Extraction of uranium (VI), plutonium (IV) and some fission products by tri-iso-amyl phosphate

The extractive properties of tri-isoamyl-phosphate (TAP), an indigenously prepared extractant, and the loading capacity of extraction solvent containing TAP for U(VI) and Pu(IV) ions in nitric solution have been investigated. The dependence of the distribution ratio on the concentration of nitric acid showed that TAP has an ability to extract these actinides, while the fission product contaminants are poorly extracted. The distribution data revealed a quantitative extraction of both U(VI) and Pu(IV) from moderate nitric acidities in the range 2–7 mol · dm^–3. Slope analysis proved predominant formation of the disolvated organic phase complex of the type UO₂(NO₃). 2TAP and Pu(NO₃)₄·2TAP with U(VI) and PU(IV), respectively. On the contrary, the extraction of fission product contaminants such as¹⁴⁴Ce,¹³⁷Cs,⁹Nb.,¹⁴⁷Pr,¹⁰⁶Ru,⁹⁵Zr was almost negligible even at very high nitric acid concentrations in the aqueous phase indicating its potential application in actinide partitioning. The recovery of TAP from the loaded actinides could be easily accomplished by using a dilute sodium carbonate solution or acidified distiled water (0.01 mol · dm^–3 HNO₃) as the strippant for U(VI) and using uranous nitrate or ferrous sulphamate as that for Pu(IV). Radiation stability of TAP was adequate for most of the process applications.     

Extractive—spectrophotometric determination of americium at trace levels with arsenazo-III

Americium(III) can be quantitatively extracted with 1 M diisoamylsulphoxide in Solvesso-100 from aqueous 0.02 M HNO₃—2.5 Al(NO₃)₃ solutions and, after dilution of the extract with ethanol and nitric acid, determined in the organic phase with arsenazo-III. The apparent molar absorptivity is 1.58 × 10⁵ l mol^-1 cm^-1 at 652 nm. The system obeys Beer's law within the range 0.1–1.6 μg Am ml^-1; 0.11 μg Am ml^-1 is determined with a reproducibility better than ±2%. Relatively large amounts of Ca(II), Cr(III), Fe (III), U(VI), Cl^-, NO₂^-, NO₃^- and F^- are tolerated. Interferences of Ce(IV), Pu(IV) and Th(IV) are eliminated by prior extraction with 2-thenoyltrifluoroacetone; only europium(III) interferes appreciably. Colour development is almost instantaneous and absorbances are virtually constant for 12 h.     

Stereospecific solid-state NaBH4-promoted reduction of 1-methylpentacyclo[5.4.0.02,6.03,10.05,9]undecane-8,11-dione

NaBH₄ reduction of a cage dione proceeds in a stereospecific fashion to give theendo,endo-diol. This reactivity is related to the crystal structure.     

Novel symmetries in the modified version of two dimensional Proca theory

The European Physical Journal C - We present a study of the expected precision of the top quark mass determination, measured at a linear e + e − collider based on CLIC technology....     

Investigation of W/O microemulsion droplets by contrast variation light scattering

Dynamic and static light scattering experiments have been performed at various molar ratios (γ) of water to AOT and temperatures on water-in-oil (W/O) microemulsions dispersed in n-heptane, n-octane, and n-nonane. Size and shape fluctuations of microemulsion droplets are determined with very high precision because polydispersity influences the characteristic features of scattering data as well as the hydrodynamic radius withγ. Self-consistent interpretation of dynamic and static light scattering data using optical properties and packing consideration on the basis of the layered sphere model are obtained. The estimated extent of polydispersity index of 17% is found, whereas the polydispersity is independent of the alkane types. The geometrical parameters, e.g., hydrodynamic radius, area per head group of the surfactant molecule and thickness of the surfactant layer of microemulsion droplets are also estimated and compared in three different n-alkane types. The best interpretation of the temperature dependence of data has shown a transition from spherical droplets to ellipsoid aggregates with increasing temperature. Axial ratio increases with increase of temperature and the longer the alkane the larger is the axial ratio. The parameters describing the polydispersity and shape change are in agreement with theoretical and experimental results found in the literature     

A comparative study of PFP and BAB models in predicting the excess thermo-acoustical and its allied properties of liquid ternary mixtures at 298.15 K

Densities and speed of sound were measured for six binaries and three ternary liquid systems. Excess acoustical and its allied properties like excess internal pressure, excess thermal pressure coefficient, excess pseudo-Gruneisen parameter, excess speed of sound and excess ultrasonic impendence, were evaluated with the help of perspective of two liquid models i.e. Prigogine–Flory–Patterson (PFP) and Bertrand–Acree–Bruchfield (BAB) at 298.15 K over a wide range of composition. The results so obtained from two liquid models are very much comparable and are in good agreement. A molecular interaction study has also been made successfully in the light of these excess acoustical properties.     

Experimental investigations of the nuclear level density by using heavy ion reactions

The transition of the level density parameter a _off from the low excitation energy value a _off=A/8 MeV⁻¹ to the Fermi gas value a _FG ∼ A/15 MeV⁻¹ was discovered a few years ago studying particle spectra evaporated from hot compound systems of A∼ 160. A number of experiments have been recently performed to confirm the earlier findings and extend the investigation to other mass regions and to higher excitation energies. Furthermore, precision coincidence experiments have been done in the lead region in which evaporation residues are tagged by low energy gammarays. Those experiments open the possibility of a detailed study of the level densities in nuclei where the shell effects are important.     

A new approach for improving ballistic performance of composite armor

An experimental investigation of the ballistic performance of composite armor with geometric modifications was carried out. The armor was simulated using polymeric materials. Four different geometric modifications were incorporated into the front plate of the armor, and two different adhesives were considered in this study. High-speed photography was employed to observe the real-time evolution of impact damage and to obtain the projectile penetration history. The nature and extent of damage for each modification and adhesive was estimated by postmortem inspection of the impacted armor and was compared to that obtained in unmodified armor of equal weight. The results of the study indicate that the geometric modifications after the nature and extent of damage significantly compared to conventional composite armor. The strong adhesive causes tearing of the back plate, whereas the compliant adhesive results in extensive delamination without any back plate damage. The modifications assist in spreading the damage laterally away from the impact site, thus distributing the load onto a larger area of the back plate. Calculations using a one-dimensional theoretical model also conclude that geometrical modifications improve the ballistic performance of the armor.     

Influence of hydrodynamic slip on convective transport in flow past a circular cylinder

The presence of a finite tangential velocity on a hydrodynamically slipping surface is known to reduce vorticity production in bluff body flows substantially while at the same time enhancing its convection downstream and into the wake. Here, we investigate the effect of hydrodynamic slippage on the convective heat transfer (scalar transport) from a heated isothermal circular cylinder placed in a uniform cross-flow of an incompressible fluid through analytical and simulation techniques. At low Reynolds (\({\textit{Re}}\ll 1\)) and high Péclet (\({\textit{Pe}}\gg 1\)) numbers, our theoretical analysis based on Oseen and thermal boundary layer equations allows for an explicit determination of the dependence of the thermal transport on the non-dimensional slip length \(l_s\). In this case, the surface-averaged Nusselt number, Nu transitions gradually between the asymptotic limits of \(Nu \sim {\textit{Pe}}^{1/3}\) and \(Nu \sim {\textit{Pe}}^{1/2}\) for no-slip (\(l_s \rightarrow 0\)) and shear-free (\(l_s \rightarrow \infty \)) boundaries, respectively. Boundary layer analysis also shows that the scaling \(Nu \sim {\textit{Pe}}^{1/2}\) holds for a shear-free cylinder surface in the asymptotic limit of \({\textit{Re}}\gg 1\) so that the corresponding heat transfer rate becomes independent of the fluid viscosity. At finite \({\textit{Re}}\), results from our two-dimensional simulations confirm the scaling \(Nu \sim {\textit{Pe}}^{1/2}\) for a shear-free boundary over the range \(0.1 \le {\textit{Re}}\le 10^3\) and \(0.1\le {\textit{Pr}}\le 10\). A gradual transition from the lower asymptotic limit corresponding to a no-slip surface, to the upper limit for a shear-free boundary, with \(l_s\), is observed in both the maximum slip velocity and the Nu. The local time-averaged Nusselt number \(Nu_{\theta }\) for a shear-free surface exceeds the one for a no-slip surface all along the cylinder boundary except over the downstream portion where unsteady separation and flow reversal lead to an appreciable rise in the local heat transfer rates, especially at high \({\textit{Re}}\) and Pr. At a Reynolds number of \(10^3\), the formation of secondary recirculating eddy pairs results in appearance of additional local maxima in \(Nu_{\theta }\) at locations that are in close proximity to the mean secondary stagnation points. As a consequence, Nu exhibits a non-monotonic variation with \(l_s\) increasing initially from its lowermost value for a no-slip surface and then decreasing before rising gradually toward the upper asymptotic limit for a shear-free cylinder. A non-monotonic dependence of the spanwise-averaged Nu on \(l_s\) is observed in three dimensions as well with the three-dimensional wake instabilities that appear at sufficiently low \(l_s\), strongly influencing the convective thermal transport from the cylinder. The analogy between heat transfer and single-component mass transfer implies that our results can directly be applied to determine the dependency of convective mass transfer of a single solute on hydrodynamic slip length in similar configurations through straightforward replacement of Nu and \({\textit{Pr}}\) with Sherwood and Schmidt numbers, respectively.     

Magnetic and Magnetodielectric Properties of Ho<Subscript>0.5</Subscript>Nd<Subscript>0.5</Subscript>Fe<Subscript>3</Subscript>(BO<Subscript>3</Subscript>)<Subscript>4</Subscript>

The magnetic and magnetodielectric properties of Ho_0.5Nd_0.5Fe₃(BO₃)₄ ferroborate with the competing Ho–Fe and Nd–Fe exchange couplings have been experimentally and theoretically investigated. Step anomalies in the magnetization curves at the spin-reorientation transition induced by the magnetic field B ║ c have been found. The spontaneous spin-reorientation transition temperature T_SR ≈ 8 K has been refined. The measured magnetic properties and observed features are interpreted using a single theoretical approach based on the molecular field approximation and calculations within the crystal field model of the rare-earth ion. Interpretation of the experimental data includes determination of the crystal field parameters for Ho³⁺ and Nd³⁺ ions in Ho_0.5Nd_0.5Fe₃(BO₃)₄ and parameters of the Ho–Fe and Nd–Fe exchange couplings.