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61.
This paper deals with a phase transitions model describing the evolution of damage in thermoviscoelastic materials. The resulting system is highly non-linear, mainly due to the presence of quadratic dissipative terms and non-smooth constraints on the variables. Existence and uniqueness of a solution are proved, as well as regularity results, on a suitable finite time interval. 相似文献
62.
Giovanna Guidoboni Roland Glowinski Matteo Pasquali 《Journal of Computational and Applied Mathematics》2009,232(1):72-81
Free surface flows are pervasive in engineering and biomedical applications. In many interesting cases—particularly when small length scales are involved—surface forces (capillarity) dominate the flow dynamics. In these cases, computing the flow together with the shape of the surfaces, requires specialized solution techniques. This article investigates the capabilities of an operator splitting/finite elements method at handling accurately incompressible viscous flow with free surfaces at low capillary numbers. The test case of flow in the downstream section of a slot coater is used for three reasons: (1) it is an established benchmark; (2) it represents an idealized, yet industrially relevant flow; (3) high-fidelity results obtained with monolithic algorithms are available in literature. The flow and free surface shape attained with the new operator splitting scheme agree very satisfactorily with the results obtained with monolithic solvers. Because of its inherent computational simplicity, the new operator splitting scheme is attractive for large-scale simulations, three-dimensional flows, and flows of complex fluids. 相似文献
63.
Alessandro Sorrenti Marco Diociaiuti Valentina Corvaglia Pietro Chistolini Giovanna Mancini 《Tetrahedron: Asymmetry》2009,20(23):2737-2741
The recognition of the enantiomeric couples of ditryptophan in Langmuir films of N-hexadecanoyl-l-proline was investigated by surface pressure–area (π–A) isotherm measurements and Brewster angle microscopy experiments. The π–A isotherms relative to the films including the enantiomeric dipeptides show small differences whereas an evident enantiodiscrimination is observed by Brewster angle microscopy images. 相似文献
64.
65.
Chen‐Chang Lee Giovanna Grandinetti Patrick M. McLendon Theresa M. Reineke 《Macromolecular bioscience》2010,10(6):585-598
A versatile polycation scaffold that can easily be modified with targeting ligands has been designed, synthesized, and characterized. A series of galactose‐containing polymers has been produced to demonstrate the ease of modification of this polynucleotide delivery vehicle motif via the click reaction and to study how various structural modifications affect recognition by ASGPr on hepatocytes. A small library of structures was created where DCS and alkyl spacer length between the targeting group and the polymer backbone was varied. The novel polymer scaffold described proves to be a valuable tool for understanding structure/activity relationships of complexes made with receptor‐targeted polymers.
66.
Ylenia Pecci Fabrizio Rivardo Maria Giovanna Martinotti Gianna Allegrone 《Journal of mass spectrometry : JMS》2010,45(7):772-778
Lipopeptide biosurfactants produced by the Bacillus licheniformis V9T14 strain showed an interesting anti‐adhesion activity against biofilm formation of human pathogenic bacterial strains. The chemical characterisation of the crude extract of V9T14 strain was first developed through electrospray ionisation mass spectrometry (ESI‐MS) and ESI‐MS/MS direct infusions: two sets of molecular ion species belonging to the fengycin and surfactin families were revealed and their structures defined, interpreting their product ion spectra. The LC/ESI‐MS analysis of the crude extract allowed to separate in different chromatogram ranges the homologues and the isoforms of the two lipopeptide families. The extract was then fractionated by silica gel chromatography in two main fractions, I and II. The purified biosurfactants were analysed through a new, rapid and suitable LC/ESI‐MS/MS method, which allowed characterising the composition and the structures of the produced lipopeptides. LC/ESI‐MS/MS analysis of fraction I showed the presence of C13, C14 and C15 surfactin homologues, whose structures were confirmed by the product ion spectra of the sodiated molecules [M + Na]+ at m/z 1030, 1044 and 1058. LC/ESI‐MS/MS analysis of fraction II confirmed the presence of two main fengycin isoforms, with the protonated molecules [M + H]+ at m/z 1478 and 1506 corresponding to C17 fengycin A and C17 fengycin B, respectively. Other homologues (C14 to C16) were revealed and confirmed as belonging to fengycin A or B according to the retention times and the product ions generated, although with the same nominal mass. Finally, a relative percentage content of each homologue for both lipopeptides families in the whole extract was proposed. Copyright © 2010 John Wiley & Sons, Ltd. 相似文献
67.
Francesca Guerriero Giovanna Miglionico Filomena Olivito 《European Journal of Operational Research》2014
The paper addresses restaurant revenue management from both a strategic and an operational point of view. Strategic decisions in restaurants are mainly related to defining the most profitable combination of tables that will constitute the restaurant. We propose new formulations of the so-called “Tables Mix Problem” by taking into account several features of the real setting. We compare the proposed models in a computational study showing that restaurants, with the capacity of managing tables as renewable resources and of combining different-sized tables, can improve expected revenue performances. Operational decisions are mainly concerned with the more profitable assignment of tables to customers. Indeed, the “Parties Mix Problem” consists of deciding on accepting or denying a booking request from different groups of customers, with the aim of maximizing the total expected revenue. A dynamic formulation of the “Parties Mix Problem” is presented together with a linear programming approximation, whose solutions can be used to define capacity control policies based on booking limits and bid prices. Computational results compare the proposed policies and show that they lead to higher revenues than the traditional strategies used to support decision makers. 相似文献
68.
69.
In this paper the question of finding infinitely many solutions to the problem −Δu+a(x)u=|u|p−2u, in RN, u∈H1(RN), is considered when N≥2, p∈(2,2N/(N−2)), and the potential a(x) is a positive function which is not required to enjoy symmetry properties. Assuming that a(x) satisfies a suitable “slow decay at infinity” condition and, moreover, that its graph has some “dips”, we prove that the problem admits either infinitely many nodal solutions or infinitely many constant sign solutions. The proof method is purely variational and allows to describe the shape of the solutions. 相似文献
70.
Renzo C. Silva Giovanna F. Carneiro Lúcio L. Barbosa Valdemar Lacerda Jr. Jair C. C. Freitas Eustáquio V. R. de Castro 《Magnetic resonance in chemistry : MRC》2012,50(2):85-88
Low‐field 1H NMR was used in this work for the analysis of mixtures involving crude oils and water. CPMG experiments were performed to determine the transverse relaxation time (T2) distribution curves, which were computed by the inverse Laplace transform of the echo decay data. The instrument's ability of quantifying water and petroleum in biphasic mixtures following different methodologies was tested. For mixtures between deionized water and petroleum, one achieved excellent results, with root mean squared error of cross‐validation (RMSECV) of 0.8% for a regression between the water content (wt %) and the relative area of the water peak in the T2 distribution curve, or a standard deviation of 0.9% for the relationship between the water content and the relative water peak area, corrected by the relative hydrogen index of the crude. In the case of biphasic mixtures of Mn2+‐doped water and crude oils, the best result of RMSECV = 1.6% was achieved by using the raw magnetization decay data for a partial least squares regression. Copyright © 2012 John Wiley & Sons, Ltd. 相似文献