Experimental constraints onJ PC=1−+,I=1, Hybrid mesons

Using data on coherent production of π⁺π⁺π^- systems in π⁺ collisions with nuclei we exclude the existence ofJ ^PC=1^?+,I=1, exotic hybrid mesons with masses below 1.5 GeV and widths greater than 20 MeV, provided that their primary coupling is to πρ systems. Hybrid states with just such properties have recently been predicted from arguments based on QCD sum rules. Our experimental limit is based on Primakoff production of these states, and on an argument using vector dominance to relate their radiative widths to πρ channels. There has been increasing interest of late in the existence of hybrid states, which, in the case of mesons, contain a valence gluon in addition to aq \(\bar q\) pair in a color-octet state [1–5]. The pursuit of spectroscopic gluon degrees of freedom has been strongly motivated by the general QCD picture of hadrons, as well as by many specific calculations based on QCD sum rules, lattice simulations, and more phenomenological approaches such as QCD-bag models. Although much effort, both thoretical and experimental, has been devoted to the spectroscopy of glueballs, for which several candidates exist [6], it has also been realized that hybrid states may be as amenable to discovery, and perhaps less ambiguous to interpretation.     

A Facile Synthesis of Various Butenolides

The synthesis of α'-acyloxy-α,β-unsaturated cyclic ketones from the corresponding α,β-unsaturated cyclic ketones by using manganese (III) acetate in combination with 2-chloropropionic acid followed by subsequent Arbuzov and intramolecular Horner-Emmons cyclization reactions provided a convenient synthetic pathway to various butenolides 4a-d.     

Manganese(III) acetate promoted acetoxylation of various α,β-unsaturated cyclopentanones

We describe the results of manganese(III) acetate based regioselective oxidation of various α,β-unsaturated cyclopentanones leading to α′-acetoxy α,β-unsaturated cyclopentanones in good yields. Products due to monophenyl and diphenyl substituted dimerization have been identified as byproducts of the reaction.