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631.
The composition fields in turbulent reacting flows are affected by turbulent transport (macromixing), molecular diffusion (micromixing), and chemical reactions. In the joint velocity-composition probability density function transport equation the highly nonlinear macromixing and chemical reaction terms appear in closed form. This is a considerable advantage over second moment closure methods. Micromixing on the other hand requires modelling and especially for turbulent combustion accurate mixing models are crucial. In this paper we present an approach to model the mixing of scalars, e.g. species mass fractions or temperature, based on considering one-dimensional parameterized scalar profiles (PSP). (© 2005 WILEY-VCH Verlag GmbH & Co. KGaA, Weinheim) 相似文献
632.
In hybrid joint probability density function (joint PDF) algorithms for turbulent reactive flows the equations for the mean flow discretized with a classical grid based method (e.g. finite volume methods (FVM)) are solved together with a Monte Carlo (particle) method for the joint velocity composition PDF. When applied for complex geometries, the solution strategy for such methods which aims at obtaining a converged solution of the coupled problem on a sufficiently fine grid becomes very important. This paper describes one important aspect of this solution strategy, i.e. multigrid computing, which is well known to be very efficient for computing numerical solutions on fine grids. Two sets of grid based variables are involved: cell-centered variables from the FVM and node-centered variables, which denote the moments of the PDF extracted from the particle fields. Starting from a given multiblock grid environment first a new (refined or coarsened) grid is defined retaining the grid quality. The projection and prolongation operators are defined for the two sets of variables. In this new grid environment the particles are redistributed. The effectiveness of the multigrid algorithm is demonstrated. Compared to solely solving on the finest grid, convergence can be reached about one order of magnitude faster when using the multigrid algorithm in three stages. Computation time used for projection or prolongation is negligible. (© 2005 WILEY-VCH Verlag GmbH & Co. KGaA, Weinheim) 相似文献
633.
Hole transport in two fluorene-arylenediamine copolymers is studied by means of time-of-flight (ToF) and space-charge-limited dark-injection (SCL DI) transient current methods. Non-dispersive and dispersive hole transport is observed for a range of sample thicknesses, applied electric fields and temperatures. 相似文献
634.
635.
Prof. Ryo Ohtani Jianeng Xu Dr. Junichi Yanagisawa Yuudai Iwai Takumi Ehara Dr. Kiyoshi Miyata Prof. Ken Onda Dr. Jenny Pirillo Prof. Yuh Hijikata Tomoaki Hiraoka Prof. Shinya Hayami Dr. Benjamin Le Ouay Prof. Masaaki Ohba 《Angewandte Chemie (International ed. in English)》2023,62(32):e202306853
We synthesized a (1-propylpyridinium)2[ReN(CN)4]-type organic–inorganic hybrid exhibiting water-vapor-induced drastic structural changes of the [ReN(CN)4]2− assemblies. Specifically, upon exposure to water vapor, dehydrated nitrido-bridged chains were converted to hydrated cyanido-bridged tetranuclear clusters via rearrangements of large molecular building units in the crystals. These switchable assembly forms display substantially different photo-physical properties, although in both cases the emission is caused by a metal-centered d–d transition. The nitrido-bridged chain exhibited a near-infrared (749 nm) emission, which blue-shifted as the temperature increased, while a visible (561 nm) emission and its red shift was demonstrated by the cyanido-bridged cluster. 相似文献
636.