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91.
Effect of Surface Protonation on Device Performance and Dye Stability of Dye-sensitized TiO2 Solar Cell 下载免费PDF全文
A flat thin TiO2 film was employed as the photo-electrode of a dye sensitized solar cell (DSSC), on which only a geometrical mono-layer of dye was attached. The effect of sur-face protonation by HCl chemical treatment on the performance of DSSCs was studied. The results showed that the short-circuit current Jsc increased significantly upon the HCl treatment, while the open-circuit voltage Voc decreased slightly. Compared to the untreated DSSC, the Jsc and energy conversion efficiency was increased by 31% and 25%, respectively, for the 1 mol/L HCl treated cell. TiO2 surface protonation improved electronic coupling between the chemisorbed dye and the TiO2 surface, resulting in an enhanced electron in-jection. The decreased open-circuit voltage after TiO2 surface protonation was mainly due to the TiO2 conduction band edge downshift and was partially caused by increased electron recombination with the electrolyte. In situ Raman degradation study showed that the dye stability was improved after the TiO2 surface protonation. The increased dye stability was contributed by the increased electron injection and electron back reaction with the electrolyte under the open-circuit condition. 相似文献
92.
掺镱氟铅硅酸盐玻璃光谱性质研究 总被引:2,自引:1,他引:1
采用高温熔融法制备了组成为(80-x)SiO2·xPbO·(17~19)( R2O+RF) ·(1~3)Yb2O3(R=Li、Na、K)(mol%)的掺镱氟铅硅酸盐玻璃,测量了样品的吸收光谱、荧光光谱和荧光寿命,利用McCumber理论计算了该玻璃系统中Yb3+离子2F5/2→2F7/2能级跃迁受激发射截面.结果表明,该玻璃在1 013 nm处的σemi为0.21×10-20 cm2,荧光有效线宽为94.8 nm,荧光寿命为2.36 ms.激光性能评价结果表明,该玻璃是实现大能量超短脉冲激光的理想材料. 相似文献
93.
山东滕州西宫桥遗址人骨的线扫描分析 总被引:1,自引:0,他引:1
采用SEM-EDS技术,分析了山东滕州西宫桥遗址出土的古代人骨。其骨组织的显微结构分析指出,成岩作用业已严重破坏了骨骼的哈佛氏系统结构。而骨剖面线扫描分析显示,骨剖面上的元素分布具有明显的差异,表明骨内外表面与中间部分的元素发生了富集或流失。该结果将对古代人类食谱分析的样品预处理具有重要的参考价值。 相似文献
94.
证明一类非线性抛物方程ut-g(DGσ*u,D2Gσ*u)Du div DDuu=0u(x,0)=u0粘性解的存在惟一性,并通过实验验证了该模型在图像处理中的应用. 相似文献
95.
用MATLAB解决高等数学中的图形问题 总被引:13,自引:0,他引:13
本文通过实例将 MATLAB与 Mathematica的图形功能做了比较 ,指出了 MATLAB在解决高等数学图形问题时的优势 . 相似文献
96.
A strategy combining ligand design and counterion variation has been used to investigate the assembly of silver(I) complexes. As a result, dinuclear, octanuclear, and polymeric silver(I) species have been synthesized by complexation of the rigid aliphatic amino ligands cis-3,5-diamino-trans-hydroxycyclohexane (DAHC), cis-3,5-diamino-trans-methoxycyclohexane (DAMC), and cis-3,5-diamino-trans-tert-butyldimethylsilylanyloxycyclohexane (DATC) with silver(I) triflate, nitrate, and perchlorate. The compositions of these aggregates, established by X-ray crystallography and elemental analysis, are [{Ag(DAHC)}2](CF3SO3)2 (1), [{Ag(DAMC)}2](CF3SO3)2 (2), [{Ag(DAMC)}2](NO3)2 (3), [{Ag(DATC)}6{Ag(DAHC)}2](NO3)8 (4), and [{Ag(DATC}n](NO3)n (5), where the DAHC present in 4 is formed by in situ hydrolysis of the acid labile silyl ether group. The type of aggregate formed depends both upon the noncoordinating O-substituent of the ligand and the (also noncoordinating) counterion, with the normal preference of the ligand topology for forming Ag2L2 structures being broken by introduction of the bulky, lipophilic O-tert-butyldimethylsilyl (TBDMS) group. Of particular note is the octanuclear silver ring structure 4, which is isolated only when both the O-TBDMS group and the nitrate counteranion are present and is formed from four Ag2L2 dimers connected by Ag...Ag and hydrogen-bonding interactions. Diffusion rate measurement of this {Ag8} complex by 1H NMR (DOSY) indicates dissociation in CD3OD and CD3CN, showing that this supramolecular ring structure is formed upon crystallization, and establishing a qualitative limit to the strength of Ag...Ag interactions in solution. When solutions of the {Ag8} cluster in methanol are kept for several days though, a new UV-vis absorption is observed at around 430 nm, consistent with the formation of silver nanoparticles. 相似文献
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99.
讨论了基于Caputo导数的Miller-Ross序列导数的分数阶微分方程的稳定性.根据Laplace变换,得到分数阶微分方程的解;应用Mittag-Leffler函数的渐近展开,讨论了方程的稳定性.分两部分:齐次方程与非齐次方程. 相似文献
100.
利用磁控溅射法,采用亚分子分层掺杂技术交替溅射Co靶和ZnO靶,在Si衬底上制备了不同氢氩流量比的H:ZCO薄膜样品,研究了氢氩流量比对薄膜结构特性和磁学性能的影响。所制备的薄膜样品具有c轴择优取向。由于H对表面和界面处悬挂键的钝化作用,随H2流量比的增加,薄膜的择优取向变差。磁性测量结果显示,薄膜样品的铁磁性随着氢氩流量比的增大而增强。XPS结果表明,随着H含量的增大,金属态Co团簇的相对含量逐渐增加,而氧化态Co离子的相对含量逐渐减小。H:ZCO样品中的铁磁性可能来源于Co金属团簇,H的掺入促使ZnO中的Co离子还原成Co金属团簇,从而增强了薄膜样品的室温铁磁性。 相似文献