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61.
Families of parameter dependent univariate and bivariate subdivision schemes are presented in this paper. These families are new variants of the Lane-Riesenfeld algorithm. So the subdivision algorithms consist of both refining and smoothing steps. In refining step, we use the quartic B-spline based subdivision schemes. In smoothing step, we average the adjacent points. The bivariate schemes are the non-tensor product version of our univariate schemes. Moreover, for odd and even number of smoothing steps, we get the primal and dual schemes respectively. Higher regularity of the schemes can be achieved by increasing the number of smoothing steps. These schemes can be nicely generalized to contain local shape parameters that allow the user to adjust locally the shape of the limit curve/surface. 相似文献
62.
Mir MA Chat OA Najar MH Younis M Dar AA Rather GM 《Journal of colloid and interface science》2011,364(1):163-169
Solubilization and co-solubilization of triphenyls (TPs) viz., triphenylphosphine (TPP), triphenylphosphineoxide (TPPO), triphenylamine (TPA) and triphenylmethanol (TPM) were studied in various single and binary surfactant systems at 25 °C using UV-visible spectroscopy and HPLC. The solubilization capacities of different micelles towards TPs were found to be a function of the nature and structure of solubilizates, locus of solubilization, size of micelles and the nature of interactions between the solubilizate and micelles. The effect of surfactant mixing on the solubilization of TPs was evaluated using the Regular Solution Approach (RSA). The solubility enhancement of TPs within mixed micelles relative to that observed in single surfactant systems was explained in light of the structural micellar changes associated with the mixing of ionic and non-ionic surfactants. Moreover, kinetics of oxidation of TPP by hydrogen peroxide investigated in these surfactant systems was found to be sensitive to the nature of micelle and the locus of solubilization of TPP within the micelles. 相似文献
63.
Usman Z Cao C Nabi G Kun DY Khan WS Mehmood T Hussain S 《The journal of physical chemistry. A》2011,115(24):6622-6628
The ab initio pseudopotential (PP) method within the generalized gradient approximation (GGA) has been used to investigate the electronic, elastic constants, and optical properties of zinc-blende GaN. An underestimated band gap along with higher DOS and squeezed energy bands around the fermi level is obtained. The d-band effect is briefly discussed for electronic band structure calculations. With the help of elastic constants, acoustic wave speeds are calculated in [100], [110], and [111] planes. The dielectric constant, refractive index, and its pressure coefficient are well illustrated. The effect of hydrostatic pressure is explicated for all these properties. The results of the present study are evaluated with the existing experimental and first-principle calculations. 相似文献
64.
Musharraf SG Ali A Ali RA Yousuf S Rahman AU Choudhary MI 《Rapid communications in mass spectrometry : RCM》2011,25(1):104-114
Structural elucidation and gas‐phase fragmentation of ten withanolides (steroidal lactones) were studied using a positive ion electrospray ionization quadropole time‐of‐flight mass spectrometry (ESI‐QqTOF‐MS/MS) hybrid instrument. Withanolides form an important class of plant secondary metabolites, known to possess a variety of biological activities. Withanolides which possess hydroxyl groups at C‐4, C‐5, C‐17, C‐20, and C‐27, and an epoxy group at C‐5/C‐6, were evaluated to determine the characteristic fragments and their possible pathways. ESI‐QqTOF‐MS (positive ion mode) showed the presence of the protonated molecules [M + H]+. Low‐energy collision‐induced dissociation tandem mass spectrometric (CID‐MS/MS) analysis of the protonated molecule [M + H]+ indicated multiple losses of water and the removal of the C‐17‐substituted lactone moiety affording the [M + H–Lac]+ product ion as the predominant pathways. However, withanolides containing a hydroxyl group at C‐24 of the lactone moiety showed a different fragmentation pathway, which include the loss of steroidal part as a neutral molecule, with highly diagnostic ions at m/z 95 and 67 being generated from the cleavage of lactone moiety. Our results also determined the influence of the presence and positions of hydroxyl and epoxy groups on product ion formation and stability. Moreover, the knowledge of the fragmentation pattern was utilized in rapid identification of withanolides by the LC/MS/MS analysis of a Withania somnifera extract. Copyright © 2010 John Wiley & Sons, Ltd. 相似文献
65.
JPC – Journal of Planar Chromatography – Modern TLC - A reliable and sensitive thin-layer chromatographic (TLC)-densitometric method is developed for the analysis of danazol in its... 相似文献
66.
ABSTRACT: A rapid and reproducible stability indicating TLC method was developed for the determination of prednisolone acetate and chloramphenicol in presence of their degraded products. Uniform degradation conditions were maintained by refluxing sixteen reaction mixtures for two hours at 80°C using parallel synthesizer including acidic, alkaline and neutral hydrolysis, oxidation and wet heating degradation. Oxidation at room temperature, photochemical and dry heating degradation studies were also carried out. Separation was done on TLC glass plates, pre-coated with silica gel 60F-254 using chloroform: methanol (14:1 v/v). Spots at Rf 0.21 ± 0.02 and Rf 0.41 ± 0.03 were recognized as chloramphenicol and prednisolone acetate, respectively. Quantitative analysis was done through densitometric measurements at multiwavelength (243 nm, λmax of prednisolone acetate and 278 nm, λmax of chloramphenicol), simultaneously. The developed method was optimized and validated as per ICH guidelines. Method was found linear over the concentration range of 200-6000 ng/spot with the correlation coefficient (r2 ± S.D.) of 0.9976 ± 3.5 and 0.9920 ± 2.5 for prednisolone acetate and chloramphenicol, respectively. The developed TLC method can be applied for routine analysis of prednisolone acetate and chloramphenicol in presence of their degraded products in their individual and combined pharmaceutical formulations. 相似文献
67.
68.
T. HAYAT M.MUSTAFA Z.IQBAL A.ALSAEDI 《应用数学和力学(英文版)》2013,34(2):167-176
Melting heat transfer in the boundary layer flow of a couple stress fluid over a stretching surface is investigated. The developed differential equations are solved for homotopic solutions. It is observed that the velocity and the boundary layer thickness are decreasing functions of the couple stress fluid parameter. However, the temperature and surface heat transfer increase when the values of the couple stress fluid parameter increase. The velocity and temperature fields increase with an increase in the melting process of the stretching sheet. 相似文献
69.
A method of solution impregnation and calcination has been demonstrated for synthesizing nanoparticles of Ag–TiO2 composite photocatalysts for use in the disinfection of water. Only a small proportion of the TiO2 surface is covered by nano-islands of Ag corresponding to a loading of 4 wt.% of Ag; thus, most of the TiO2 surface is available for photocatalytic function. Although the primary particles of both Ag and TiO2 are in the 10- to 20-nm range, microscopic studies indicate that the primary particles of Ag are deposited on nano-agglomerates
of 30- to 70-nm-sized TiO2. It is seen that the relatively small loading of Ag has not caused any UV–vis spectral shift but has enhanced the rate of
photocatalytic antibacterial action of TiO2, presumably by electron trapping. 相似文献
70.
In this paper we classify Kantowski-Sachs and Bianchi type Ⅲ space-times according to their teleparallel Killing vector fields using direct integration technique. It turns out that the dimension of the telepaxallel Killing vector fields are 4 or 6, which are the same in numbers as in general relativity. In case of 4 the teleparallel Killing vector fields are multiple of the corresponding Killing vector fields in general relativity by some function of t. In the case of 6 Killing vector fields the metric functions become constants and the Killing vector fields in this case are exactly the same as in general relativity. Here we also discuss the Lie algebra in each case. 相似文献