Disjunkte Folgen in Banachverbänden und Kegel-absolutsummierende Operatoren

Ohne ZusammenfassungDie Autoren wurden unterstützt von der Alexander von Humboldt-Stiftung (Cartwright) sowie von der United States National Science Foundation (Lotz).     

Positive fluorine - misconception or reality?

Some of the evidence for positive fluorine is summarized. Evidence against positive fluorine based on the direction of addition to fluoroolefins, and polarity as judged by electronegativity values, is queried.     

A direct complex stress function approach for modelling stiffened panels containing multiple site damage

The analysis of stiffened panel structures containing multiple site damage (MSD) is addressed through the complex variable method, in association with the requirement for displacement compatibility. The method is extended by replacing the usual single crack stress and displacement functions by those for a series of arbitrary straight collinear cracks which are used to model exactly the main and secondary crack damage in the sheet. It is shown that the problem can be reduced to a system of linear equations for the unknown forces at the attachment points between the sheet and the stiffener from which the stress intensity factor of the collinear cracks can be determined. The stress intensity factor and the attachment force distribution are determined for several configurations and compared with those from numerically based approaches.     

Thermal investigation of the crystallisation nucleant formed between 2,4,6 trinitrotoluene, (TNT) and 2,2′,4,4′,6,6′ hexanitrostilbene (HNS)

Hexanitrostilbene (HNS), is added to trinitrotoluene (TNT), in order to improve the grain structure of cast munitions. The formation and composition of the nucleant material has been investigated by thermal methods using mixtures of HNS and TNT, with composition in the range 0.5%, the normal casting level, to 50% w/w HNS to TNT. These were cycled between ambient and upper temperatures in the range 160 to 235°C. Endotherms in the DSC traces, due to nucleant decomposition, have been observed in situ without the need for separation and purification. DSC enthalpy measurements, before and after thermal decomposition, were used to determine the composition of separated nucleant. Nucleant regeneration after decomposition, was investigated by thermal methods. Nucleant could not be recrystallised from solvents. Results have been interpreted on the basis of the formation of a, solid solution of TNT in HNS, rather than a complex of formula TNT₂HNS.     

Rapid determination of moisture/solids and fat in dairy products by microwave and nuclear magnetic resonance analysis

A peer-verified method is presented for the determination of percent moisture/solids and fat in dairy products by microwave drying and nuclear magnetic resonance (NMR) analysis. The method involves determining the moisture/solids content of dairy samples by microwave drying and using the dried sample to determine the fat content by NMR analysis. Both the submitting and peer laboratories analyzed various dairy products by using a CEM SMART system (moisture) and the SMART Trac (fat). The samples included milks, creams, ice cream mix, sour cream, yogurt, cream cheese, and mozzarella, Swiss, and cheddar cheeses. These samples represented a range of products that processors deal with in daily plant operations. The results were compared with moisture/solids and fat values derived from AOAC-approved methods.     

The precipitation of bismuth basic acetate from homogeneous solution

Precipitation from homogeneous solution by urea hydrolysis has been used to investigate the conditions affecting the precipitation of bismuth basic acetate. Evidence has been found that indicates that acetate complexes may be formed. The method has been tested for the determination of bismuth, but is not suitable if lead is present.     

Intraspecific comparisons reveal differences in the pattern of ultraviolet radiation responses in four maize (Zea mays L.) varieties.

Four maize (Zea mays L.) varieties were examined for ultraviolet radiation-induced changes in leaf rolling, biomass, fluctuating leaf asymmetry and DNA damage. Short-term dose-response curves for each response were constructed and responses in each line compared. The four varieties each exhibited a different pattern of tolerance and reactivity, ranging from B73, which was tolerant in all four measures, to TS1, which was affected in DNA damage levels and leaf rolling but unaffected in biomass accumulation and fluctuating leaf asymmetry. The pattern of ultraviolet radiation responses allows us to narrow the possibilities for the source of the defect in reactive varieties. The four varieties tested include inbred parents that have been used to construct recombinant inbred lines and a variety that is found in the background of the engineered RescueMu transposon mutagenesis lines. These dose-response curves and variety comparisons provide the foundation for genetic dissection of the mechanisms of ultraviolet radiation responses in maize.     

Dipyrido[1,2-a;3′,4′-d]imidazole systems

Novel tricyclic dipyridoimidazole derivatives can be readily synthesised in one pot processes from various highly fluorinated pyridine systems such as pentafluoropyridine and relatively nucleophilic 2-aminopyridine derivatives. Further nucleophilic aromatic substitution reactions of the novel tricyclic scaffolds allow the regioselective synthesis of various nitrogen, oxygen, carbon and sulfur-functionalised dipyridoimidazole products.