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71.
Let X1 be a random variable with density function f(t), Ψ(t) be an increasing absolutely continuous function, Φ(t) be the inverse function to Ψ(t), and X2 be the random variable X2 = Φ(X1). We consider the maximum likelihood estimator for the density ψ of the function Ψ in the case when we observe two independent samples from the distributions of X1 and X2. Under appropriate conditions on the involved distributions, we prove the consistency of the maximum likelihood estimator.
Bibliography: 1 title.
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Translated from Zapiski Nauchnykh Seminarov POMI, Vol. 320, 2004, pp. 160–165.
An erratum to this article is available at . 相似文献
72.
A high-performance liquid chromatographic method previously developed (Lozano et al. in J Chromatogr A 830:477–483, 1999) for simultaneous detection, identification and quantification of the secondary metabolites in commercial saffron was extended
for the detection of adulterated saffron prepared by adding styles colored with the natural colorants extracted from saffron
petals, safflower, madder and red beet. The chromatograms of the methanol-water (50%, v/v) extracts of pure and adulterated saffron were obtained at the assayed wavelengths, 402 (or 254), 260 and 535 (or 440) nm
and then by applying two-way analysis of variance (ANOVA) to the obtained data the presence of the styles colored with the
colorant of safflower (>14.3%), styles colored with the colorant of madder (>9.1%) and styles colored with the colorant of
red beet (>14.3%) in saffron were significantly detected. But the detection of adulterated saffron prepared with the colorant
of saffron petals was not successful. 相似文献
73.
Morteza Sheikhalipour Behrooz Esmaielpour Gholamreza Gohari Maryam Haghighi Hessam Jafari Habib Farhadi Muhittin Kulak Andrzej Kalisz 《Molecules (Basel, Switzerland)》2021,26(13)
High salt levels are one of the significant and major limiting factors on crop yield and productivity. Out of the available attempts made against high salt levels, engineered nanoparticles (NPs) have been widely employed and considered as effective strategies in this regard. Of these NPs, titanium dioxide nanoparticles (TiO2 NPs) and selenium functionalized using chitosan nanoparticles (Cs–Se NPs) were applied for a quite number of plants, but their potential roles for alleviating the adverse effects of salinity on stevia remains unclear. Stevia (Stevia rebaudiana Bertoni) is one of the reputed medicinal plants due to their diterpenoid steviol glycosides (stevioside and rebaudioside A). For this reason, the current study was designed to investigate the potential of TiO2 NPs (0, 100 and 200 mg L−1) and Cs–Se NPs (0, 10 and 20 mg L−1) to alleviate salt stress (0, 50 and 100 mM NaCl) in stevia. The findings of the study revealed that salinity decreased the growth and photosynthetic traits but resulted in substantial cell damage through increasing H2O2 and MDA content, as well as electrolyte leakage (EL). However, the application of TiO2 NPs (100 mg L−1) and Cs–Se NPs (20 mg L−1) increased the growth, photosynthetic performance and activity of antioxidant enzymes, and decreased the contents of H2O2, MDA and EL under the saline conditions. In addition to the enhanced growth and physiological performance of the plant, the essential oil content was also increased with the treatments of TiO2 (100 mg L−1) and Cs–Se NPs (20 mg L−1). In addition, the tested NPs treatments increased the concentration of stevioside (in the non-saline condition and under salinity stress) and rebaudioside A (under the salinity conditions) in stevia plants. Overall, the current findings suggest that especially 100 mg L−1 TiO2 NPs and 20 mg L−1 Cs–Se could be considered as promising agents in combating high levels of salinity in the case of stevia. 相似文献
74.
S. Mohammad Reza Seyedein Ghannad Mohammad Nader Lotfollahi Ali Haghighi Asl 《The Journal of chemical thermodynamics》2011,43(3):329-333
Experimental (liquid + liquid) equilibrium (LLE) data for a ternary system containing (ethylene glycol + benzene + cyclohexane) were determined at temperatures (298.15, 308.15, and 318.15) K and at atmospheric pressure. The experimental distribution coefficients and selectivity factors are presented to evaluate the efficiency of the solvent for extraction of benzene from cyclohexane. The effect of temperature in extraction of benzene from the (benzene + cyclohexane) mixture indicated that at lower temperatures the selectivity (S) is higher, but the distribution coefficient (K) is rather lower. The LLE results for the system studied were used to obtain binary interaction parameters in the UNIQUAC and NRTL models by minimizing the root mean square deviations (RMSD) between the experimental results and calculated results. Using the interaction parameters obtained, the phase equilibria in the systems were calculated and plotted. The NRTL model fits the (liquid + liquid) equilibrium data of the mixture studied slightly better. The root mean square deviations (RMSDs) obtained comparing calculated and experimental two-phase compositions are 0.92% for the NRTL model and 0.95% for the UNIQUAC model. 相似文献
75.
In this paper, we first investigate the stability of two weak second order methods introduced by Debrabant and Rößler (Appl Numer Math 59:582–594, 2009) and Platen (Math Comput Simulation 38:69–76, 1995). We then propose a new weak second order predictor-corrector method, with an improved stability properties, based on the Rößler’s method as the predictor and the implicit method of Platen as the corrector. The stability functions of these methods, applied to a scalar linear test equation with multiplicative noise, are determined and their regions of stability are then compared with the corresponding stability regions of the test equation. Furthermore, we also investigate mean square stability (MS-stability) of these methods applied to a linear Itô 2-dimensional stochastic differential test equation. Numerical examples will be presented to support the theoretical results. 相似文献
76.
Antifungal activity of TiO2/ZnO nanostructures under visible light irradiation was investigated. A simple chemical method was used to synthesize ZnO nanowires. Zinc acetate dihydrate, Polyvinyl Pyrrolidone and deionized water were used as precursor, capping and solvent, respectively. TiO2 nanoparticles were deposited on ZnO nanowires using an atmospheric pressure chemical vapor deposition system. X-ray diffraction pattern of TiO2/ZnO nano-composite has represented the diffraction peaks relating to the crystal planes of the TiO2 (anatase and rutile) and ZnO. TiO2/ZnO nanostructure antifungal effect on Candida albicans biofilms was studied and compared with the activity of TiO2 nanoparticles and ZnO nanowires. The high efficiency photocatalytic activity of TiO2 nanoparticles leads to increased antifungal activity of ZnO nanowires. Scanning electron microscope was utilized to study the morphology of the as prepared nanostructures and the degradation of the yeast. 相似文献
77.
Nanosized ZSM-5 type ferrisilicates were successfully prepared using hydrothermal process. Several parameters including gel initiative compositions (Na+ or K+ alkali system), SiO2/Fe2O3 molar ratios and hydrothermal temperature were systematically investigated. The samples were characterized by XRD, TEM, SEM-EDS, BET surface area and ICP techniques. It was found that surface areas and the total pore volume increase with increasing in the SiO2/Fe2O3 molar ratio at Na-FZ ferrisilicates. The catalytic performance of the synthesized catalysts was evaluated in ethylbenzene dehydrogenation to styrene in the presence of N2O or steam at temperatures ranging from 400 °C to 660 °C under atmospheric pressure. The effects of gel initiative compositions, SiO2/Fe2O3 molar ratio as well as the hydrothermal synthesis temperature on the catalytic performance of these catalysts have been addressed. It was shown that styrene yield significantly influenced by altering in the SiO2/Fe2O3 ratio but was not greatly influenced by changes in hydrothermal synthesis temperatures. The comparison between performance of potassium and sodium containing catalysts was shown that the one with potassium has higher yield and selectivity toward styrene production at an optimum temperature of 610 °C. 相似文献
78.
N. Nikkam M. Saleemi M. S. Toprak S. Li M. Muhammed E. B. Haghighi R. Khodabandeh B. Palm 《Journal of nanoparticle research》2011,13(11):6201-6206
Nanofluids, which are liquids with engineered nanometer-sized particles suspensions, have drawn remarkable attraction from
the researchers because of their enormous potential to enhance the efficiency in heat-transfer fluids. In the present study,
water-based calcined mesoporous silica nanofluids were prepared and characterized. The commercial mesoporous silica (MPSiO2) nanoparticles were dispersed in deionized water by means of pH adjustment and ultrasonic agitation. MPSiO2 nanoparticles were observed to have an average particle size of 350 ± 100 nm by SEM analysis. The concentration of MPSiO2 was varied between 1 and 6 wt%. The physicochemical properties of nanofluids were characterized using various techniques,
such as particle size analyzer, zeta-potential meter, TEM, and FT-IR. The thermal conductivity was measured by Transient Plane
Source (TPS) method, and nanofluids showed a higher thermal conductivity than the base liquid for all the tested concentrations. 相似文献
79.
Zahra Haghighi Amir-Hossein Karimy Farshad Karami Mohammadreza Khanmohammadi 《Natural product research》2019,33(7):1052-1060
AbstractThis paper addresses the application of infrared spectroscopy in combination with chemometrics to identify wall painting’s binding medium while employing pattern recognition techniques to process FTIR data-set of complex samples. In this regard, based on the historical documents and previous researches, firstly 56 standard samples were prepared to represent strata of Persian wall paintings in the Safavid period in addition to real historic samples from the case study; Sukias mansion. Then, each sample was analysed by the means of FTIR and chemometrics. Finally, SIMCA was applied to the whole region of studied IR spectra which predicted egg yolk as the binding medium of Sukias mansion samples. 相似文献
80.
Samira Chamyani Hamid R. Shahsavari Sedigheh Abedanzadeh Mohsen Golbon Haghighi Sepideh Shabani Behrouz Notash 《应用有机金属化学》2019,33(1)
Cyclometalated Pt (II) complexes [PtMe(C^N)(L)], in which C^N = deprotonated 2,2′‐bipyridine N‐oxide (Obpy), 1 , deprotonated 2‐phenylpyridine (ppy), 2 , deprotonated benzo [h] quinolone (bzq), 3 , and L = tricyclohexylphosphine (PCy3) were prepared and fully characterized. By treatment of 1–3 with excess MeI, the thermodynamically favored Pt (IV) complexes cis‐[PtMe2I(C^N)(PCy3)] (C^N = Obpy, 1a ; ppy, 2a ; and bzq, 3a ) were obtained as the major products in which the incoming methyl and iodine groups adopted cis positions relative to each other. All the complexes were characterized by means of NMR spectroscopy while the absolute configuration of 1a was further determined by X‐ray crystal structure analysis. The reaction of methyl iodide with 1–3 were kinetically explored using UV–vis spectroscopy. On the basis of the kinetic data together with the time‐resolved NMR investigation, it was established that the oxidative addition reaction occurred through the classical SN2 attack of Pt (II) center on the MeI reagent. Moreover, comparative kinetic studies demonstrated that the electronic and steric nature of either the cyclometalating ligands or the phosphine ligand influence the rate of reaction. Surprisingly, by extending the oxidative addition reaction time, very stable iodine‐bridged Pt (IV)‐Pt (IV) complexes [Pt2Me4(C^N)2(μ‐I)2] (C^N = Obpy, 1b ; ppy, 2b ; and bzq, 3b ) were obtained and isolated. In order to find a reasonable explanation for the observation, a DFT (density functional theory) computational analysis was undertaken and it was found that the results were consistent with the experimental findings. 相似文献