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71.
Franceschini E Yu FT Cloutier G 《The Journal of the Acoustical Society of America》2008,123(4):EL85-EL91
The analysis of the ultrasonic frequency-dependent backscatter coefficient of aggregating red blood cells reveals information about blood structural properties. The difficulty in applying this technique in vivo is due to the frequency-dependent attenuation caused by intervening tissue layers that distorts the spectral content of backscattering properties from blood microstructures. An optimization method is proposed to simultaneously estimate tissue attenuation and blood structure factor. With in vitro experiments, the method gave satisfactory estimates with relative errors below 22% for attenuations between 0.101 and 0.317 dBcmMHz, signal-to-noise ratios>28 dB and kR<2.7 (k being the wave number and R the aggregate radius). 相似文献
72.
Gaëtan Compère Emilie Marchandise Jean-François Remacle 《Journal of computational physics》2008,227(3):1923-1942
An anisotropic adaptation process is applied to a three-dimensional incompressible two-phase flow solver. The solver uses a level set/finite element method on unstructured tetrahedral meshes. We show how the level set function can be used to build an anisotropic mesh with good properties. Some computations with a strong transient character and large densities ratios (1/1000) are presented. We show that the efficiency of the computations can be deeply enhanced by mesh adaptations. 相似文献
73.
Karoline Wiesner 《Physica D: Nonlinear Phenomena》2008,237(9):1173-1195
We introduce stochastic and quantum finite-state transducers as computation-theoretic models of classical stochastic and quantum finitary processes. Formal process languages, representing the distribution over a process’ behaviors, are recognized and generated by suitable specializations. We characterize and compare deterministic and nondeterministic versions, summarizing their relative computational power in a hierarchy of finitary process languages. Quantum finite-state transducers and generators are a first step toward a computation-theoretic analysis of individual, repeatedly measured quantum dynamical systems. They are explored via several physical systems, including an iterated-beam-splitter, an atom in a magnetic field, and atoms in an ion trap—a special case of which implements the Deutsch quantum algorithm. We show that these systems’ behaviors, and so their information processing capacity, depends sensitively on the measurement protocol. 相似文献
74.
Bethelihem Mekonnen Xavier Cheseto Christian Pirk Abdullahi Yusuf Sunday Ekesi Emilie Deletre Baldwyn Torto 《Molecules (Basel, Switzerland)》2021,26(4)
The African weaver ant, Oecophylla longinoda, is used as a biological control agent for the management of pests. The ant has several exocrine glands in the abdomen, including Dufour’s, poison, rectal, and sternal glands, which are associated with pheromone secretions for intra-specific communication. Previous studies have analyzed the gland secretions of Dufour’s and poison glands. The chemistry of the rectal and sternal glands is unknown. We re-analyzed the secretions from Dufour’s and poison glands plus the rectal and sternal glands to compare their chemistries and identify additional components. We used the solid-phase microextraction (SPME) technique to collect gland headspace volatiles and solvent extraction for the secretions. Coupled gas chromatography–mass spectrometry (GC-MS) analysis detected a total of 78 components, of which 62 were being reported for the first time. These additional components included 32 hydrocarbons, 12 carboxylic acids, 5 aldehydes, 3 alcohols, 2 ketones, 4 terpenes, 3 sterols, and 1 benzenoid. The chemistry of Dufour’s and poison glands showed a strong overlap and was distinct from that of the rectal and sternal glands. The different gland mixtures may contribute to the different physiological and behavioral functions in this ant species. 相似文献
75.
Inside Back Cover: Control over Nanostructures and Associated Mesomorphic Properties of Doped Self‐Assembled Triarylamine Liquid Crystals (Chem. Eur. J. 5/2015) 下载免费PDF全文
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Emilie V. Banide Helge Müller-Bunz Michael Casey M. Cristina Lagunas Michael J. McGlinchey 《Journal of organometallic chemistry》2008,693(10):1759-1770
Successive treatment of 9-(phenylethynyl)fluoren-9-ol (1a), with HBr, butyllithium and chlorodiphenylphosphine furnishes 3,3-(biphenyl-2,2′-diyl)-1-diphenylphosphino-1-phenylallene (5). Moreover, reaction of 1a directly with chlorodiphenylphosphine yields the corresponding allenylphosphine oxide (6). The allenylphosphine (5), and Fe2(CO)9 initially form the phosphine-Fe(CO)4 complex, 11, which is very thermally sensitive and readily loses a carbonyl ligand. In the resulting phosphine-Fe(CO)3 system, 12, the additional site at iron is coordinated by the allene double bond adjacent to phosphorus; the Fe(CO)3 tripod in 12 exhibits restricted rotation on the NMR time-scale even at room temperature. The corresponding chromium complex, (5)-Cr(CO)5 (9), has also been prepared. The gold complexes (5)-AuCl (13), and [(5)-Au(THT)]+ X−, where (THT) is tetrahydrothiophene, and X = PF6 (14a), or ClO4 (14b), are analogous to the known triphenylphosphine-gold complexes. In contrast, in the (arene)(allenylphosphine)RuCl2 system the allene double bond adjacent to phosphorus displaces a chloride, and the resulting cationic species undergoes nucleophilic attack by water yielding ultimately a five-membered Ru-P-CC-O ruthenacycle (17). Thus, the allenylphosphine (5), reacts initially as a conventional mono-phosphine but, when the metal centre has a readily displaceable ligand such as a carbonyl or halide, the allene double bond adjacent to the phosphorus can also function as a donor. X-ray crystal structures are reported for 5, 6, 11, 12, 13, 14a, 14b and 17. 相似文献