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51.
Selected N-alkyl ketoimines having at least one methyl group at the imino carbon were reacted in a Stork enamine reaction with 2,2-difluoro-2-fluorosulfonylacetyl fluoride to yield enaminones carrying one fluorosulfonyldifluoromethylene function. In the case of N-tertbutyl methyl aldimine two of these groups were present in a triketone derivative. Taking a ethylene bis(imine) also a ring closure reaction was observed, proven by X-ray structure analysis. 相似文献
52.
The Donor Properties of Bis(pyrazolyl)‐Sulfur Derivatives From the reactions of bis(pyrazolyl)sulfane S(pz)2 ( 1 ) with the fluoro Lewis acids BF3 and AsF5 in liquid SO2 the 1:2‐adducts S(pz·BF3)2 ( 2 ) and S(pz·AsF5)2 ( 3 ) are obtained. 1 reacts with [Co(SO2)4(FAsF5)2] to give the doubly bridged FAsF4F dimeric complex [Co{S(pz)2}(FAsF5)(SO2)(μ‐FAsF4F)]2 ( 5 ). From F2S(pz)2 and [Ni(SO2)6](AsF6)2, the fluorocubane [Ni4F4{S(pz)2}4(μ‐FAsF4F)2](AsF6)2·4SO2 ( 8 ) is isolated. The X‐ray structures of the compounds 2 , 3 , 5 and 8 are reported. 相似文献
53.
Carsten Knapp Enno Lork Tobias Borrmann Wolf‐Dieter Stohrer Rüdiger Mews 《无机化学与普通化学杂志》2005,631(10):1885-1892
Attempts to prepare t‐BuCN5S3 and the unexpected Isolation of a covalent Modification of Tetrasulfur‐pentanitrogen Chloride S4N5Cl Attempts to prepare the bicyclic sulfur‐nitrogen heterocycle t‐BuCN5S3 via (NSCl)3 and the corresponding silylated amidinates and amidines failed because of the inaccessibility of the silylated intermediates. Reactions of MN(SiMe3)2 (M = Li, Na) with t‐BuCN did not yield the expected amidinates t‐BuC(NSiMe3)2M, instead the adducts [t‐BuCN·MN(SiMe3)2]2 were isolated. The attempted synthesis of t‐BuCN5S3 from t‐BuCN(SiMe3)2M, prepared in situ from t‐BuLi and Me3SiNCNSiMe3, and (NSCl)3 unexpectedly resulted a mixture of S4N5Cl and S5N6. The crystal structure determination for S4N5Cl showed a new covalent modification of S4N5Cl (monoclinic, P21/c, a = 1005.0(4) pm, b = 1193.5(8) pm, c = 1152.5(6) pm, β = 93.67(3)°), different from the known ionic S4N5Cl (orthorhombic, Pnma, a = 1738.90(10) pm, b = 781.50(10) pm, c = 483.03(5)). The unsuccessful attempts to prepare t‐BuCN5S3, the unexpected formation of S4N5Cl and S5N6, and the bonding properties of the new covalent modification of S4N5Cl are discussed. 相似文献
54.
Opris LM Silvestru A Silvestru C Breunig HJ Lork E 《Dalton transactions (Cambridge, England : 2003)》2004,(21):3575-3585
The cyclostibane R(4)Sb(4)(1)(R = 2-(Me(2)NCH(2))C(6)H(4)) was synthesized by reduction of RSbCl(2) with Mg in THF or with Na in liquid NH(3). The reaction of 1 with [W(CO)(5)(THF)] gives the stibinidene complex RSb[W(CO)(5)](2)(2). RSbCl(2) and (RSbCl)(2)E [E = O (6), E = S (8)] react with KOH or Na(2)S in toluene/water to give the heterocycles (RSbE)(n)[E = O, n= 3 (3); E = S, n= 2 (4)]. The chalcogeno-bridged compounds of the type (RSbCl)(2)E [E = O (6), E = S (8)] were synthesized by reaction of RSbCl(2) with KOH or Na(2)S in toluene/water, but also by reaction of RSbCl(2) with the heterocycles (RSbE)(n). The compounds (RSbI)(2)O (7) and (RSbBr)(2)S (9) were prepared via halogen-exchange reactions between (RSbCl)(2)E and NaI (E = O) or KBr (E = S) or by reactions between RSbI(2) and KOH or RSbBr(2) and Na(2)S. The reaction of cyclo-(RSbS)(2) with W(CO)(5)(THF) in THF results in trapping of the cis isomer in cyclo-(RSbS)(2)[W(CO)(5)](5). The solution behaviour of the compounds was investigated by (1)H and (13)C NMR spectroscopy. The molecular structures of compounds 1-7 and 9 were determined by single-crystal X-ray diffraction. 相似文献
55.
Kolomeitsev AA Bissky G Barten J Kalinovich N Lork E Röschenthaler GV 《Inorganic chemistry》2002,41(23):6118-6124
Hexaalkylguanidinium and 2-(dialkylamino)-1,3-dimethylimidazolinium trimethyldifluorosiliconates, precursors for two stable hexaalkylguanidinium perfluoroalkoxides, were synthesized by treating commercially available bis(dialkylamino)difluoromethane derivatives with (dialkylamino)trimethylsilanes in aprotic media. With hexamethylguanidinium pentafluoroethoxide the introduction of the lipophilic and electronegative C2F5O group was straightforwardly achieved in the case of primary and secondary alkyl triflates to furnish the respective fluorinated ethers. The molecular structures of [(CH2NMe)2C(NEt2)]+[Me3SiF2]- and [C(NMe2)3]+F-*6CH2Cl2 were determined, showing in the latter case a fluoride anion octahedrally coordinated by six methylene chloride molecules via hydrogen bridges with a F...H distance of 205 pm (C...F distance 270.0(3) pm). 相似文献
56.
By oxidation of 3-thioderivatives of 1,2,4-triazine 1a,b 3-alkylsulfonic derivatives 2a,b were obtained. Interaction of the sulfonic derivative 2a with indole leads to 3-oxo-5-indolyl-5-phenyl-as-triazine 4. The sulfone 2a reacts with 1-ethyl-2,6-dimethylquinolinium iodide to give 3-(1-ethyl-6-methyl-1,2-dihydroquinoline-2-methylene)-5-phenyl-1,2,4-triazine 5. The 3-morpholino- 3 and 3-thioderivatives 6, 7a,b of as-triazine were obtained by interaction of the sulfone 2 with morpholine and organic boron-containing thiols. The crystal structure of boron-containing derivative of as-triazine 7b was investigated by X-ray analysis. 相似文献
57.
Shevchenko I Andrushko V Lork E Röschenthaler GV 《Chemical communications (Cambridge, England)》2002,(2):120-121
The oxidation of bis[bis(dialkylamino)phosphinyl]methane 1 with 5,5,5-trifluoro-4-(trifluoromethyl)penta-3-en-2-one 2 unexpectedly gave zwitterionic compound 7 which according to X-ray analysis contains two phosphorus atoms of opposite charge and different coordination number (lambda 4P(+); lambda 6P(-)) with a direct P-H bond at the hexacordinated phosphorus. 相似文献
58.
A [2]-catenane consisting of methylene groups and two additional acetylated aza groups has been synthesized in a multi-step sequence. After splitting off the acetyl bonds, the resulting secondary diamine should provide a good starting material for stepreaction (condensation or addition, respectively) polymerization. 相似文献
59.
60.