An efficient palladium catalyzed synthesis of 2-arylbenzothiazoles

A novel and convergent palladium catalyzed synthesis of 2-arylbenzothiazoles has been investigated. The key step in the synthesis is a Suzuki biaryl coupling of 2-bromobenzothiazole with aryl boronic acids to provide a variety of 2-arylbenzothiazole derivatives in good yield. The synthetic utility of this methodology is demonstrated by the synthesis of 2-(4-aminophenyl)-6-methoxybenzothiazole, a PET probe precursor for the in vivo imaging of Alzheimer's disease.     

Spin dynamics investigated by EPR in the paramagnetic regime of La2/3Ca1/3Mn1−x Me x O3 (Me = Al, In) manganites

We report an electron paramagnetic resonance (EPR) investigation of the spin dynamics in the paramagnetic regime of the colossal magnetoresistive manganites La_2/3Ca_1/3Mn_1?x Me _x O₃ (Me=Al, In;x≤0.05). The temperature dependences of the EPR linewidth and integral intensity have been analyzed in terms of the bottleneck spin relaxation and small-polaron hopping models. The exchange coupling integral between Mn³⁺ and Mn⁴⁺ ions and the polaron activation energy decrease with increasing doping level. A discussion is given concerning the factors which could explain the observed changes.     

Identification,synthesis and conformational study of a CN(R,S) synthon by-product: (5R, 10R)-5,10-diphenyl-1,6-diaza-3,8-dioxabicyclo[4.4.1]undecane

The title compound, containing a new heterocyclic skeleton, was identified by X-ray crystallography as the product of condensation of (R)-phenylglycinol with an excess of formaldehyde. The molecule adopts a rigid double twist-chair conformation in both solid and solution states.     

On the vector field problem for O(n)/O(1)xO(1)xO(n-2)

We prove new results about the vector field problem on the real flag manifolds O(n)/O(1) x O(1) x O(n - 2). For some infinite families of these manifolds, we completely solve the vector field problem.     

Investigation of multiwavelength clock recovery based on heterodyne beats of sideband-filtered signal

We investigate a new parallel all-optical clock recovery scheme based on heterodyne beats of an optical sideband-filtered signal. The oscillating clock signal is recovered when the filtered sideband is combined with a stable local oscillator. The filtering is performed with an optical resonator, which by nature provides possibility for multiwavelength operation. The local oscillator could be realized by a multiwavelength laser, whose emission wavelengths are injection seeded with carrier wavelengths of the input data. The output signal of such a configuration benefits from a reduced bit-pattern effect and a stable offset level. The sideband filtering is demonstrated for 23 simultaneous channels at 100 GHz DWDM grid, each hosting a data stream of 10 Gbit/s.