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101.
Kazuaki Fukamichi Hidetoshi Hiroyoshi Michio Kikuchi Tsuyoshi Masumoto 《Journal of magnetism and magnetic materials》1979,10(2-3):294-299
The thermal expansion and magnetic properties of Fe-B and Fe-P amorphous alloys prepared from melts have been investigated. These amorphous alloys show distinct Invar characteristics. heir magnetic properties are also very similar to those of Fe-Ni crystalline Invar alloys; that is, the high-field susceptability and forced-volume magnetostriction are remarkably large, the magnetic moment per Fe atom does not increase linearly, the Curie temperature decreases with a decrease in concentration of B or P, and their reduced their magnetization curves are much flatter than those of crystalline pure Fe. 相似文献
102.
Y. Nakagawa Y. Tanji H. Morita H. Hiroyoshi H. Fujimori 《Journal of magnetism and magnetic materials》1979,10(2-3):145-151
Fe-Ni Invar alloys exhibit anomalies in thermodynamic and physical properties at high temperatures. This is considered to result from the tendency to two-phase separation in the fcc phase. This idea is supported also by interdiffusion experiments in the Fe-Ni system, where the interdiffusion coefficient is anomalously small in the Invar region at lower temperatures. A simple theory of regular solutions based on a pair interaction model is applied to the Fe-Ni system; with the assumption of two gamma states this gives a miscibility gap in the Invar region. 相似文献
103.
104.
(+)-Cerulenin was synthesized stereoselectively from D-glucose. 相似文献
105.
Four kinds of vinyl polymers containing N-substituted phenothiazinyl groups in side chains were obtained by syntheses of the respective monomers and subsequent polymerizations. Thus, N-acrylamidomethylphenothiazine, N-(N-acrylamidomethyl)carbamoylethyl phenothiazine, β-(N-phenothiazinyl)ethyl acrylate and methacrylate, and β-(N-phenothiazinyl)ethyl vinyl ether were synthesized. It was found that all monomers except the last monomer can be polymerized with typical free-radical initiators such as α,α′-azobisisobutyronitrile to afford stable soluble polymers with electron-donating characteristics, presumably due to the absence of a hydrogen atom at the site of the nitrogen atom of the phenothiazinyl group. The last monomer was found to be susceptible to typical cationic initiators such as boron trifluoride etherate to afford a stable soluble polymer also with the electron-donating characteristic. 相似文献
106.
107.
Electronic absorption and magnetic circular dichroism (MCD) spectra in UV-vis region of Waugh-structure [XMo9O32]6?(X = Ni(IV), Mn(IV)) ion in aqueous solution and solid IR spectra have been measured. The Ni(IV) ion in the polyanion has a low-spin d6 electronic configuration and the Mn(IV) ion has a d3 configuration. Visible absorption spectrum of the nickelate(IV) polyanion is interpreted to be mainly governed by charge-transfer transitions of the “ligand”, Mo9O32, to Ni(IV) ion, rather than d-d transitions, while visible absorption of the manganate(IV) polyanion is governed, to a great extent, by d-d transitions. It is indicated by the MCD spectrum that the splitting of the first d-d absorption in the manganate(IV) polyanion is due to a contribution of the spin-forbiden transition, rather than from a trigonal splitting of the spin-allowed transition. Absorption and MCD spectra in UV region are due to charge-transfer transition within a common “ligand”, which are less influenced by the kind of heteroatom, Ni(IV) or Mn(IV). The MCD pattern by the intra-ligand charge-transfer is especially characteristic of the Waugh-structure polyanions. 相似文献
108.
109.
Hiroyoshi?Mitake Kohei?SogaEmail author 《Calculus of Variations and Partial Differential Equations》2018,57(3):78
Weak KAM theory for discounted Hamilton–Jacobi equations and corresponding discounted Lagrangian/Hamiltonian dynamics is developed. Then it is applied to error estimates for viscosity solutions in the vanishing discount process. The main feature is to introduce and investigate the family of \(\alpha \)-limit points of minimizing curves, with some details in terms of minimizing measures. In error estimates, the family of \(\alpha \)-limit points is effectively exploited with properties of the corresponding dynamical systems. 相似文献
110.
Takeshi Takematsu Hiroyuki Okada Hiroyoshi Onnagawa 《Molecular Crystals and Liquid Crystals》2013,570(1):817-824
Abstract Modulated microdomain switching of nematic liquid crystals have been investigated. This display mode used for light switching of micron-sized domains regions using a complicated electric field with special mesh electrode structures. Under He-Ne laser irradiation, contrast ratio was 22:1 for homeotropic alignment cell and transmittance change was no dependent of incident polarization condition. Under white light illumination, the contrast ratio was 4.3:1. 相似文献