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431.
Tran Duc Thiep Truong Thi An Nguyen Tuan Khai Nguyen The Vinh Phan Viet Cuong I. P. Gangrski I. E. Penhionzkevich G. V. Mishinski V. I. Zemenhik 《Journal of Radioanalytical and Nuclear Chemistry》2010,285(3):511-517
The ratio of the probabilities of population of the isomeric and ground states, so called the isomeric ratio is closely connected to the angular momentum of the initial fission fragments that is dissipated at the later stages of gamma ray cascade. This ratio also provides important information on the nuclear level structure as well as the nuclear reaction mechanism involved. In this work, the isomeric ratio in fission fragment 135Xe from photofission of 233U induced by 23.5 MeV bremsstrahlung has been determined by the method that uses inert gaseous flow. The results have been discussed and compared with that of other authors. 相似文献
432.
Brayner R Iglesias R Truong S Beji Z Felidj N Fiévet F Aubard J 《Langmuir : the ACS journal of surfaces and colloids》2010,26(22):17465-17469
Silver nanostructured films were directly prepared by spray deposition of preformed polyol-based Ag-PVP nanoparticles. These homogeneous films of high optical quality were tested as SERS-active substrates. Laser excitation at 514.5 nm within the red part of the plasmon band leads to intense and reproducible SERS spectra of acridine, used as the probe molecule. From SERS measurements at different pH values, it was possible to determine the apparent pK(a) of acridine and to obtain specific surface properties of the film. Finally, these SERS titrations along with enhancement factor estimates allowed us to further depict the nature of the films. 相似文献
433.
This paper concerns the study of the so-called super minimizers related to the concept of super efficiency in constrained
problems of multiobjective optimization, where cost mappings are generally set-valued. We derive necessary conditions for
super minimizers on the base of advanced tools of variational analysis and generalized differentiation that are new in both
finite-dimensional and infinite-dimensional settings for problems with single-valued and set-valued objectives.
相似文献
434.
435.
Kinetics of the β-scission in alkyl radical reaction class was studied using the reaction class transition state theory (RC-TST) combined with the linear energy relationship (LER) and the barrier height grouping (BHG) approach. All necessary parameters were derived from first-principle density functional calculations for a representative set of 21 reactions. Different error analyses and comparisons with available literature data were made. Direct comparison with available experimental data indicates that the RC-TST/LER, where only reaction energy is needed, can predict rate constants for any reaction in this reaction class with excellent accuracy. Specifically for this reaction class, the RC-TST/LER method has less than 60% systematic errors on average in the predicted rate constants when compared to explicit rate calculations. 相似文献
436.
The salts K[AuCl(2)(CN)(2)]·H(2)O (1), K[AuBr(2)(CN)(2)]·2H(2)O (2) and K[AuI(2)(CN)(2)]·?H(2)O (3) were synthesized and structurally characterized. Compound 1 crystallizes as a network of square planar [AuCl(2)(CN)(2)](-) anions separated by K(+) cations. However, 2 and 3 feature 2-D sheets built by the aggregation of [AuX(2)(CN)(2)](-) anions via weak, intermolecular X···X interactions. The mixed anion double salts K(3)[Au(CN)(2)](2)[AuBr(2)(CN)(2)]·H(2)O (4) and K(5)[Au(CN)(2)](4)[AuI(2)(CN)(2)]·2H(2)O (5) were also synthesized by cocrystallization of K[Au(CN)(2)] and the respective K[AuX(2)(CN)(2)] salts. Similarly to 2 and 3, the [Au(CN)(2)](-) and [AuX(2)(CN)(2)](-) anions form 2-D sheets via weak, intermolecular Au(I)···X and Au(I)···Au(I) interactions. In the case of 5, a rare unsupported Au(I)···Au(III) interaction of 3.5796(5) ? is also seen between the two anionic units. Despite the presence of Au(I) aurophilic interactions of 3.24-3.45 ?, neither 4 nor 5 exhibit any detectable emission at room temperature, suggesting that the presence of Au(I)···X or Au(I)···Au(III) interactions may affect the emissive properties. 相似文献
437.
Tai TB Ceulemans A Nguyen MT 《Chemistry (Weinheim an der Bergstrasse, Germany)》2012,18(15):4510-4512
The presence of excess electrons modifies the structural landscape and tends to extend the planarity of boron clusters. While the neutral B(20) is tubular, both the anion and dianion B(20)(-/2-) become planar. Geometrical features of the stable anions suggest the existence of a new type of cluster that is planar and doubly cyclic with one atom located at the center (see figure), as well as being fluxional. 相似文献
438.
439.
This paper presents an application of the reaction class transition state theory (RC-TST) to predict thermal rate constants for hydrogen abstraction reactions of the type OH + alkane --> HOH + alkyl. We have derived all parameters for the RC-TST method for this reaction class from rate constants of 19 representative reactions, coupling with linear energy relationships (LERs), so that rate constants for any reaction in this class can be predicted from its reaction energy calculated at either the AM1 semiempirical or BH&HLYP/cc-pVDZ level of theory. The RC-TST/LER thermal rate constants for selected reactions are in good agreement with those available in the literature. Detailed analyses of the results show that the RC-TST/LER method is an efficient method for accurately estimating rate constants for a large number of reactions in this class. Analysis of the LERs leads to the discovery of the beta-carbon radical stabilization effect that stabilizes the transition state of any reaction in this class that yields products having one or more beta-carbons, and thus leads to the lower barrier for such a reaction. 相似文献
440.
Tran Duc Thiep Truong Thi An Nguyen Tuan Khai Phan Viet Cuong Nguyen The Vinh A. G. Belov O. D. Maslov 《Journal of Radioanalytical and Nuclear Chemistry》2012,292(3):1035-1042
We have determined the isomeric ratios in 74Se(γ, n)73m,gSe and 82Se(γ, n)81m,gSe photonuclear reactions of natural Selenium induced by bremsstrahlungs with end-point energies in the giant dipole resonance
region. The investigated samples were irradiated at electron accelerator Microtron MT-25 of the Flerov Laboratory of Nuclear
Reaction, Joint Institute for Nuclear Research, Dubna, Russia. The gamma spectra of the samples irradiated were measured with
spectroscopic system consisting of 8,192 channel analyzer and high-energy resolution (180 keV at gamma ray 1,332 keV of 60Co) HP(Ge) semiconductor detector Canberra. The GENIE2000 (Canberra) computer program was used for data processing. The results
were discussed and compared with those of other authors. 相似文献