Efficient preparation of carbohydrate- and related polyol-amphiphiles by hydrazone ligation

The hydrazone ligation can be used to couple clustered-glycosides or glycomimetics functionalized with a hydrazino group with lipophilic glyoxylyl acid derivatives to give the corresponding amphiphiles in high yield and purity.     

Selective double Suzuki cross-coupling reactions. Synthesis of unsymmetrical diaryl (or heteroaryl) methanes

Using a double Suzuki cross-coupling reaction ortho- or para-bromobenzyl bromides are easily transformed into unsymmetrical diaryl (or heteroaryl) methanes     

Decay of neutron-rich Ga isotopes near N = 50 at PARRNe

The PARRNe facility has been used to produce neutron-rich isotopes ^83,84Gaby the ISOL method. Their decay has been studied, and β-γ coincidence and γ-γ coincidence data were collected as a function of time. The first two excited levels in ⁸³Ge and the first excited level in ⁸⁴Ge have been measured for the first time.     

Factorization of operator valued Lp for 0 ≤ p < 1

In [5], it is proved that a bounded linear operator u, from a Banach space Y into an L_p(S, ν) factors through L_p1 (S, ν) for some p₁ > 1, if Y* is of finite cotype; (S, ν) is a probability space for p = 0, and any measure space for 0 < p < 1. In this paper, we generalize this result to uv, where u : Y → L_p(S, ν) and v : X → Y are linear operators such that v* is of finite Ka?in cotype. This result gives also a new proof of Grothendieck's theorem. (© 2004 WILEY‐VCH Verlag GmbH & Co. KGaA, Weinheim)     

Impact of Partial Separability on Large-Scale Optimization

ELSO is an environment for the solution oflarge-scale optimization problems. With ELSO the user is required to provide only code for the evaluation of a partially separable function. ELSO exploits the partialseparability structure of the function to computethe gradient efficiently using automatic differentiation.We demonstrate ELSO's efficiency by comparing thevarious options available in ELSO.Our conclusion is that the hybrid option in ELSOprovides performance comparable to the hand-coded option, while having the significantadvantage of not requiring a hand-coded gradient orthe sparsity pattern of the partially separable function.In our test problems, which have carefully coded gradients,the computing time for the hybrid AD option is within a factor of two of thehand-coded option.     

Real Paley-Wiener theorems associated with the weinstein operator

In this paper we use real analysis techniques to establish a new real Paley-Wiener theorems for the Fourier-Bessel transform associated with the Weinstein operator. More precisely we characterize the C ^∞-functions whose image under the Fourier-Bessel transform are functions with compact support through an L ^p growth condition, p ∈ [1, +∞] and we give another version of the real Paley-Wiener theorem for L ²-functions.     

The Matsumoto-Yor property and the structure of the Wishart distribution

This paper establishes a link between a generalized matrix Matsumoto-Yor (MY) property and the Wishart distribution. This link highlights certain conditional independence properties within blocks of the Wishart and leads to a new characterization of the Wishart distribution similar to the one recently obtained by Geiger and Heckerman but involving independences for only three pairs of block partitionings of the random matrix.In the process, we obtain two other main results. The first one is an extension of the MY independence property to random matrices of different dimensions. The second result is its converse. It extends previous characterizations of the matrix generalized inverse Gaussian and Wishart seen as a couple of distributions.We present two proofs for the generalized MY property. The first proof relies on a new version of Herz's identity for Bessel functions of matrix arguments. The second proof uses a representation of the MY property through the structure of the Wishart.