全文获取类型
收费全文 | 359篇 |
免费 | 6篇 |
国内免费 | 5篇 |
专业分类
化学 | 203篇 |
力学 | 5篇 |
数学 | 101篇 |
物理学 | 61篇 |
出版年
2022年 | 3篇 |
2020年 | 5篇 |
2018年 | 3篇 |
2016年 | 5篇 |
2015年 | 5篇 |
2014年 | 15篇 |
2013年 | 13篇 |
2012年 | 17篇 |
2011年 | 13篇 |
2010年 | 16篇 |
2009年 | 9篇 |
2008年 | 19篇 |
2007年 | 17篇 |
2006年 | 14篇 |
2005年 | 16篇 |
2004年 | 18篇 |
2003年 | 22篇 |
2002年 | 6篇 |
2001年 | 10篇 |
2000年 | 6篇 |
1999年 | 6篇 |
1998年 | 8篇 |
1997年 | 10篇 |
1996年 | 3篇 |
1994年 | 9篇 |
1993年 | 3篇 |
1992年 | 4篇 |
1990年 | 5篇 |
1989年 | 3篇 |
1987年 | 6篇 |
1986年 | 7篇 |
1985年 | 5篇 |
1982年 | 5篇 |
1981年 | 2篇 |
1979年 | 7篇 |
1977年 | 7篇 |
1976年 | 3篇 |
1973年 | 2篇 |
1972年 | 2篇 |
1971年 | 5篇 |
1970年 | 2篇 |
1969年 | 2篇 |
1968年 | 2篇 |
1967年 | 2篇 |
1965年 | 2篇 |
1964年 | 3篇 |
1961年 | 2篇 |
1960年 | 2篇 |
1957年 | 3篇 |
1907年 | 2篇 |
排序方式: 共有370条查询结果,搜索用时 31 毫秒
61.
Variations in the essential oil composition of Thymus serpyllum L., growing wild in Estonia (33 samples) and in some other countries (Russia, Latvia and Armenia, seven samples) were determined. The oil were obtained from Estonia (46 samples) in yields 0.6-4.4 and 1.9-8.2 mL kg(-1) in other countries. The T. serpyllum herb grown in Estonia usually did not confirmed to the EP standard in the aspect of the essential oil contents (3.0 mL kg(-1)). Variations in the essential oil composition of wild thyme were studied using capillary gas chromatographic methods. A total of 94 components were identified. Thymol and carvacrol, mentioned in literature as principial components, are not the main components of the essential oil of wild thyme growing in Estonia. (E)-nerolidol, caryophyllene oxide, myrcene and borneol chemotypes of wild thyme drug are distinguishable. The chemical composition of samples from Russia, Latvia and Armenia is very variable. 相似文献
62.
Hollemeyer K Altmeyer W Heinzle E Pitra C 《Rapid communications in mass spectrometry : RCM》2008,22(18):2751-2767
Identification of ancient biological samples from the 1991-discovered and more than 5300-year-old Tyrolean mummy, also called iceman or Oetzi, is very difficult. The species of origins of four animal-hair-bearing samples of the accoutrement of the mummy not yet diagnosed were identified by a special proteomics method. Ha 43/91/130 and Ha 6/91, two samples from his coat, and Ha 5/91, a sample from his leggings, were assigned to sheep. The upper leather of his moccasins, Ha 2/91, was made from cattle. Despite the enormous age of these samples with partial (bio)chemical alterations, reliable identification was possible using a recently developed matrix-assisted laser desorption/ionization time-of-flight mass spectrometric ((MALDI-TOF MS)-based analytical method. The method is exclusively based on the analysis of proteins and uses minute amounts of peptides directly derived from tryptic hair digests without any separation or enrichment steps. Unknown species are identified by comparison of their peptide ion patterns with known spectra stored in existing databases. Hereby, the correlation distance, a form of Euclidean distance, and deduced parameters are used to measure similarities.If more than one potential hit remains, specific diagnostic peptide ions are used to stepwise exclude incorrect matches. These ions are specific for orders, families, subfamilies/genera and/or even species. Peptide mass fingerprinting data combined with those from collision-induced dissociation spectra (combined MS & MS/MS) were used for interpretation with the MASCOT search engine and the NCBI database to find the potential parentage of hair proteins. For this technique, selected precursor ions were identified as specific diagnostic peptide ions. Copyright (c) 2008 John Wiley & Sons, Ltd. 相似文献
63.
Lenz T Bonnist EY Pljevaljcić G Neely RK Dryden DT Scheidig AJ Jones AC Weinhold E 《Journal of the American Chemical Society》2007,129(19):6240-6248
We report the crystal structure of the DNA adenine-N6 methyltransferase, M.TaqI, complexed with DNA, showing the fluorescent adenine analog, 2-aminopurine, flipped out of the DNA helix and occupying virtually the same position in the active site as the natural target adenine. Time-resolved fluorescence spectroscopy of the crystalline complex faithfully reports this state: base flipping is accompanied by the loss of the very short ( approximately 50 ps) lifetime component associated with fully base-stacked 2-aminopurine in DNA, and 2-aminopurine is subject to considerable quenching by pi-stacking interactions with Tyr108 in the catalytic motif IV (NPPY). This proves 2-aminopurine to be an excellent probe for studying base flipping by M.TaqI and suggests similar quenching in the active sites of DNA and RNA adenine-N6 as well as DNA cytosine-N4 methyltransferases sharing the conserved motif IV. In solution, the same distinctive fluorescence response confirms complete destacking from DNA and is also observed when the proposed key residue for base flipping by M.TaqI, the target base partner thymine, is substituted by an abasic site analog. The corresponding cocrystal structure shows 2-aminopurine in the active site of M.TaqI, demonstrating that the partner thymine is not essential for base flipping. However, in this structure, a shift of the 3' neighbor of the target base into the vacancy left after base flipping is observed, apparently replicating a stabilizing role of the missing partner thymine. Time-resolved fluorescence and acrylamide quenching measurements of M.TaqI complexes in solution provide evidence for an alternative binding site for the extra-helical target base within M.TaqI and suggest that the partner thymine assists in delivering the target base into the active site. 相似文献
64.
Elmar Grosse-Klnne 《Finite Fields and Their Applications》2007,13(4):896-921
Let be an abelian prime-to-p Galois covering of smooth schemes over a perfect field k of characteristic . Let Y be a smooth compactification of such that is a normal crossings divisor on Y. We describe a logarithmic F-crystal on Y whose rational crystalline cohomology is the rigid cohomology of X, in particular provides a natural -lattice inside the latter; here W is the Witt vector ring of k. If a finite group G acts compatibly on X, and Y then our construction is G-equivariant. As an example we apply it to Deligne–Lusztig varieties. For a finite field k, if is a connected reductive algebraic group defined over k and a k-rational torus satisfying a certain standard condition, we obtain a meaningful equivariant -lattice in the cohomology (ℓ-adic or rigid) of the corresponding Deligne–Lusztig variety and an expression of its reduction modulo p in terms of equivariant Hodge cohomology groups. 相似文献
65.
Given a perfect field of characteristic , a smooth proper -scheme , a crystal on relative to and a finite group acting on and , we show that, viewed as a virtual -module, the reduction modulo of the crystalline cohomology of is the de Rham cohomology of modulo . On the way we prove a base change theorem for the virtual -representations associated with -equivariant objects in the derived category of -modules.
66.
We introduce the algebra of smoothing Mellin and Green symbols in a pseudodifferential calculus for manifolds with edges. In addition, we define scales of weighted Sobolev spaces with asymptotics based on the Mellin transform and analyze the mapping properties of the operators on these spaces. This will allow us to obtain complete information on the regularity and asymptotics of solutions to elliptic equations on these spaces. 相似文献
67.
68.
Elmar Hecht 《无机化学与普通化学杂志》2000,626(3):759-765
Preparation, Properties, and Molecular Structures of Dimethylaminomethyl Ferrocenyl Compounds of selected Elements of Group 13 and 14 Dimethylmetalchlorides of gallium and indium react with dimethylaminomethylferrocenyllithium (FcNLi) to give the corresponding dimethylmetaldimethylaminomethylferrocenes 1 and 2 [Me2MFcN; M=Ga, In]. In a similar manner dialkylmetaldichlorides of germanium and tin yield the expected chlordialkylmetaldimethylaminomethylferrocenes 3 – 5 [R2(Cl)MFcN; M=Ge; R = Me ( 3 ), M=Sn; R=Me ( 4 ), Ph ( 5 )]. In a reaction of Me3Al and Me2AlCl with dimethylaminomethylferrocene the formation of the 1 : 1 adducts 7 and 8 could be observed. All compounds were characterised by 1H and 13C nmr spectroscopy. The molecular structures of 1 , 3 , 4 and 7 were determined. 3 and 4 build in contrast to 1 monomeric molecules with chelat rings as a result of the M–N coordination. Compound 7 consist of monomeric molecules with 4 coordinated Al atoms. 相似文献
69.
Marc Pignot Christoph Siethoff Michael Linscheid Elmar Weinhold 《Angewandte Chemie (International ed. in English)》1998,37(20):2888-2891
How to outwit a methyltransferase: Methyltransferases (Mtases) catalyze the transfer of the activated methyl group from the cofactor S-adenosyl-L -methionine ( 1 ) to acceptors R within a large variety of biomolecules. Through the use of the cofactor analogue 2 a whole nucleoside was coupled to DNA in a Mtase-catalyzed reaction. 相似文献
70.
Intra- and inter-chain fluctuations in entangled polymer melts in bulk and confined to pore channels
Rainer Kimmich Nail Fatkullin Ralf-Oliver Seitter Elmar Fischer Uwe Beginn Martin Mller 《Macromolecular Symposia》1999,146(1):109-115
It is known that topological restraints by “chain entanglements” severely affect chain dynamics in polymer melts. In this field-cycling NMR relaxometry and fringe-field NMR diffusometry study, melts of linear polymers in bulk and confined to pores in a solid matrix are compared. The diameter of the pore channels was 10 nm. It is shown that the dynamics of chains in bulk dramatically deviate from those observed under pore constraints. In the latter case, one of the most indicative signatures of the reptation model is verified 28 years after its prediction by de Gennes: The frequency and molecular mass dependencies of the spin-lattice relaxation time obey the power law T! ∝ M0 v3/4 on a time scale shorter than the longest Rouse relaxation time τR. The mean squared segment displacement in the pores was also found to be compatible to the reptation law < r2>∝ M−1/2t1/2 predicted for τR < t < τd, where τd is the so-called disengagement time. Contrary to these findings, bulk melts of entangled polymers show frequency and molecular mass dependencies significantly different from what one expects on the basis of the reptation model. The data can however be described with the aid of the renormalized Rouse theory. 相似文献