全文获取类型
收费全文 | 964篇 |
免费 | 31篇 |
国内免费 | 2篇 |
专业分类
化学 | 718篇 |
晶体学 | 4篇 |
力学 | 21篇 |
数学 | 158篇 |
物理学 | 96篇 |
出版年
2021年 | 9篇 |
2020年 | 13篇 |
2019年 | 13篇 |
2018年 | 20篇 |
2017年 | 11篇 |
2016年 | 26篇 |
2015年 | 18篇 |
2014年 | 24篇 |
2013年 | 43篇 |
2012年 | 62篇 |
2011年 | 66篇 |
2010年 | 37篇 |
2009年 | 38篇 |
2008年 | 54篇 |
2007年 | 49篇 |
2006年 | 56篇 |
2005年 | 54篇 |
2004年 | 37篇 |
2003年 | 49篇 |
2002年 | 40篇 |
2001年 | 12篇 |
2000年 | 9篇 |
1999年 | 14篇 |
1998年 | 10篇 |
1997年 | 10篇 |
1996年 | 14篇 |
1995年 | 5篇 |
1994年 | 8篇 |
1993年 | 16篇 |
1992年 | 9篇 |
1991年 | 8篇 |
1990年 | 8篇 |
1989年 | 4篇 |
1988年 | 5篇 |
1987年 | 7篇 |
1985年 | 7篇 |
1984年 | 10篇 |
1982年 | 7篇 |
1981年 | 4篇 |
1980年 | 16篇 |
1979年 | 6篇 |
1978年 | 7篇 |
1977年 | 11篇 |
1976年 | 11篇 |
1975年 | 8篇 |
1974年 | 7篇 |
1973年 | 5篇 |
1972年 | 6篇 |
1965年 | 5篇 |
1926年 | 5篇 |
排序方式: 共有997条查询结果,搜索用时 15 毫秒
991.
Peter Politzer Jane S. Murray Fakher Abu‐Awwad 《International journal of quantum chemistry》2000,76(5):643-647
We have shown that the solvation energies of a group of 12 solutes in 7 different solvents can be presented analytically in terms of quantities computed at the density functional B3P86/6‐31+G** level for the isolated solute molecules. These quantities include the molecular surface area and several properties of the electrostatic potential on the surface, e.g., the most positive and negative values, the average deviation of the potential, the positive and negative portions of the surface, and their average potentials. Overall, the average absolute deviation of the predicted from the experimental solvation free energies is 0.25 kcal/mol; the poorest results are obtained for the solute butanone, for which the average absolute deviation is 0.63 kcal/mol. The forms of the relationships reflect the natures of the solute–solvent interactions; for the solvents with low dielectric constants, these are primarily global, involving extended portions of the molecular surfaces, whereas for the more polar solvents, site‐specific interactions also play key roles. © 2000 John Wiley & Sons, Inc. Int J Quant Chem 76: 643–647, 2000 相似文献
992.
The deformation of a knotted polymer under a stretching force is studied by modeling the deformed knot as a composite spring system. Our results predict that the elastic modulus of a knotted polymer is larger when compared to an equal‐length linear chain. More complex knots are in general stiffer. The increase in stiffness of knots relative to the linear chain is also derived. Monte Carlo simulations are also performed to investigate the streching of polymer knots. Chain lengths up to N = 82 and prime knots 01 , 31 , 41 , 51 , 61 and 81 are considered. Segregation of the crossings into a small tight region of the knot structure at strong forces is observed. The increase in stiffness predicted by the composite spring model agree well with the simulation data. Our simulation data show that the scaling laws proposed by de Gennes and Pincus for a single linear chain under traction force still hold for the knotted type polymers. 相似文献
993.
Edwin L. Thomas John T. Chen Mary Jane E. O'Rourke Christopher K. Ober Guoping Mao 《Macromolecular Symposia》1997,117(1):241-256
We report on the phase behavior and microdomain structure of two types of diblock copolymers containing a liquid crystal (LC) block joined to a flexible coil block. Consideration of the symmetry groups of the liquid crystalline phases and of the block copolymer microdomain structures provides a rationale for predicting the possible types of liquid crystalline block copolymer morphologies. Both previously reported and newly discovered structural types are identified. Possible organizational schemes are developed for the mesogens and periodic disclination defects with respect to the intermaterial dividing surfaces separating the liquid crystalline and flexible coil domains. The first type of copolymer investigated has a rod-like LC block whereas the second type copolymer has a side chain LC block. Five different rod-coil diblocks based on poly(hexyl isocyanate-b-styrene) P(HIC-b-S) were synthesized by anionic polymerization. Wavy lamellae, zig-zag and arrowhead microdomain morphologies corresponding to smectic-C and smectic-O structures were observed depending on the composition. These layered phases have the director (PHIC chain axis) tilted at various orientations with respect to the layer normal. Side-chain LC diblocks based on functionalized poly(isoprene-b-styrene) P(I-b-S) were also investigated. These polymers were synthesized using polymer analogous chemistry from P(I-b-S) precursors. Three different mesogenic groups were attached to the PI blocks: one based on biphenyl benzoate and two based on azobenzene. The microdomain structures found for the functionalized poly(isoprene side-chain LC-b-styrene) P(ILC-b-S) diblocks are typical of traditional coil-coil diblocks (lamellae and cylinders). However, these morphologies possess an additional smectic layering of the mesogens within the microdomains of the LC block. In the case of the rod-coil diblocks, the transformation from an initially isotropic state to the final microphase separated solid state occurs via nematic and then smectic liquid crystalline states, whereas for the side-chain LC-coil cases, the microphase separation transition occurs prior to development of orientational order. The long-range microdomain order of LC block-coil block copolymers can extend over very large distances due to the influence of the orientational ordering of the LC block. 相似文献
994.
Ben Dexter Annika Smith Rachel King Nathan J. Downs Catherine Jane Nikles Alfio V. Parisi Yik-Hong Ho Simone Lee Harrison 《Photochemistry and photobiology》2023,99(5):1352-1356
Skin cancer, the most prevalent cancer in Caucasians residing at low latitudes, can primarily be prevented by avoiding overexposure to sunlight. Serial cross-sectional observations were conducted at an outdoor motorsport event held in Townsville, Queensland each July (Southern winter) to determine whether sun-protection habits changed over time. Most (71.1%) of the 1337 attendees observed (97.6% lightly pigmented skin, 64.0% male) wore a hat (any style shading the face), while few (18.5%) wore three-quarter or full-length sleeves. While hat-wearing rates (any style) were similar in 2009 (326, 72.6%) and 2013 (625, 70.4%), the use of sun-protective styles (wide-brimmed/bucket/legionnaires) decreased from 29.2% to 18.6% over the same period, primarily because the use of sun-protective hats halved (from 28.7% to 14.0%) among females, while decreasing from 29.4% to 21.1% in males. Although relatively few individuals wore sun-protective (three-quarter-length or full-length) sleeves regardless of year (OR = 0.117, P < 0.0001), encouragingly, the use of sun-protective sleeves more than doubled between 2009 (10.5%) and 2013 (22.5%). Interestingly females, albeit the minority, at this sporting event were less likely to wear a hat (OR = 0.473, P < 0.0001) than males. These findings highlight the need for continued momentum toward skin cancer primary prevention through sun protection with a dedicated focus on outdoor sporting settings. 相似文献
995.
996.
Nerve conduits are used to reconnect broken nerve bundles and provide protection to facilitate nerve regeneration. However, the low degradation rate and regeneration rate, as well as the requirement for secondary surgery are some of the most criticized drawbacks of existing nerve conduits. With high processing flexibility from the photo-curability, poly (glycerol sebacate) acrylate (PGSA) is a promising material with tunable mechanical properties and biocompatibility for the development of medical devices. Here, polyvinylpyrrolidone (PVP), silver nanoparticles (AgNPs), and graphene are embedded in biodegradable PGSA matrix. The polymer composites are then assessed for their electrical conductivity, biodegradability, three-dimensional-printability (3D-printability), and promotion of cell proliferation. Through the four-probe technique, it is shown that the PGSA composites are identified as highly conductive in swollen state. Furthermore, biodegradability is evaluated through enzymatic degradation and facilitated hydrolysis. Cell proliferation and guidance are significantly promoted by three-dimensional-printed microstructures and electrical stimulation on PGSA composites, especially on PGSA-PVP. Hence, microstructured nerve conduits are 3D-printed with PGSA-PVP. Guided cell growth and promoted proliferation are subsequently demonstrated by Schwann cell culture combined with electrical stimulation. Consequently, 3D-printed nerve conduits fabricated with PGSA composites hold great potential in nerve tissue regeneration through electrical stimulation. 相似文献
997.