全文获取类型
收费全文 | 783篇 |
免费 | 31篇 |
国内免费 | 16篇 |
专业分类
化学 | 457篇 |
晶体学 | 20篇 |
力学 | 24篇 |
数学 | 169篇 |
物理学 | 160篇 |
出版年
2021年 | 8篇 |
2020年 | 12篇 |
2019年 | 6篇 |
2018年 | 9篇 |
2017年 | 6篇 |
2016年 | 13篇 |
2015年 | 14篇 |
2014年 | 15篇 |
2013年 | 31篇 |
2012年 | 42篇 |
2011年 | 57篇 |
2010年 | 28篇 |
2009年 | 36篇 |
2008年 | 35篇 |
2007年 | 40篇 |
2006年 | 36篇 |
2005年 | 40篇 |
2004年 | 22篇 |
2003年 | 27篇 |
2002年 | 39篇 |
2001年 | 8篇 |
2000年 | 15篇 |
1999年 | 9篇 |
1998年 | 8篇 |
1997年 | 6篇 |
1996年 | 15篇 |
1995年 | 17篇 |
1994年 | 13篇 |
1993年 | 7篇 |
1992年 | 5篇 |
1991年 | 11篇 |
1990年 | 8篇 |
1989年 | 9篇 |
1988年 | 8篇 |
1987年 | 12篇 |
1986年 | 8篇 |
1985年 | 10篇 |
1983年 | 8篇 |
1982年 | 11篇 |
1981年 | 13篇 |
1980年 | 11篇 |
1979年 | 7篇 |
1978年 | 15篇 |
1977年 | 7篇 |
1976年 | 5篇 |
1975年 | 13篇 |
1974年 | 13篇 |
1973年 | 7篇 |
1972年 | 6篇 |
1971年 | 4篇 |
排序方式: 共有830条查询结果,搜索用时 15 毫秒
51.
Don N. Page 《Physics letters. A》1982,91(2):57-60
Quantum mechanics can completely describe what may actually be predicted about any system, contrary to the argument of Einstein, Podolsky, and Rosen. One does not however need to restric predictions to specified experimental arrangements as Bohr did. 相似文献
52.
The Einstein equations with a negative cosmological constant admit black hole solutions which are asymptotic to anti-de Sitter space. Like black holes in asymptotically flat space, these solutions have thermodynamic properties including a characteristic temperature and an intrinsic entropy equal to one quarter of the area of the event horizon in Planck units. There are however some important differences from the asymptotically flat case. A black hole in anti-de Sitter space has a minimum temperature which occurs when its size is of the order of the characteristic radius of the anti-de Sitter space. For larger black holes the red-shifted temperature measured at infinity is greater. This means that such black holes have positive specific heat and can be in stable equilibrium with thermal radiation at a fixed temperature. It also implies that the canonical ensemble exists for asymptotically anti-de Sitter space, unlike the case for asymptotically flat space. One can also consider the microcanonical ensemble. One can avoid the problem that arises in asymptotically flat space of having to put the system in a box with unphysical perfectly reflecting walls because the gravitational potential of anti-de Sitter space acts as a box of finite volume. 相似文献
53.
Partial fluorination overcomes herringbone crystal packing in small polycyclic aromatics 总被引:1,自引:0,他引:1
[structure: see text] We report the synthesis and characterization of partially fluorinated condensed tetracyclic aromatic compounds. Typical edge-to-face/herringbone packing of nonfluorinated analogues is replaced here by columnar stacks with disk planes orthogonal to the columnar axes. Enhanced pi-overlap results with overlaid electron-poor and -rich regions. 相似文献
54.
Bunch J Clench MR Richards DS 《Rapid communications in mass spectrometry : RCM》2004,18(24):3051-3060
Matrix-assisted laser desorption/ionisation (MALDI) quadrupole time-of-flight mass spectrometry (Q-TOFMS) has been used to detect and image the distribution of a xenobiotic substance in skin. Porcine epidermal tissue was treated with 'Nizoral', a medicated shampoo containing ketoconazole (+/-)-1-acetyl-4-[p-[[(2R,4S)-2-(2,4-dichlorophenyl)-2-(imidazol-1-ylmethyl)-1,3-dioxolan-4-yl]methoxy]phenyl]piperazine) as active ingredient. Following incubation for 1 h at 37 degrees C all excess formulation was washed from the surface. A cross-section of the drug-treated tissue was then blotted onto a cellulose membrane, precoated in matrix (alpha-cyano-4-hydroxycinnamic acid (CHCA)), by airspray deposition. In separate experiments the tissue surface was treated with Nizoral within a triangular former, and subsequently blotted onto a matrix-coated membrane. Sample membranes were then mounted into the recess of specialised MALDI targets with adhesive tape. All samples were analysed by MALDI-TOFMS using an Applied Biosystem 'Q-star Pulsar i' hybrid Q-TOF mass spectrometer fitted with an orthagonal MALDI ion source and imaging software. Detection of the protonated molecule was readily achievable by this technique. Treatment of the tissue within a template gave rise to images depicting the expected distribution of the drug, demonstrating that this technique is capable of producing spatially useful data. Ion images demonstrating the permeation of the applied compound into the skin were achieved by imaging a cross-sectional imprint of treated tissue. A calibration graph for the determination of ketoconazole was prepared using the sodium adduct of the matrix ion as an internal standard. This enabled construction of a quantitative profile of drug in skin. Conventional haematoxylin and eosin staining and microscopy methods were employed to obtain a histological image of the porcine epidermal tissue. Superimposing the mass spectrometric and histological images appeared to indicate drug permeation into the dermal tissue layer. 相似文献
55.
Lowe Terry C. Bishop Alan Burns Carol Hartford Allen Parkin Don Trewhella Jill 《Journal of nanoparticle research》2000,2(3):249-266
Research in the emerging field of nanoscale science and technology has grown steadily at Los Alamos National Laboratory since 1990. This article summarizes some of this work, examining research highlights within the seven key categories of nanoscience in which Los Alamos has ongoing projects, capabilities, and facilities: (1) Materials and chemistry, (2) Theory and modeling, (3) Bioscience, (4) Investigative tools and facilities, (5) Sensors and devices, (6) Synthesis and fabrication, and (7) Education and outreach. Future research horizons are indicated throughout while institutional strategies for advancing nanoscale science are summarized at the end. 相似文献
56.
57.
Zusammenfassung Es wird gezeigt, da? ?ls?ure auf anges?uerter Permanganatl?sung einen Film ergibt, der au?erordentlich empfindlich gegenüber
Einwirkungen anderer Flüssigkeiten ist. Die charakteristischen sternf?rmigen Teilchen dieses Filmes werden durch viele organische
Flüssigkeiten und auch durch menschliche Blutseren ver?ndert. Besonders ausgepr?gt ist dies der Fall, wenn die Seren Wassermannreaktion
zeigen, denn dann ist die Ver?nderung der Teilchen sehr einfacher Natur. Diese Reaktion kann aber nicht als wirklich spezifisch
für syphilitische Seren betrachtet werden, da die Seren gewisser Patienten, die jedoch nicht syphilitisch sind, ganz ?hnliche
Reaktionen ergeben.
übersetzt von Rud. Walter (Leipzig).
Die Verfasser danken den Herren Dr. Robb M. D. und Dr. Ross M. B. C. M. für ihre wertvolle Unterstützung bei diesen Untersuchungen. 相似文献
58.
A new algorithm is presented, based on elements of artificial intelligence theory, to determine the fractal properties of the backbone of the incipient infinite cluster. It is found that the fractal dimensionality of the backbone isd
f
BB
=1.61±0.01, the chemical dimensionality isd
t=1.40±0.01, and the fractal dimension of the minimum pathd
min=1.15 ± 0.02 for the two-dimensional triangular lattice. 相似文献
59.
Andreas J. Steiner Georg Schitter Arnold E. Stütz Tanja M. Wrodnigg Chris A. Tarling Stephen G. Withers Don J. Mahuran Michael B. Tropak 《Tetrahedron: Asymmetry》2009,20(6-8):832-835
Cyclisation by double reductive amination of 2-acetamino-2-deoxy-d-xylo-hexos-5-ulose with N-2 protected l-lysine derivatives provided 2-acetamino-1,2-dideoxynojirimycin derivatives without any observable epimer formation at C-5. Modifications on the lysine moiety gave access to lipophilic derivatives that exhibited improved hexosaminidase inhibitory activities. 相似文献
60.
In most papers establishing consistency for learning algorithms it is assumed that the observations used for training are realizations of an i.i.d. process. In this paper we go far beyond this classical framework by showing that support vector machines (SVMs) only require that the data-generating process satisfies a certain law of large numbers. We then consider the learnability of SVMs for α-mixing (not necessarily stationary) processes for both classification and regression, where for the latter we explicitly allow unbounded noise. 相似文献