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941.
This paper reviews current understanding of the process of multiple photon excitation and dissociation of polyatomic molecules, whereby in the presence of an intense infrared laser field a molecule may absorb upwards of 30 photons. The application of this process to new photochemistry and in particular laser isotope separation will also be discussed. 相似文献
942.
Abhishek Roy Michael A. Hickner Brian R. Einsla William L. Harrison James E. McGrath 《Journal of polymer science. Part A, Polymer chemistry》2009,47(2):384-391
Partially disulfonated hydroquinone (HQ)‐based poly(arylene ether sulfone) random copolymers were synthesized and characterized for application as proton exchange membranes. The copolymer composition was varied in the degree of disulfonation. The copolymers were characterized by 1H NMR, Differential Scanning Calorimetry (DSC), and other analytical techniques. The copolymer with a 25% degree of disulfonation showed the best balance between water uptake and proton conductivity. The copolymers showed substantially reduced methanol permeability compared with Nafion® and satisfactory direct methanol fuel cell performance. The methanol selectivity improved significantly in comparison to Nafion® 117. At a given ionic composition, the HQ‐based system showed higher water uptake and proton conductivity than the biphenol‐based (BPSH‐xx) poly(arylene ether sulfone)s copolymers. © 2008 Wiley Periodicals, Inc. J Polym Sci Part A: Polym Chem 47: 384–391, 2009 相似文献
943.
Elodie Champarnaud Alice M.‐F. Laures Phil J. Borman Marion J. Chatfield James T. Kapron Mark Harrison Jean‐Claude Wolff 《Rapid communications in mass spectrometry : RCM》2009,23(1):181-193
For the determination of trace level impurities, analytical chemists are confronted with complex mixtures and difficult separations. New technologies such as high‐field asymmetric waveform ion mobility spectrometry (FAIMS) have been developed to make their work easier; however, efficient method development and troubleshooting can be quite challenging if little prior knowledge of the factors or their settings is available. We present the results of an investigation performed in order to obtain a better understanding of the FAIMS technology. The influence of eight factors (polarity of dispersion voltage, outer bias voltage, total gas flow rate, composition of the carrier gas (e.g. %He), outer electrode temperature, ratio between the temperatures of the inner and outer electrodes, flow rate and composition of the make‐up mobile phase) was assessed. Five types of responses were monitored: value of the compensation voltage (CV), intensity, width and asymmetry of the compensation voltage peak, and resolution between two peaks. Three types of studies were performed using different test mixtures and various ionisation modes to assess whether the same conclusions could be drawn across these conditions for a number of different types of compounds. To extract the maximum information from as few experiments as possible, a Design of Experiment (DoE) approach was used. The results presented in this work provide detailed information on the factors affecting FAIMS separations and therefore should enable the user to troubleshoot more effectively and to develop efficient methods. Copyright © 2008 John Wiley & Sons, Ltd. 相似文献
944.
Tony Bristow Mark Harrison Martin Sims 《Rapid communications in mass spectrometry : RCM》2010,24(11):1673-1681
Accurate mass measurement (used to determine elemental formulae) is an essential tool for impurity identification in pharmaceutical development for process understanding. Accurate mass liquid chromatography/mass spectrometry (LC/MS) is used widely for these types of analyses; however, there are still many occasions when gas chromatography (GC)/MS is the appropriate technique. Therefore, the provision of robust technology to provide accurate mass GC/MS (and GC/MS/MS) for this type of activity is essential. In this report we describe the optimisation and application of a newly available atmospheric pressure chemical ionisation (APCI) interface to couple GC to time‐of‐flight (TOF) MS. To fully test the potential of the new interface the APCI source conditions were optimised, using a number of standard compounds, with a variety of structures, as used in synthesis at AstraZeneca. These compounds were subsequently analysed by GC/APCI‐TOF MS. This study was carried out to evaluate the range of compounds that are amenable to analysis using this technique. The range of compounds that can be detected and characterised using the technique was found to be extremely broad and include apolar hydrocarbons such as toluene. Both protonated molecules ([M + H]+) and radical cations (M+.) were observed in the mass spectra produced by APCI, along with additional ion signals such as [M + H + O]+. The technique has been successfully applied to the identification of impurities in reaction mixtures from organic synthesis in process development. A typical mass accuracy of 1–2 mm/zunits (m/z 80–500) was achieved allowing the reaction impurities to be identified based on their elemental formulae. These results clearly demonstrate the potential of the technique as a tool for problem solving and process understanding in pharmaceutical development. The reaction mixtures were also analysed by GC/electron ionisation (EI)‐MS and GC/chemical ionisation (CI)‐MS to understand the capability of GC/APCI‐MS relative to these two firmly established techniques. Copyright © 2010 John Wiley & Sons, Ltd. 相似文献
945.
946.
Jin Ho Kang Cheol Park Jonathan A. Scholl Amy H. Brazin Nancy M. Holloway James W. High Sharon E. Lowther Joycelyn S. Harrison 《Journal of Polymer Science.Polymer Physics》2009,47(10):994-1003
A systematic study of the effect of single wall carbon nanotubes (SWCNTs) on the enhanced piezoresistive sensitivity of polyimide nanocomposites from below to above percolation was accomplished. The maximum piezoresistive stress coefficient (Π) of 1.52 × 10?3 MPa?1 was noted at just above the percolation threshold concentration (Φ ~ 0.05 wt %) of SWCNT. This coefficient value exceeds those of metallic piezoresistive materials by two orders of magnitude (4.25 × 10?5 MPa?1 for aluminum). The high piezoresistive characteristics appear to originate from a change in the intrinsic resistivity of the composite caused by the variation of the tunneling distance between conducting inclusions (SWCNTs) under compression or tension. © 2009 Wiley Periodicals, Inc. J Polym Sci Part B: Polym Phys 47: 994–1003, 2009 相似文献
947.
948.
P. Lemeland Y. Shimidzu A. Grigaut A. Mayer G. Schaeffer A. Neumann J. P. Gregersen H. S. Raper S. Posternak L. Grimbert M. Laudat M. Tamura G. Blix A. Fleisch H. Forster A. Löw A. Fölling C. P. Steward A. C. White A. Hugo T. Theorell E. Gorter F. Grendel Ph. Bamberger N. D. Zelinsky Sch R. Zinzadze E. Herzfeld Orla-Jensen H. M. Höyberg G. C. Supplee B. Bellis F. S. Fowweather G. J. Saxon Cammidge und G. A. Harrison 《Fresenius' Journal of Analytical Chemistry》1928,75(3-4):144-160
Ohne Zusammenfassung 相似文献
949.
On-board generation of a set of calibration standards was demonstrated within a microfluidic device designed to perform immunoassay. Electrokinetic flow was used to proportionally mix the antibody (Ab) to bovine serum albumin (BSA) and a diluting buffer, to provide varying Ab concentrations for downstream mixing with fluorescently labeled BSA (BSA*). Mixing ratios were determined from electrical impedance modeling of the fluidic network using P-SPICE software, and peak heights for the labeled species were analyzed relative to the concentration calculated from the model. For dilution and separation of fluorescently labeled amino acids, a linear calibration curve was obtained for mixing ratios of 0.118 to 7.46. A linear calibration curve was obtained for the immunoassay calibration using dilution ratios between 0.197 and 5.077. Deviations were observed at larger extremes, possibly due to leakage effects at intersections. Peak height reproducibility was +/- 3% for the immunoassay, using diluted monoclonal Ab in mouse ascites fluid as the analyte. Recovery for on-chip calibration was 92 +/- 6% versus calibrants prepared off-chip, indicating a small bias. 相似文献
950.