Extraction,complex formation and spectrophotometric determination of iron(III) with 2-carbethoxy-5-hydroxy-1-(4-tolyl)-4-pyridone

Summary The extraction of iron(III) from aqueous HCl, H₂SO₄, HClO₄, HNO₃ solutions by 2-carbethoxy-5-hydroxy-1-(4-tolyl)-4-pyridone (HA) dissolved in CHCl₃ has been studied. Quantitative extraction of iron(III) is achieved if the concentration of the acids does not exceed 1N. The composition of the iron (III)—HA complex formed in the organic phase was investigated spectrophotometrically, radiometrically and by analysis of the isolated species. In the aqueous phase iron (III) and HA form three different complexes, depending on the initial iron: HA concentration ratio and the pH of the solution. They are the violet FeA²⁺, the orange-red FeA₂ ⁺ and the orange-yellow FeA₃. The latter is identical with the complex found in the organic phase, which was isolated as a solid crystalline material and characterized by elemental analysis and infrared spectroscopy. A spectrophotometric method for the determination of iron(III) in the aqueous phase and in the chloroform solution, by extraction with HA, is described.

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Zusammenfassung Die Extraktion von Fe(III) aus wäßrigen Lösungen von HCl, H₂SO₄, HClO₄ oder HNO₃ mit 2-Carbäthoxy-5-hydroxy-1-(4-tolyl)-4-pyridon (HA) in chloroformischer Lösung wurde untersucht. Sie verläuft quantitativ, wenn die Konzentration der Säure nicht größer ist als 1-n. Die Zusammensetzung des Fe(III)-HA-Komplexes in der organischen Phase wurde spektrophotometrisch, radiometrisch und durch Analyse der isolierten Substanz untersucht. In wäßrigem Milieu bilden Eisen(III) und HA drei verschiedene Komplexe je nach dem anfänglichen Konzentrationsverhältnis Fe(III): HA und je nach dem pH der Lösung. FeA²⁺ ist violett, FeA₂ ⁺ ist orange-rot und FeA₃ orangegelb. Diese Verbindung ist mit dem in der organischen Phase gefundenen Komplex identisch, der in kristallisierter Form isoliert und durch Elementaranalyse und IR-Spektrometrie charakterisiert wurde. Eine spektrophotometrische Methode zur Eisen(III)-Bestimmung in wäßriger Phase und in chloroformischer Lösung durch Extraktion mit HA wurde beschrieben.

     

Solvent extraction and separation of zirconium,niobium and tantalum by 2-carbethoxy-5-hydroxy-1-(4-tolyl)-4-pyridone

Summary Extraction of zirconium, niobium and tantalum from oxalic and hydrofluoric acid solutions, by 2-carbethoxy-5-hydroxy-1-(4-tolyl)-4-pyridone (HA) dissolved in chloroform was studied. Extraction mechanism for the extraction of zirconium from oxalate solutions and of niobium from fluoride solutions is proposed. Separation of zirconium and niobium from oxalate solution as well as from fluoride solution and tantalum and niobium from fluoride solution is described. Back-extraction of these metals is possible by hydrofluoric and oxalic acid. Results obtained show that the efficiency of extraction by HA decreases in the sequence tantalum > niobium > zirconium.

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Zusammenfassung Die Extraktion von Zirkonium, Niob und Tantal aus oxalsauren und fluorwasserstoffsauren Lösungen mit Hilfe einer chloroformischen Lösung von 2-Carbäthoxy-5-hydroxy-(4-tolyl)-4-pyridon wurde untersucht. Ein Extraktionsmechanismus für Zirkonium aus Oxalatlösungen und für Niob aus Fluoridlösungen wurde vorgeschlagen. Die Trennung von Zirkonium und Niob aus einer Oxalatlösung oder aus einer Fluoridlösung sowie von Tantal und Niob aus einer Fluoridlösung wurde beschrieben. Die Rückextraktion dieser Metalle mit Flußsäure und Oxalsäure ist möglich. Die Ergebnisse zeigen, daß die Effizienz der Extraktion in der Reihenfolge Tantal > Niob > Zirkonium abfällt.

     

Studies of CoQ10 and cyclodextrin complexes: solubility, thermo- and photo-stability

The complexes of coenzyme Q10 with β- and γ-cyclodextrin in aqueous solutions were prepared in order to improve the water solubility, thermo- and photo-stability of coenzyme Q10. Complex formation resulted in an increase in water solubility at room temperature and pH 6.5 by a factor at least 10². The solubility of coenzyme Q10 in the presence of cyclodextrins linearly increases with temperature and pH. The UV light (λ = 254) and temperature together have a great effect on coenzyme Q10 stability. After 120 min of exposure at 80 °C and UV light about 72.3% of pure coenzyme Q10 was degraded. Thermo- and photo-stability was strongly improved by complex formation; more than 64% of coenzyme Q10 remained unchanged. The formation of complexes was evaluated using IR spectrometry, X-ray diffractometry and TGA/DSC analysis.     

Finite 2-groups all of whose nonmetacyclic subgroups are generated by involutions

We classify here nonmetacyclic finite 2-groups all of whose nonmetacyclic subgroups are generated by involutions (Theorem 1.1). This solves problem Nr. 710 for p = 2 stated by Y. Berkovich in [1]. For p > 2 the corresponding problem is open. Received: 14 March 2007 Revised: 15 April 2007     

Experimental and numerical investigations of crimped end fittings

The paper deals with numerical and experimental investigations of steel made hulls crimped onto glass fibre reinforced plastic rods. The aim is to optimize the crimping procedure to realize maximum pull out forces of the specimens. The numerical simulations were performed with the commercial FEA package ABAQUS. For the contact formulation a Coulomb friction law with a constant friction coefficient was applied. The damage and fracture states within the composite rods due to the crimping process were investigated by scanning electron microscopy. The results obtained were discussed and an outlook to further work is given. (© 2008 WILEY-VCH Verlag GmbH & Co. KGaA, Weinheim)     

Bush‐type Hadamard matrices and symmetric designs

Abstact: A symmetric 2‐(100, 45, 20) design is constructed that admits a tactical decomposition into 10 point and block classes of size 10 such that every point is in either 0 or 5 blocks from a given block class, and every block contains either 0 or 5 points from a given point class. This design yields a Bush‐type Hadamard matrix of order 100 that leads to two new infinite classes of symmetric designs with parameters and where m is an arbitrary positive integer. Similarly, a Bush‐type Hadamard matrix of order 36 is constructed and used for the construction of an infinite family of designs with parameters and a second infinite family of designs with parameters where m is any positive integer. © 2000 John Wiley & Sons, Inc. J Combin Designs 9: 72–78, 2001     

The Existence of a Bush-Type Hadamard Matrix of Order 324 and Two New Infinite Classes of Symmetric Designs

A symmetric 2-(324, 153, 72) design is constructed that admits a tactical decomposition into 18 point and block classes of size 18 such that every point is in either 0 or 9 blocks from a given block class, and every block contains either 0 or 9 points from a given point class. This design is self-dual and yields a symmetric Hadamard matrix of order 324 of Bush type, being the first known example of a symmetric Bush-type Hadamard matrix of order 4n ² for n > 1 odd. Equivalently, the design yields a strongly regular graph with parameters v=324, k=153, ==72 that admits a spread of cocliques of size 18. The Bush-type Hadamard matrix of order 324 leads to two new infinite classes of symmetric designs with parameters