Defect-controlled transport properties of metallic atoms along carbon nanotube surfaces

The diffusion mechanism of indium atoms along multiwalled carbon nanotubes is studied by means of photoemission spectromicroscopy and density functional theory calculations. The unusually high activation temperature for diffusion (approximately 700 K), the complex C 1s and In 3d5/2 spectra, and the calculated adsorption energies and diffusion barriers suggest that the indium transport is controlled by the concentration of defects in the C network and proceeds via hopping of indium adatoms between C vacancies.     

Allocation strategies in hub networks

In this paper, we study allocation strategies and their effects on total routing costs in hub networks. Given a set of nodes with pairwise traffic demands, the p-hub median problem is the problem of choosing p nodes as hub locations and routing traffic through these hubs at minimum cost. This problem has two versions; in single allocation problems, each node can send and receive traffic through a single hub, whereas in multiple allocation problems, there is no such restriction and a node may send and receive its traffic through all p hubs. This results in high fixed costs and complicated networks. In this study, we introduce the r-allocation p-hub median problem, where each node can be connected to at most r hubs. This new problem generalizes the two versions of the p-hub median problem. We derive mixed-integer programming formulations for this problem and perform a computational study using well-known datasets. For these datasets, we conclude that single allocation solutions are considerably more expensive than multiple allocation solutions, but significant savings can be achieved by allowing nodes to be allocated to two or three hubs rather than one. We also present models for variations of this problem with service quality considerations, flow thresholds, and non-stop service.     

Determination of molybdenum in biological samples by flame atomic spectrometry after preconcentration on activated carbon

Abstract  

Molybdenum is well known for its toxic effects, although it is also essential for N₂-fixing cyanobacteria and several enzymes. This study proposes a simple and accurate procedure for separation, preconcentration, and determination of trace amounts of molybdenum in biological samples by flame atomic absorption spectrometry. It is based on complexation of Mo by cupferron and sorption onto activated carbon. Effects of parameters such as pH, stirring time, and amounts of activated carbon and cupferron on recovery were examined. The results demonstrated that Mo at pH range of 2.5–3.5 was quantitatively sorbed onto activated carbon as its cupferron complex. The optimum stirring time was found to be 30 min. The relative standard deviation was found to be 12% for 200 cm³ 50 ng/cm³ Mo using 10 replicate preconcentration procedures. The limits of detection and quantification were found to be 1.0 and 3 ng/cm³, respectively, by preconcentration of 200 cm³ initial sample to 2 cm³ final volume. As a result, an enrichment factor of 100-fold was achieved. The proposed preconcentration procedure was applied to determine Mo in biological samples such as vegetables, milk, and animal liver. The molybdenum concentrations were found (as μg/dm³ or μg/kg) in the range of 70–5,500 for plants, 3–124 for milk and milk powder, and 960 for liver samples.     

The use of passive sampling to monitor spatial trends of volatile organic compounds (VOCs) at an industrial city of Turkey

Ambient concentrations of volatile organic compounds (VOCs) were measured using passive sampling technique at 49 sampling points in Kocaeli, an important industrial city in Turkey. Air samples were analyzed using thermal desorption (TD) and gas chromatography/flame ionization detectors (FID). Concentrations of benzene, toluene, ethylbenzene, m/p-xylenes, and o-xylene (BTEX), 1,3,5-trimethylbenzene, n-propylbenzene, 3-ethyltoluene, and 4-ethyltoluene were investigated to determine their spatial distribution and source apportionment. Concentrations of ΣBTEX ranged from 3.7 to 335.5 μg/m³. Among all the VOC species, m/p-xylene and toluene have the highest concentration. The spatial distributions for BTEX concentrations showed characteristic patterns: high concentrations were typically found along major roads, city centres, and near industrial plants. Pollution sources potentially affecting concentrations were identified using statistical analyses. The results of factor analysis indicated that vehicle exhaust and industrial activity were the predominant emission sources of the VOCs.     

Electronic absorption and Raman resonance scattering of spectroscopically pure SiO2

An ultraviolet absorption, as well as Stokes and anti-Stokes Raman resonance scattering of spectroscopically pure SiO2 was investigated by flash photolysis technique. The whole spectrum of 'absorption and scattered bands' was recorded photographically in ultraviolet. A resonance absorption line was observed at 288.2 nm, without structure, while scattered lines were observed at 285-288.2 and 288.2-290 nm.     

Variations in Toxic Metal Levels of Two Fish Species,Pomatomus saltatrix and Dicentrarchus labrax,and Risk Estimation for Children简

The concentrations of five toxic metals were monthly determined in two fish species, obtained from fish markets in Turkey during 2010—2011. For the determinations, AAS and ICP-AES were used. The obtained lead concentrations for all studied Pomatomus saltatrix (mean 635 μg·kg-1) and Dicentrarchus labrax (mean 463 μg·kg-1) samples were found to be significantly higher than the maximum allowances concentration (MAC) of 300 μg·kg-1. Mean chromium (324 μg·kg-1) and Cu (940 μg·kg-1) concentrations in Pomatomus saltatrix were higher than in Dicentrarchus labrax (268 μg Cr·kg-1 and 600 μg Cu·kg-1) while Ni in Pomatomus saltatrix (216 μg·kg-1) was lower in Dicentrarchus labrax (291 μg·kg-1). The estimated non-carcinogenic and carcinogenic health risks by the Target Hazard Quotient and target carcinogenic risk indicate that there are no sytemic effects, and the risk of developing cancer over a human lifetime is between 2～9 in 1 000 000.     

Determination of Chlorine in Plastics via SrCl by Solid-Sampling High-Resolution Continuum Source Graphite Furnace Molecular Absorption Spectrometry

Solid sampling high resolution continuum source molecule absorption spectrometry (SS-HR-CS MAS) was applied for the determination of chlorine in plastic using the strontium monochloride (SrCl) molecule. For this purpose, 10?µL of 20?g L^?1 strontium (prepared from Sr(NO₃)₂) solution were pipetted with aqueous Cl standards or 0.05 to 4?mg of slivered plastic samples on a platform and introduced into the furnace. Chlorine was determined with the molecular absorption of SrCl at 635.862?nm using 1100?°C and 2200?°C for the pyrolysis and vaporization temperatures, respectively. Aqueous standards were used for calibration. The accuracy of the method was evaluated using a certified polyethylene reference material. The limit of detection and characteristic mass values of the method were 2.5?ng and 0.4?ng, respectively. The chlorine concentrations in various polyethylene beverage containers were determined.     

He—HF体系的结构和分析势能函数

利用Ｇｕａｓｓｉａｎ９４程序和ＱＣＩＳＤ／６－３１１＋＋Ｇ方法得到Ｈｅ－ＨＦ和Ｈｅ－ＦＨ两种线性平衡结构,计算出了这两种弱结合分子的结构参数、离解能和二阶力常数。在此基础上,利用多体项展式方法民出Ｈｅ－ＨＦ（Ｘ＾１Σ＾＋）体系的分析势能函数,得到的势能面准确地再现了Ｈｅ－ＨＦ和Ｈｅ－ＦＨ两种线性结构。     

Radiation‐grafted solid polymer electrolyte membrane: studies of fluorinated ethylene propylene (FEP) copolymer‐g‐acrylic acid grafted membranes and their sulfonated derivatives

Acrylic acid was grafted onto FEP by simultaneous radiation technique and the resulting membranes were sulfonated. Results of dynamic mechanical properties of the membranes showed that storage modulus and temperature at tan δ_(max) increases on grafting. X‐ray diffraction (XRD) analysis of the grafted and sulfonated membranes showed decreasing trend in crystallinity with increase in degree of grafting. From scanning electron microscopy (SEM) studies it was confirmed that grafting takes place by the front mechanism. Copyright © 2004 John Wiley & Sons, Ltd.