 1,2,3, are arbitrary complex constants that satisfy α₂ = α₁ + α₃ and σ = 0,1. The boundary conditions of this problem are regular, but not strongly regular. Asymptotic formulae for eigenvalues and eigenfunctions of the considered boundary value problem are established. It is proved that all the eigenvalues, except for finite number, are simple and the system of root functions of this spectral problem forms a basis in the space L_p(0,1), 1 < p < ∞ , when ; moreover, this basis is unconditional for p = 2. We note that the considered problem was previously investigated in the condition of α₂ ≠ α₁ + α₃. Copyright © 2013 John Wiley & Sons, Ltd.