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11.
Efficient removal of hexavalent chromium and lead from aqueous solutions by s‐triazine containing nanoporous polyamide 下载免费PDF全文
s‐Triazine containing dicarboxylic acid was synthesized. Then, it was reacted with 1,3‐phenylenediamine in molten tetrabutylammonium bromide to formed soluble aromatic polyamide with good yield and moderate inherent viscosity of 0.35 dL g?1. The solubility and flexibility of polyamides are low. So, we used ether group such as di(4‐aminephenyl) ether in building polyamide. The structure of monomer and polymer was confirmed by Fourier transform infrared spectroscopy, elemental analysis, and proton nuclear magnetic resonance techniques. Thermogravimetric analysis was used to evaluate the thermal properties of synthesized polyamide, and their results show that this polymer had a good thermal stability. The surface morphology of s‐triazine containing polyamide was studied by field emission‐scanning electron microscopy and transmission electron microscopy, and the results show that it has a porous morphology and moderate Brunauer–Emmett–Teller specific surface (367 m2 g?1). It was further investigated for Pb (II) and Cr(VI) ion removal by optimizing the parameters including pH and contact time. The maximum uptakes of Pb(II) and Cr(VI) at pH 5.0 and pH 4.0 are 57% and 76%, respectively. Also, sorption kinetics of this polymer was investigated. Copyright © 2017 John Wiley & Sons, Ltd. 相似文献
12.
ZnO nanoparticles (nanoZnO) were decorated on multiwalled carbon nanotubes (MWCNTs) and then the prepared nano-hybrids, nanoZnO-MWCNTs, were immobilized on the surface of a glassy carbon electrode (GCE) to fabricate nanoZnO-MWCNTs modified GCE. The prepared electrode, GCE/nanoZnO-MWCNTs, showed excellent electrocatalytic activity towards luminol electrochemiluminescence (ECL) reaction. The electrode was then further modified with lactate oxidase and Nafion to fabricate a highly sensitive ECL lactate biosensor. Two linear dynamic ranges of 0.01-10 μmol L−1 and 10-200 μmol L−1 were obtained for lactate with the correlation coefficient better than 0.9996. The detection limit (S/N = 3) was 4 nmol L−1 lactate. The relative standard deviation for repetitive measurements (n = 6) of 10 μmol L−1 lactate was 1.5%. The fabrication reproducibility for five biosensors prepared and used in different days was 7.4%. The proposed ECL lactate biosensor was used for determination of lactate in human blood plasma samples with satisfactory results. 相似文献
13.
Incorporation of palladium nanoparticles on the surface of multi-walled carbon nanotubes and modification of glassy carbon electrode with the prepared nano-hybrid material led to the fabrication of a novel electrode. The modified electrode showed attractive electrocatalytic activity and sensitizing effect on luminol-O(2) and luminol-H(2)O(2) electrochemiluminescence (ECL) reactions at neutral media. The sensitized luminol-O(2) and luminol-H(2)O(2) reactions were successfully applied for the ECL determination of dissolved O(2) and glucose, respectively. Under the optimal conditions for luminol-O(2) system, the ECL signal intensity of luminol was linear with the concentration of dissolved oxygen in the range between 0.08 and 0.94 mM (r=0.9996) and for luminol-H(2)O(2) system, the ECL signal intensity of luminol was linear with the concentration of glucose in the range between 0.1 and 1000 μM (r=0.9998). The limits of detection (S/N=3) for dissolved oxygen and glucose were 0.02 mM and 54 nM, respectively. The relative standard deviations (RSD) for repetitive measurements of 0.50 mM oxygen (n=10) and 10 μM glucose (n=30) were 3.5% and 0.3%, respectively. Also, under the optimal conditions for luminol-H(2)O(2) system, the ECL signal intensity of luminol was linear with the concentration of H(2)O(2) in the range between 1 nM and 0.45 mM (r=0.9997). The limit of detection (S/N=3) for H(2)O(2) detection was 0.5 nM and the relative standard deviation for repetitive measurements of 10 μM H(2)O(2) (n=10) was 0.8%. 相似文献
14.
A graph of order is called degree-equipartite if for every -element set , the degree sequences of the induced subgraphs and are the same. In this paper, we characterize all degree-equipartite graphs. This answers Problem 1 in the paper by Grünbaum et al. [B. Grünbaum, T. Kaiser, D. Král, and M. Rosenfeld, Equipartite graphs, Israel J. Math. 168 (2008) 431–444]. 相似文献
15.
In this paper the analytical equation of state (EoS) proposed by Ihm‐Song‐Mason was applied to calculate molar volume of mixtures of carbon dioxide with nitrogen and methane. The pair interaction potential has been used to evaluate the second virial coefficients and the ISM EoS parameters (i.e. α and b). The calculated values of the aforesaid quantities were applied to predict the molar volumes for mixtures of carbon dioxide with nitrogen and methane. Agreement with experiment was excellent for both mixtures. 相似文献
16.
Majid M. Heravi Fatemeh Derikvand Masoumeh Haghighi 《Monatshefte für Chemie / Chemical Monthly》2008,139(1):31-33
Summary. An efficient and improved procedure for the synthesis of tetrasubstituted imidazoles by FeCl3 · 6H2O catalyzed four-component one-pot synthesis in refluxing ethanol is described. 相似文献
17.
We give a generalization of Eagon-Reiner’s theorem relating Betti numbers of the Stanley-Reisner ideal of a simplicial complex and the CMt property of its Alexander dual. Then we characterize bi-CMt bipartite graphs and bi-CMt chordal graphs. These are generalizations of recent results due to Herzog and Rahimi. 相似文献
18.
Marzieh Haghverdi Naeimeh Bahri-Laleh Mehdi Nekoomanesh Haghighi 《Journal of Coordination Chemistry》2018,71(8):1180-1192
Five 2-(1H-benzimidazol-2-yl)-phenol derivatives including 1H (HL1), 5-chloro-(HL2), 5-methyl-(HL3), 5,6-dichloro-(HL4), and 5,6-dimethyl-(HL5) were synthesized by the reaction of their corresponding benzene-1,2-diamine precursors and 2-hydroxybenzaldehyde which subsequently was employed in complexation with Fe(II) to prepare complexes C1–C5, respectively. Indeed, in all complexes, the ligands were coordinated as bidentate, via the C=N nitrogen and hydroxy oxygen atom of benzimidazole moiety and phenol ring, respectively. The compounds were characterized by FTIR, UV–vis, 1H- and 13C-NMR spectropscopy, ICP, and elemental analysis (C, H, and N). The purity of these compounds was determined by melting point (m.p )and TLC. The synthesized ligands and complexes were geometrically optimized by Gaussian09 software at B3LYP/TZVP level of theory and satisfactory theoretical–experimental agreement was achieved for analysis of IR data of the compounds. Catalytic behavior of the iron(II) complexes was investigated for ethylene reactivity. On activation with diethylaluminum chloride (Et2AlCl), iron(II) complex (C4) showed the highest activity (1686 kg oligomers.mol?1(Fe).h?1) for ethylene oligomerization when it contains chlorine substituents and exhibits good selectivity for linear 1-butene. The steric and electronic effects of ligands were investigated in detail on the influence of their catalytic activities. 相似文献
19.
Antonin Chapoy Hooman Haghighi Bahman Tohidi 《The Journal of chemical thermodynamics》2008,40(6):1030-1037
In this communication, we report new experimental data on n-pentane, i-pentane, cyclopentane, n-hexane, and toluene solubility in water at low temperature (below 298.15 K) and atmospheric pressure conditions. The new experimental data together with those reported in the literature have been used in developing a new equation for Henry’s constants of normal alkanes (methane to decane), BETEX compounds, and acid gases in aqueous phase over a wide range of temperature (typically from 273.15 K to 373.15 K). The new equation is based on a thermodynamic model, which uses the Peng–Robinson equation of state combined with the classical quadratic mixing rules for modelling non-aqueous phases, while the NRTL model is used to calculate the water activity.The predictions of the developed thermodynamic model are compared to the experimental data and the results of a thermodynamic approach, which uses the Valderrama modification of the Patel–Teja equation of state and non-density dependent mixing rules for modelling all fluid phases. Good agreement is observed between the experimental data and the model predictions. 相似文献
20.
Majid M. Heravi Fatemeh Derikvand Masoumeh Haghighi 《Monatshefte für Chemie / Chemical Monthly》2008,14(4):31-33
An efficient and improved procedure for the synthesis of tetrasubstituted imidazoles by FeCl3 · 6H2O catalyzed four-component one-pot synthesis in refluxing ethanol is described. 相似文献