Effective masses in a strongly anisotropic fermi liquid

Motivated by the recent experimental observation of quantum oscillations in the underdoped cuprates, we study the cyclotron and infrared Hall effective masses in an anisotropic Fermi liquid characterized by an angle-dependent quasiparticle residue Z_{q}. Our primary motivation is to explain the relatively large value of the cyclotron mass observed experimentally and its relation with the effective Hall mass. Using a phenomenological model of an anisotropic Fermi liquid, we find that the cyclotron mass is enhanced by a factor 1/Z_{q}, while the effective Hall mass is proportional to Z_{q}/Z_{q};{2}, where cdots, three dots, centered implies an averaging over the Fermi surface. If the Z-factor becomes small in some part of the Fermi surface (e.g., in the case of a Fermi arc), the cyclotron mass is enhanced sharply while the infrared Hall mass may remain small.     

Repulsion between inorganic particles inserted within surfactant bilayers

We study by synchrotron small-angle x-ray scattering highly aligned lamellar phases of a zwitterionic surfactant, doped with monodisperse and spherical hydrophobic inorganic particles as a function of particle concentration. Analysis of the structure factor of the two-dimensional fluid formed by the particles in the plane of the bilayer gives access to their membrane-mediated interaction, which is repulsive, with a contact value of about 4kBT and a range of 14 angstroms. Systematic application of this technique should lead to a better understanding of the interaction between membrane inclusions.     

Slow Magnetic Relaxation in {[CoCxAPy)] 2.15 H2O}n MOF Built from Ladder-Structured 2D Layers with Dimeric SMM Rungs

We present the magnetic properties of the metal-organic framework {[CoCxAPy]·2.15 H₂O}_n (Cx = bis(carboxypropyl)tetramethyldisiloxane; APy = 4,4′-azopyridine) (1) that builds up from the stacking of 2D coordination polymers. The 2D-coordination polymer in the bc plane is formed by the adjacent bonding of [CoCxAPy] 1D two-leg ladders with Co dimer rungs, running parallel to the c-axis. The crystal packing of 2D layers shows the presence of infinite channels running along the c crystallographic axis, which accommodate the disordered solvate molecules. The Co(II) is six-coordinated in a distorted octahedral geometry, where the equatorial plane is occupied by four carboxylate oxygen atoms. Two nitrogen atoms from APy ligands are coordinated in apical positions. The single-ion magnetic anisotropy has been determined by low temperature EPR and magnetization measurements on an isostructural compound {[Zn_0.8Co_0.2CxAPy]·1.5 CH₃OH}_n (2). The results show that the Co(II) ion has orthorhombic anisotropy with the hard-axis direction in the C_2V main axis, lying the easy axis in the distorted octahedron equatorial plane, as predicted by the ab initio calculations of the g-tensor. Magnetic and heat capacity properties at very low temperatures are rationalized within a S* = 1/2 magnetic dimer model with anisotropic antiferromagnetic interaction. The magnetic dimer exhibits slow relaxation of the magnetization (SMM) below 6 K in applied field, with a τ_lf ≈ 2 s direct process at low frequencies, and an Orbach process at higher frequencies with U/k_B = 6.7 ± 0.5 K. This compound represents a singular SMM MOF built-up of Co-dimers with an anisotropic exchange interaction.     

Radiation and hot electron temperature measurements of short-pulselaser driven hohlraums

We have performed measurements of the radiation and the hot electron temperature in sub-millimetre size hohlraums driven by a high intensity short-pulse laser. The results indicate that radiation temperatures 80 eV can be obtained with 20 J of laser energy delivered on target. Radiation-hydrodynamics simulations indicate an absorption into thermal X-rays of 1–2%, with peak temperatures similar to those measured experimentally.     

Raman and surface‐enhanced Raman spectra of flavone and several hydroxy derivatives

The Raman and surface‐enhanced Raman spectra (SERS) of flavone and three of its hydroxy derivatives, 3‐hydroxyflavone (3‐HF) and 5‐hydroxyflavone (5‐HF) and quercetin (3,5,7,3′,4′ pentahydroxyflavone) have been obtained. The normal Raman (NR) spectra were taken in the powder form. The SERS spectra were obtained both on Ag colloids and Ag electrode substrates. Assignments of the spectrally observed normal modes were aided by density functional theory (DFT) calculations using the B3LYP functional and the 6‐31 + G* basis, a split valence polarized basis set with diffuse functions. Excellent fits were obtained for the observed spectra with little or no scaling. The most intense lines of the NR spectra are those in the CO stretching region (near 1600 cm⁻¹). These lines are often weakened by proximity to the surface, while other lines at lower wavenumbers, due to in‐plane ring stretches, tend to be strongly enhanced. The SERS spectrum of flavone is weak both on the colloid and on the electrode, indicating weak attachment to the surface. In contrast, the SERS spectra of the hydroxy derivatives of flavone are intense, indicating the assistance of OH groups in attachment to the surface. The spectra of the various species are compared, and a case study of application to detection of a textile dye (Persian berries), which contains quercetin, is presented. Copyright © 2007 John Wiley & Sons, Ltd.     

Stability of peakons

The peakons are peaked solitary wave solutions of a certain nonlinear dispersive equation that is a model in shallow water theory and the theory of hyperelastic rods. We give a very simple proof of the orbital stability of the peakons in the H¹ norm. © 2000 John Wiley & Sons, Inc.     

Synthesis and Toxicity Evaluation of New Pyrroles Obtained by the Reaction of Activated Alkynes with 1-Methyl-3-(cyanomethyl)benzimidazolium Bromide

A series of new pyrrole derivatives were designed as chemical analogs of the 1,4-dihydropyridines drugs in order to develop future new calcium channel blockers. The new tri- and tetra-substituted N-arylpyrroles were synthesized by the one-pot reaction of 1-methyl-3-cyanomethyl benzimidazolium bromide with substituted alkynes having at least one electron-withdrawing substituent, in 1,2-epoxybutane, acting both as the solvent and reagent to generate the corresponding benzimidazolium N3-ylide. The structural characterization of the new substituted pyrroles was based on IR, NMR spectroscopy as well as on single crystal X-ray analysis. The toxicity of the new compounds was assessed on the plant cell using Triticum aestivum L. species and on the animal cell using Artemia franciscana Kellogg and Daphnia magna Straus crustaceans. The compounds showed minimal phytotoxicity on Triticum rootlets and virtually no acute toxicity on Artemia nauplii, while on Daphnia magna, it induced moderate to high toxicity, similar to nifedipine. Our research indicates that the newly synthetized pyrrole derivatives are promising molecules with biological activity and low acute toxicity.     

Hybrid Algorithms in Image Reconstruction

We consider in this paper a combination between the evolutionary algorithm Particle Swarm Optimization (PSO), and the ART Kaczmarz procedure. For the new hybrid algorithm so obtained some results ilustrating its efficiency are presented for consistent least-squares formulation of an image reconstruction problem. (© 2006 WILEY-VCH Verlag GmbH & Co. KGaA, Weinheim)     

Analysis of the equations for the temperature dependence of the retention index. I. Relation between equations.

The relation between the parameters of several equations for the retention index temperature dependence was established, taking the hyperbola deduced from the retention theory as starting point. The transformation factors depend only on methylene contributions to the thermodynamic functions of solution and temperature. Their evolution with the mean temperature of the range was illustrated for SE-30 and Carbowax-20M glass capillary columns. On this basis the post-run standardisation of dI/dT values at a reference mean temperature is possible. Examples and statistical correlation between series of parameters from different equations for perfumery solutes were shown.