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Bintinger D Kees KH Masek GE Miller ES Thompson JR Vernon W White JT Eisner AM Palmer DA Sullivan MK Armitage JC Buijs A Van Driel MA Erné FC Langeveld WG Paar HP Sens JC Timmer J Van Uitert B Cain MP Ko W Lander RL Maeshima K McNeil RR Pellett DE Smith JR Williams MC Caldwell DO Joshi UP Lu A Schwitkis KA Yellin SJ 《Physical review letters》1985,54(8):763-766
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[reaction: see text] The enzymatic degradation of starch can be monitored electronically using single-walled carbon nanotubes (SWNTs) as semiconducting probes in field-effect transistors (FETs). Incubation of these devices in aqueous buffer solutions of amyloglucosidase (AMG) results in the removal of the starch from both the silicon surfaces and the side walls of the SWNTs in the FETs, as evidenced by direct imaging and electronic measurements. 相似文献
35.
Plasma polymerization of aniline and in-situ doping of polvaniline with iodine was carried out using radio frequency glow discharge. Thin films of polyaniline were deposited on platinum and glass. The infrared spectrum shows that the aromatic ring is retained under the plasma conditions. The electrical conductivity measurements indicate that the conductivity increases by more than seven orders of magnitude when the polyaniline is doped by iodine. The scanning electron microscopic studies reveal the formation of irregular pentagons on glass substrate while on platinum, polvaniline forms a fibrillar network. In both the cases a continuous film is obtained. 相似文献
36.
The oxidation of lactic acid by Cr(VI) under acidic conditions is catalyzed by bidentate amino acid ligands such as glycine, alanine, aspartic acid and hydroxyproline. Catalysis is a function of [L]/[Cr(VI)] ratio and acidity. Pyruvic acid and acetaldehyde in a ratio of 2 : 1 are obtained as oxidation products in both uncatalyzed and catalyzed oxidation. This supports the previous understanding of the oxidation of -substituted carboxylic acids. Cromium(V) and chromium(VI) behave similarly in a C–H bond rupture (Rocek, J. and Radkowsky, A.E., J. Am. Chem. Soc., 1973, vol. 95, p. 7123), whereas Cr(IV) is responsible for C–C bond cleavage products (Wiberg, K.B. and Schafer, H., J. Am. Chem. Soc., 1969, vol. 91, p. 927). 相似文献
37.
J.C. Joshi B.C. Joshi N.C. Pandey R. Belwal Janardan Joshi 《Journal of solid state chemistry》1977,22(4):439-443
Energy transfer studies have been made in a terbium-erbium coactivated calibo-glass system at room temperature and at liquid-air temperature. A study of the emission and decay of 5D4 level of Tb3+ has been made by varying the acceptor (Er3+) concentration. Probabilities and efficiencies of energy transfer as well as donor-acceptor distances have been calculated. At low acceptor concentration the decay of the donor (Tb3+) emission has been found to be diffusion limited. At high acceptor concentration the mechanism governing the transfer is found to be dipole-dipole. 相似文献
38.
A controlled potential coulometric method developed earlier for the determination of uranium in the presence of iron or plutonium using platinum working electrode was extended for individual determination of uranium and iron or plutonium in single aliquot. After uranium determination, Fe(III) or Pu(IV) in the aliquot is reduced electrolytically to Fe(II) or Pu(III) and subsequently determined by electrolytic oxidation to Fe(III) or Pu(IV), respectively. Analysis of synthetic solutions indicated that the values for uranium, iron and plutonium obtained by this method are reproducible within±0.2% and are in good agreement with values obtained using conventional redox methods 1, 2. 相似文献
39.
Krishna C. Joshi Vijai N. Pathak Raj Pal Singh 《Monatshefte für Chemie / Chemical Monthly》1980,111(6):1343-1350
Several new 2-(fluoroaryl)-3-dialkylaminomethylindoles, 3-acetyl-2-(fluoroaryl)-indoles, 2-(fluoroaryl)-3-indolylglyoxamides and corresponding tryptamines have been prepared as possible psychopharmacological agents. 2-(Fluoroaryl)-indoles have been synthesized by theFischer indole synthesis. 2-(Fluoroaryl)-indoles on treatment with oxalyl chloride and subsequent reaction with amines, gave 2-(fluoroaryl)-3-indolylglyoxamides. Some of these indolylglyoxamides were reducted with lithium aluminium hydride, to the corresponding tryptamines. 2-(Fluoroaryl)-indoles when subjected toMannich reaction afforded 3-dialkylaminomethyl-2-(fluoroaryl)-indoles. All these new compounds have been characterized by IR spectral studies.Possible Psychopharmacological Agents, Part XII, Part XI, J. Indian. Chem. Soc.57, 423 (1980). 相似文献
40.
A microdialysis junction is employed as the interface for on-line coupling of capillary isoelectric focusing with transient isotachophoresis-zone electrophoresis in a two-dimensional separation system. Capillary isoelectric focusing not only provides high-resolution separation of tryptic peptides based on their differences in isoelectric point, but also potentially allows the analysis of low-abundance proteins with a typical concentration factor of 50-100 times. Carrier ampholytes, employed for the creation of a pH gradient during focusing, are further utilized as the leading electrolyte in the second separation dimension, transient isotachophoresis-zone electrophoresis. Many peptides which have the same isoelectric point would most likely have different charge-to-mass ratios, and thus different electrophoretic mobilities in zone electrophoresis. Two-dimensional separation of proteolytic peptides is demonstrated using standard proteins, including cytochrome c, ribonuclease A, and carbonic anhydrase II. The maximum peak capacity is estimated to be around approximately 1600 and can be significantly increased by simply increasing the capillary column length and manipulating the range of pH gradient in isoelectric focusing. In addition to enhanced separation efficiency and resolution, this two-dimensional electrokinetic separation system permits sensitive and comprehensive analysis of peptide fragments, especially when integrated with electrospray ionization mass spectrometry for peptide/protein identification. 相似文献